Hydrogen-Bonded Fibrous Nanotubes Assembled from Trigonal Prismatic Building Blocks DOI
Sayantan Mahapatra, Dingwen Qian, Ruihua Zhang

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(31), P. 21689 - 21699

Published: July 29, 2024

In reticular chemistry, molecular building blocks are designed to create crystalline open frameworks. A key principle of chemistry is that the most symmetrical networks likely outcomes reactions, particularly when highly involved. The strategy synthesizing low-dimensional aims reduce explicitly symmetry blocks. Here we report spontaneous formation hydrogen-bonded fibrous structures from trigonal prismatic blocks, which were form three-dimensional on account their structures. Utilizing different microscopic and spectroscopic techniques, identify at early stages assembly process in order understand growth mechanism. incorporated preferentially longitudinal direction, giving rise anisotropic porous organic nanotubes. Entropy-driven provides micrometer-scale unidirectional nanotubes with high porosity. By combining experimental evidence theoretical modeling, have obtained a deep understanding nucleation processes. Our findings offer fundamental insight into design tubular evolve further transverse directions provide extended higher-order [nano- microfibers], ultimately leading large-scale interconnected fiber-like twists turns. work paves way for innovative designs networks.

Language: Английский

Precise and Selective Detection of Perchlorate at Trace Level Using Side-Chain Engineered Perylene Sensor: From Probe to Platform DOI

Jiaxin Xiao,

Yangtao Wu, Lingjun Bu

et al.

Water Research, Journal Year: 2025, Volume and Issue: 282, P. 123658 - 123658

Published: April 15, 2025

Language: Английский

Citations

0
Imine‐Linked Covalent Organic Frameworks Tuned by Quaternary‐Ammonium‐Alkyl for Highly Effective and Selective Adsorption of Perchlorate from Water DOI

Jian Ao,

Yunpeng Wang, Lingjun Bu

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: April 21, 2025

Abstract Perchlorate (ClO 4 − ) contamination in surface water is an escalating issue for drinking safety. Herein, imine‐linked covalent organic framework (COF) tuned by quaternary ammonium alkyls (R N + developed ClO adsorption. The hydrophobic and cationic COF adsorbent achieves a record‐breaking adsorption capacity of at 912.7 mg g −1 , demonstrating remarkable selectivity over other environmentally relevant anions exhibiting rapid kinetics. Furthermore, the maintains excellent recycling performance (removal efficiency ≥ 80% after 10 cycles) using tetrachloroferrate regeneration. In dynamic flow‐through experiments with real samples, effectively treats ≈3200‐bed volumes feed streams (≈500 µg L ), enrichment factor 15.2. hydrophobicity identified as premise its interaction . Molecular simulations density functional theory calculations reveal that R anchored cores enriches via electrostatic attraction bonds unconventional hydrogen (C─H─O). These key insights pave way future design optimization adsorbents removing oxo‐anion from water, especially

Language: Английский

Citations

0
Charge-assisted hydrogen bonding in a bicyclic amide cage: an effective approach to anion recognition and catalysis in water DOI Creative Commons
Chengkai Xu, Quy Gia Tran, Dexin Liu

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

Hydrogen bonding is prevalent in biological systems, dictating a myriad of life-sustaining functions aqueous environments. Leveraging hydrogen for molecular recognition water encounters significant challenges synthetic receptors on account the hydration their functional groups. Herein, we introduce water-soluble cage, synthesized

Language: Английский

Citations

3
Ultradynamic Isoreticularly Expanded Porous Organic Crystals DOI
Yunjia Zhang, Rong‐Ran Liang, Benjamin A. Atterberry

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(22), P. 15525 - 15537

Published: May 23, 2024

Porous organic materials showcasing large framework dynamics present new paths for adsorption and separation with enhanced capacity selectivity beyond the size-sieving limits, which is attributed to their guest-responsive sorption behaviors. hydrogen-bonded crosslinked frameworks (HCOFs) are attractive remarkable ability undergo guest-triggered expansion contraction facilitated by flexible covalent crosslinkages. However, voids of HCOFs remain limited, restrains extent dynamics. In this work, we synthesized a series characterized unprecedented size capabilities induced solvents. These were constructed isoreticularly co-crystallizing two complementary sets hydrogen bonding building blocks generate porous molecular crystals, through thiol–ene/yne single-crystal-to-single-crystal transformations. The generated exhibit chemical durability, high crystallinity, extraordinary For instance, HCOF-104 crystals featuring pore diameter 13.6 Å expanded in DMF 300 ± 10% original lengths within just 1 min. This allows adsorb guest molecules that significantly larger than sizes crystalline states. Through methanol-induced contraction, these guests encapsulated fast-contracted HCOFs. advancements pave way methods encapsulating targeted delivery.

