Frank Partial Dislocation Pinning Effect Engineered IrNi Alloy Nanoparticles for Water Splitting DOI
Yunjie Liu, Yongbin Xu, Yu Tian

et al.

ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 3378 - 3390

Published: Feb. 10, 2025

Language: Английский

Remarkably enhanced acidic photoelectrochemical glycerol oxidation achieving the theoretical maximum photocurrent of BiVO4 through anion modulation DOI

Jun‐Yuan Cui,

Tian-Tian Li, Zhao-Hua Yin

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 493, P. 152461 - 152461

Published: May 21, 2024

Language: Английский

Citations

9
Recent progress in carbonaceous materials for the hydrogen cycle: Electrolytic water splitting, hydrogen storage and fuel cells DOI

Guanghui Xia,

Habibullah,

Qingfeng Xie

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 495, P. 153405 - 153405

Published: June 22, 2024

Language: Английский

Citations

9
Crystal‐Phase Engineering of Iridium‐Embedded Tungsten for Hydrogen Oxidation Electrocatalysis DOI Open Access
Lei Zhao, Bo Ouyang,

Yisong Yang

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 9, 2025

Abstract Understanding the phase structure‐dependent catalytic performance is of great significance for investigation advanced electrocatalysts. At present, research in engineering metal materials electrocatalysis predominantly concentrates on iron group, platinum and coinage group metals with A1‐, A2‐, A3‐ type structures. However, beyond above other types structures still poorly explored. Herein, using tungsten as a substrate to support iridium, it shown that iridium‐embedded diverse crystal structure (referred Ir/α‐W A2‐type Ir/β‐W A‐15 structure) exhibits distinct activity hydrogen oxidation reactions (HOR) alkaline medium. Notably, mass‐normalized exchange current density (j 0, m ) noble iridium (518.3 A g −1 Ir ≈1.8 times 16.4 higher than Ir/C, respectively. In‐depth mechanistic studies suggest enhanced HOR attributed connectivity H‐bond network well synergistic optimization adsorption binding energies H OH intermediate species. This study can inspire more scientific interest exploration electrocatalysis.

Language: Английский

Citations

1
Platinum‐Nickel Oxide Cluster‐Cluster Heterostructure Enabling Fast Hydrogen Evolution for Anion Exchange Membrane Water Electrolyzers DOI Open Access

Xinying Zheng,

Xiaozhong Zheng,

Mingxia Gao

et al.

Angewandte Chemie International Edition, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 31, 2025

Abstract Carbon black has been extensively employed as the support for noble metal catalysts electrocatalysis applications. However, nearly catalytic inertness and weak interaction with species of carbon are two major obstacles that hinder further improvement performance. Herein, we report a surface functionalization strategy by decorating transition oxide clusters on commercial to offer specific activity enhanced species. In case NiO x cluster‐decorated black, strongly coupled cluster‐cluster heterostructure consisting Pt (Pt−NiO /C) is formed delivers greatly alkaline hydrogen evolution kinetics. The can not only accelerate process co‐catalyst, but also optimize adsorption H intermediates stabilize clusters. Notably, anion exchange membrane water electrolyzer Pt−NiO /C cathode catalyst (with loading 50 μ g cm −2 ) most competitive electrochemical performance reported date, requiring 1.90 V reach current density 2 A . results demonstrate significance carbonaceous supports toward development advanced electrocatalysts.

Language: Английский

Citations

1
Frank Partial Dislocation Pinning Effect Engineered IrNi Alloy Nanoparticles for Water Splitting DOI
Yunjie Liu, Yongbin Xu, Yu Tian

et al.

ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 3378 - 3390

Published: Feb. 10, 2025

Language: Английский

Citations

1