New Carbon Materials, Journal Year: 2024, Volume and Issue: 39(1), P. 17 - 41
Published: Feb. 1, 2024
Language: Английский
New Carbon Materials, Journal Year: 2024, Volume and Issue: 39(1), P. 17 - 41
Published: Feb. 1, 2024
Language: Английский
Chinese Journal of Structural Chemistry, Journal Year: 2024, Volume and Issue: 43(3), P. 100245 - 100245
Published: Feb. 5, 2024
Language: Английский
Citations
74Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(3), P. 2275 - 2285
Published: Jan. 12, 2024
The construction of structurally well-defined supramolecular hosts to accommodate catalytically active species within a cavity is promising way address catalyst deactivation. resulting catalysts can significantly improve the utilization catalytic sites, thereby achieving highly efficient chemical conversion. In this study, Co-metalated phthalocyanine (
Language: Английский
Citations
45Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(25)
Published: Feb. 10, 2024
Abstract Adapting the coordination environment to influence electronic configuration of active sites represents an efficient approach for improving photocatalytic performance CO 2 reduction reaction (CO RR) but how execute it precisely remains challenging. Herein, heteroatom‐substitution in Ni‐porphyrin break symmetry Ni center is proposed be effective solution. Based on this, two symmetry‐breaking Ni‐porphyrins, namely Ni(Cl)ON 3 Por and Ni(Cl)SN , are designed successfully prepared. By theoretical calculation, found that efficiently regulates d orbital energy levels center. Furthermore, experimental findings jointly revealed Ni‐porphyrins facilitates generation highly reactive I species during catalytic process, effectively stabilizing reducing barrier formation key * COOH intermediate. As a result, gave production rates 24.7 38.8 mmol g −1 h as well selectivity toward 94.0% 96.4%, respectively, outperforming symmetric NiN 4 rate 6.6 82.8%). These offer microscopic insights into modulate activity by tuning rational design competent catalyst RR photocatalysis.
Language: Английский
Citations
24Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 348, P. 123827 - 123827
Published: April 24, 2024
Language: Английский
Citations
21CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Journal Year: 2024, Volume and Issue: 59, P. 126 - 136
Published: April 1, 2024
Language: Английский
Citations
17Advanced Powder Materials, Journal Year: 2024, Volume and Issue: 3(2), P. 100178 - 100178
Published: Jan. 23, 2024
Photocatalysis is considered as the promising energy conversion way to resolve issues of crisis and environmental pollution. As key point photocatalysis, photocatalyst determines final efficiency from solar, therefore, composition photoelectronic nature which deserve be valued. Halogen often affects immensely intrinsic electron configuration matrix because electrophilic property, thus its topic has attracted lots attention for photocatalytic application. In this review, halogen-contained organic porous semiconductors are discussed in detailed. Firstly, role halogens photocatalysis based on categorized. Then, introduce into their applications reviewed. At last, outlooks given at end paper. This review would bring new insights non-metal doping engineering improving performance semiconductors.
Language: Английский
Citations
15Advanced Materials, Journal Year: 2024, Volume and Issue: 36(35)
Published: July 14, 2024
Artificial photosynthesis, harnessing solar energy to convert CO
Language: Английский
Citations
15Nano Energy, Journal Year: 2024, Volume and Issue: 124, P. 109495 - 109495
Published: March 12, 2024
Language: Английский
Citations
14Journal of Alloys and Compounds, Journal Year: 2024, Volume and Issue: 983, P. 173944 - 173944
Published: Feb. 22, 2024
Language: Английский
Citations
10ChemSusChem, Journal Year: 2024, Volume and Issue: unknown
Published: April 15, 2024
Over the past decades, CO
Language: Английский
Citations
10