Language: Английский

Citations

2
Sensing features, on-site detection and bio-imaging application of a tripodal tris(hydroxycoumarin) based probe towards Cu2+/His DOI
Rajendran Kishore Kumar, Ottoor Anitha,

Kuppusamy Suganthirani

et al.

Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy, Journal Year: 2024, Volume and Issue: 324, P. 124972 - 124972

Published: Aug. 13, 2024

Language: Английский

Citations

2
The Versatile Applications of Calix[4]resorcinarene-Based Cavitands DOI Creative Commons
Kaiya Wang,

Kejia Yan,

Qian Liu

et al.

Molecules, Journal Year: 2024, Volume and Issue: 29(24), P. 5854 - 5854

Published: Dec. 11, 2024

The advancement of synthetic host–guest chemistry has played a pivotal role in exploring and quantifying weak non-covalent interactions, unraveling the intricacies molecular recognition both chemical biological systems. Macrocycles, particularly calix[4]resorcinarene-based cavitands, have demonstrated significant utility receptor design, facilitating creation intricately organized architectures. Within realm macrocycles, these cavitands stand out as privileged scaffolds owing to their adaptability, excellent topological structures, unique properties. So far, extensive investigations been conducted on various applications cavitands. In this review, we will elaborate diverse functions, including catalysis, separation purification, polymeric materials, sensing, battery well drug delivery. This review aims provide holistic understanding multifaceted roles across applications, shedding light contributions advancing field supramolecular chemistry.

Language: Английский

Citations

2
Tuning CH Hydrogen Bond‐Based Receptors toward Picomolar Anion Affinity via the Inductive Effect of Distant Substituents DOI Creative Commons
Matúš Chvojka,

Dominik Madea,

Hennie Valkenier

et al.

Angewandte Chemie International Edition, Journal Year: 2023, Volume and Issue: 63(5)

Published: Dec. 8, 2023

Inspired by nature, artificial hydrogen bond-based anion receptors have been developed to achieve high selectivity; however, their binding affinity is usually low. The potency of these increased the introduction aryl substituents, which withdraw electrons from site through resonance effect. Here, we show that polarization C(sp

Language: Английский

Citations

6
Artificial light-harvesting nanoparticles based on a tripodal fluorescence sensor mediated by multiple luminescence mechanisms DOI Creative Commons

Zhiying Wu,

Qiaona Zhang,

Dengli Chen

et al.

Sensors & Diagnostics, Journal Year: 2023, Volume and Issue: 3(2), P. 295 - 300

Published: Dec. 22, 2023

A tripodal sensor based on TPE was designed and synthesized. The compound with sensing ability can be constructed as nanoparticles in aqueous media, which have outstanding fluorescence properties mediated by the ESIPT–AIE–FRET triple mechanism.

Language: Английский

Citations

6
Synthesis and anion recognition characteristics of a trapezoidal benzene cage DOI

Caihong Mao,

Ruiye Wu,

Nana Chen

et al.

Organic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(12), P. 3348 - 3357

Published: Jan. 1, 2024

A novel trapezoidal cage was exclusively prepared and exhibits high binding affinity for anions with tetrahedral geometry alkaline features.

Language: Английский

Citations

1
Near-quantitative Removal of Oxalate and Terephthalate from Water by Precipitation with a Rigid Bis-amidinium Compound DOI Creative Commons
Rosemary J. Goodwin, Phonlakrit Muang‐Non,

Nikki A. Tzioumis

et al.

Published: June 18, 2024

A simple, readily-prepared precipitant (1.Cl2) precipitates oxalate or terephthalate from water with very high efficacy, removing these anions at sub-millimolar concentrations using only one equivalent of precipitant. simple aqueous base/acid cycle can be used to regenerate 1.Cl2 after use. The resulting precipitates, 1.oxalate and 1.terephthalate, are anhydrous closely-packed, each anion receiving eight charge-assisted hydrogen bonds amidinium N–H donors. Precipitation occurs much lower than other dicarboxylates, direct competition experiments the biologically/environmentally relevant divalent CO32–, HPO42– SO42– reveal selectivity for over competitors.

Language: Английский

Citations

1