Localized assembly in biological activity: Origin of life and future of nanoarchitectonics

Advances in Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 339, P. 103420 - 103420

Published: Feb. 3, 2025

Language: Английский

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Cathode Design Based on Nitrogen Redox and Linear Coordination of Cu Center for All-Solid-State Fluoride-Ion Batteries

Journal of the American Chemical Society, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 13, 2025

All-solid-state fluoride-ion batteries (FIBs) have attracted extensive attention as candidates for next-generation energy storage devices; however, promising cathodes with high density are still lacking. In this study, Cu3N is investigated a cathode material all-solid-state batteries, which offers enough anionic vacancies around the 2-fold coordinated Cu center F- intercalation, thereby enabling multielectron-transferred fluorination process. The contribution of both cationic and redox to charge compensation, in particular, generation molecular nitrogen species highly charged states, has been proved by several synchrotron-radiation-based spectroscopic technologies. As result, exhibits reversible capacity ∼550 mAh g-1, exceeding many conventional cathodes. It believed that new compensation chemistry well unique intercalation behaviors novel mixed-anion Cu-N/F local structures could bring insights into materials.

Language: Английский

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Supra-ceramics: a molecule-driven frontier of inorganic materials

Science and Technology of Advanced Materials, Journal Year: 2024, Volume and Issue: 25(1)

Published: Oct. 16, 2024

Discoveries and technological innovations over the past decade are transforming our understanding of properties ceramics, such as 'hard', 'brittle', 'homogeneous'. For example, inorganic crystals containing molecular anions exhibit excellent secondary battery characteristics, fusion solids molecules results in innovative catalytic functions physical properties. Different from conventional ceramics metal oxides that formed by monatomic cations anions, unique can be expected molecular-incorporated solids, due to asymmetric dynamic brought about constituent units. We name materials produce supra-ceramics. In this article, we describe various kinds supra-ceramics viewpoint synthesis, analysis properties/functions for a wide range applications.

Language: Английский

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Revealing the Unusual Mechanism of Mixed Cationic and Anionic Redox in Oxyfluorosulfide Cathode for All-Solid-State Fluoride-Ion Batteries

Chemistry of Materials, Journal Year: 2024, Volume and Issue: 36(4), P. 1928 - 1940

Published: Feb. 14, 2024

All-solid-state fluoride-ion batteries (FIBs) have been considered next-generation energy storage devices because of their high theoretical density. However, previously reported metal/metal fluoride active materials suffer from severe degradation due to large volume expansion; consequentially, fluoride-ion-intercalating fail deliver a capacity. Here, oxyfluorosulfide Sr2F2Fe2OS2 (SFFOS) with layer structure is as topotactic (de)intercalation host. This material delivers reversible capacity more than 340 mAh g–1, which remains well maintained after 20 cycles. The intercalation reaction mechanism for this and stable elucidated via X-ray diffraction fine analysis. Wherein both Fe2+/Fe3+ redox sulfide ion are involved in charge compensation during charge/discharge processes, where the contributes whole voltage range −1.5 1.5 V only middle state charge. Fluoride ions can not insert into Sr–S interstitial sites but also combine Fe cations. Meanwhile, excessive leads formation S–S bonds SFFOS lattice. These results highlight oxyfluorosulfides new class constructing high-performance FIBs.

Language: Английский

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Construction of Acceptor‐Multi‐F State Electrolyte to Enable Unprecedented Long‐Life and High‐Capacity Fluoride‐Ion Batteries

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 17, 2025

Abstract Fluoride ion batteries (FIBs) have garnered significant attention due to their ultrahigh theoretical energy density, dendrite‐free safety, and resource abundance. Although some anion acceptors been proposed address the insolubility of inorganic fluoride salts, difficulty in dissociating ions from results short lifespan extremely low specific capacity FIBs. Here, a battery is demonstrated with unprecedented long life through design an acceptor‐multi‐F state electrolyte. The high Lewis acidity triphenylantimony chloride (TSbCl) as novel acceptor electrolyte facilitates complete dissociation CsF, resulting TSbCl‐F complex can further interact form states. This strategy combines capability for salts minimal thermodynamic barriers releasing at electrode‐electrolyte interface. endows FIBs durable reversible fluorination/defluorination reaction (3700 cycles coulombic efficiency 99.5% small voltage polarization 30 mV) (580 mAh g −1 after 40 100 mA ). high‐output CuF 2 //Li configuration (with discharge plateau 2.9 V) larger‐sized pouch‐type //Sn+SnF 530 ) are demonstrated.

Language: Английский

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Fluorine as a Key Element in Solid-State Chemistry of Mixed Anions 3d Transition Metal-Based Materials for Electronic Properties and Energy

Chemical Reviews, Journal Year: 2025, Volume and Issue: unknown

Published: March 31, 2025

Mixed anion compounds containing fluorine and based on 3d transition elements represent a class of materials with significant interest in solid-state chemistry. Indeed, their highly varied chemical composition, structural diversity, the resulting electronic properties provide rich playground for imagining new applications field energy. The anions bonds they form are at heart this review. Key parameters such as electronegativity, hardness, polarizability introduced discussed to better understand charge capacity formed solid. Oxyfluorides most studied family due size similarity two anions, part review is dedicated specific synthesis these by systematically adjusting content within various structures analyzing electrochemical compositions. final sections focus often exhibiting two-dimensional character, where ionic blocks coexist covalent layers, fluorochalcogenides, fluoropnictides, fluorotetrelides. compositions correlated properties.

Language: Английский

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Anion-Controlled Inorganic Materials as Catalysts for Small-Molecule Conversion Reactions

ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown

Published: April 17, 2025

Various catalytic reactions such as water oxidation to O2 and CO2 reduction have been achieved using the surfaces of inorganic materials reaction sites, exemplified by oxygen-defect-induced in metal oxides. In recent years, anion-controlled post-transition-metal oxide attracted attention. These shown exhibit unique reactivity that cannot be with oxides because effect paired anion species coexisting anions. They also enable highly difficult surface properties resulting from molecular nature species. This Perspective reports on developments small-molecule conversion catalyzed materials.

Language: Английский

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Evidence of High Fluorine Ion Conductivity in SrF₂-Rich SrF₂–TiO₂-Based Compounds

ACS Omega, Journal Year: 2025, Volume and Issue: unknown

Published: April 28, 2025

Language: Английский

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Improved electrical transport properties of La0.7Ca0.3−K MnO3 (0.0 ≤ x ≤ 0.3) films grown on La0.3Sr0.7Al0.65Ta0.35O3 (00l) substrates by sol–gel spin coating method

Ceramics International, Journal Year: 2024, Volume and Issue: 50(15), P. 27027 - 27038

Published: May 1, 2024

Language: Английский

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Internal strain-driven bond manipulation and band engineering in Bi_2−xSb_xYO₄Cl photocatalysts with triple fluorite layers

Chemical Science, Journal Year: 2024, Volume and Issue: 15(30), P. 11856 - 11864

Published: Jan. 1, 2024

Internal strain within the triple fluorite layer of Bi 2− x Sb YO 4 Cl explains bond breaking and allows bandgap engineering.

Language: Английский

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