Defect engineering of carbon-based electrocatalysts for the CO2 reduction reaction: A review DOI Open Access

Yankun Lu,

Baixue Cheng,

Haoyu Zhan

et al.

New Carbon Materials, Journal Year: 2024, Volume and Issue: 39(1), P. 17 - 41

Published: Feb. 1, 2024

Language: Английский

Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction DOI

Ziruo Zhou,

Wenyu Guo,

Tingyu Yang

et al.

Chinese Journal of Structural Chemistry, Journal Year: 2024, Volume and Issue: 43(3), P. 100245 - 100245

Published: Feb. 5, 2024

Language: Английский

Citations

74
Molecular Co-Catalyst Confined within a Metallacage for Enhanced Photocatalytic CO2 Reduction DOI
Dongdong Liu,

Huirong Ma,

Chao Zhu

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(3), P. 2275 - 2285

Published: Jan. 12, 2024

The construction of structurally well-defined supramolecular hosts to accommodate catalytically active species within a cavity is promising way address catalyst deactivation. resulting catalysts can significantly improve the utilization catalytic sites, thereby achieving highly efficient chemical conversion. In this study, Co-metalated phthalocyanine (

Language: Английский

Citations

45
Regulating the Electronic Configuration of Ni Sites by Breaking Symmetry of Ni‐Porphyrin to Facilitate CO2 Photocatalytic Reduction DOI
Yuan‐Hui Zhong, Yang Wang,

Sheng‐Yi Zhao

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(25)

Published: Feb. 10, 2024

Abstract Adapting the coordination environment to influence electronic configuration of active sites represents an efficient approach for improving photocatalytic performance CO 2 reduction reaction (CO RR) but how execute it precisely remains challenging. Herein, heteroatom‐substitution in Ni‐porphyrin break symmetry Ni center is proposed be effective solution. Based on this, two symmetry‐breaking Ni‐porphyrins, namely Ni(Cl)ON 3 Por and Ni(Cl)SN , are designed successfully prepared. By theoretical calculation, found that efficiently regulates d orbital energy levels center. Furthermore, experimental findings jointly revealed Ni‐porphyrins facilitates generation highly reactive I species during catalytic process, effectively stabilizing reducing barrier formation key * COOH intermediate. As a result, gave production rates 24.7 38.8 mmol g −1 h as well selectivity toward 94.0% 96.4%, respectively, outperforming symmetric NiN 4 rate 6.6 82.8%). These offer microscopic insights into modulate activity by tuning rational design competent catalyst RR photocatalysis.

Language: Английский

Citations

24
Artificial photosynthesis platform of 2D/2D MXene/crystalline covalent organic frameworks heterostructure for efficient photoenzymatic CO2 reduction DOI
Jiafu Qu, Tingyu Yang,

Pengye Zhang

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 348, P. 123827 - 123827

Published: April 24, 2024

Language: Английский

Citations

21
Tailoring CuNi heteronuclear diatomic catalysts: Precision in structural design for exceptionally selective CO2 photoreduction to ethanol DOI

Entian Cui,

Yulian Lu, Jizhou Jiang

et al.

CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Journal Year: 2024, Volume and Issue: 59, P. 126 - 136

Published: April 1, 2024

Language: Английский

Citations

17
Achieving Almost 100% Selectivity in Photocatalytic CO2 Reduction to Methane via In‐Situ Atmosphere Regulation Strategy DOI

Wanyi Zhang,

Chaoyuan Deng, Wei Wang

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(35)

Published: July 14, 2024

Artificial photosynthesis, harnessing solar energy to convert CO

Language: Английский

Citations

17
Halogen modified organic porous semiconductors in photocatalysis: mechanism, synthesis, and application DOI Creative Commons
Yue Yang, Liping Guo, Xuepeng Wang

et al.

Advanced Powder Materials, Journal Year: 2024, Volume and Issue: 3(2), P. 100178 - 100178

Published: Jan. 23, 2024

Photocatalysis is considered as the promising energy conversion way to resolve issues of crisis and environmental pollution. As key point photocatalysis, photocatalyst determines final efficiency from solar, therefore, composition photoelectronic nature which deserve be valued. Halogen often affects immensely intrinsic electron configuration matrix because electrophilic property, thus its topic has attracted lots attention for photocatalytic application. In this review, halogen-contained organic porous semiconductors are discussed in detailed. Firstly, role halogens photocatalysis based on categorized. Then, introduce into their applications reviewed. At last, outlooks given at end paper. This review would bring new insights non-metal doping engineering improving performance semiconductors.

Language: Английский

Citations

15
Mechanisms of noble metal-enhanced ferroelectric spontaneous polarized photocatalysis DOI
Mingliang Du, Wei Liu, Nian Liu

et al.

Nano Energy, Journal Year: 2024, Volume and Issue: 124, P. 109495 - 109495

Published: March 12, 2024

Language: Английский

Citations

15
Pivotal Impact Factors in Photocatalytic Reduction of CO2 to Value‐Added C1 and C2 Products DOI

Yongqian Cui,

Abdelkader Labidi,

Xinxin Liang

et al.

ChemSusChem, Journal Year: 2024, Volume and Issue: unknown

Published: April 15, 2024

Over the past decades, CO

Language: Английский

Citations

11
CQDs-interspersed floral CdS/NiAl-LDH heterojunction towards efficient photoreduction of CO2-to-CO DOI
Jia Li, Wentao Liu, Yang Li

et al.

Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 983, P. 173944 - 173944

Published: Feb. 22, 2024

Language: Английский

Citations

10