Electrosynthesis of pure urea from pretreated flue gas in a proton-limited environment established in a porous solid-state electrolyte electrolyser DOI
Yanchen Liu, Jia‐Run Huang, Haolin Zhu

et al.

Nature Nanotechnology, Journal Year: 2025, Volume and Issue: unknown

Published: April 17, 2025

Language: Английский

Tailoring CO2 Adsorption Configuration with Spatial Confinement Switches Electroreduction Product from Formate to Acetate DOI

Hua‐Qin Wang,

Heyu Sui,

Ya-Long Ding

et al.

Journal of the American Chemical Society, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 5, 2025

Multi-proton-coupled electron transfer, multitudinous intermediates, and unavoidable competing hydrogen evolution reaction during CO2 electroreduction make it tricky to control high selectivity for specific products. Here, we present spatial confinement of Fe single atoms (FeN2S2) by adjacent FeS clusters (Fe4S4) orientate the transition adsorption configuration from C,O-side O-end, which triggers a shift activated first-step protonation C–C coupling, thus switching target product HCOOH in Faraday efficiency (FE: 90.6%) on FeN2S2 CH3COOH 82.3%) Fe4S4/FeN2S2. The strength *OCHO upon solitary site is linearly related coordination number Fe–S, with predominantly produced over single-atom (ortho-substituted S atoms). Fe4S4 cluster functions as switch reduction product, can not only optimize electronic structure neighboring but also impel complete hydrocarbon intermediate *CH3, followed coupling CO2* *CH3 via synergistic catalysis This strategy provides new avenue modulate reactant model desirable pathways, potential applications diverse multistep electrochemical processes controlled selectivity.

Language: Английский

Citations

6
Recent strategies to improve the electroactivity of metal–organic frameworks for advanced electrocatalysis DOI Creative Commons

Runzhi Wei,

Xiao Li, Aziz B. Ibragimov

et al.

Deleted Journal, Journal Year: 2024, Volume and Issue: 1(2), P. 181 - 206

Published: Aug. 4, 2024

Abstract Metal–organic frameworks (MOFs) have emerged as promising materials in the realm of electrocatalysis due to their high surface area, tunable porosity, and versatile chemical functionality. However, practical application has been hampered by inherent limitations such low electrical conductivity a limited number active metal sites. Researchers addressed these challenges through various strategies, including enhancing incorporating conductive nanoparticles, modifying structure composition MOFs replacing nodes functionalizing linkers, preparing catalysts thermal processes decarburization conversion into oxides, phosphides (MPs), sulfides (MSs). This review provided comprehensive summary strategies that were employed enhance electroactivity for improved electrocatalytic performance recent years. It also explored future directions potential innovations design synthesis MOF‐based electrocatalysts, offering valuable insights advancing sustainable energy technologies.

Language: Английский

Citations

11
Bamboo-like amorphous Ni(OH)2 nanotubes wrapped Cu nanoparticles with a confined geometry for CO2 electroreduction to ethane in a flow cell DOI
Xiangyu Wang,

Weipei Sun,

Peng Wang

et al.

Science China Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 2, 2025

Language: Английский

Citations

2
Highly Selective CO2 Electroreduction to Multi‐carbon Alcohols via Amine Modified Copper Nanoparticles at Acidic Conditions DOI Open Access
Buxing Han,

Yahui Wu,

Chunjun Chen

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(49)

Published: Aug. 13, 2024

Abstract Electroreduction of CO 2 into multi‐carbon (C2+) products (e.g. C2+ alcohols) offers a promising way for utilization. Use strong alkaline electrolytes is favorable to producing products. However, can react with hydroxide form carbonate/bicarbonate, which results in low carbon utilization efficiency and poor stability. Using acidic electrolyte an efficient solve the problems, but it challenge achieve high selectivity Here we report that amine modified copper nanoparticles exhibit at condition. The Faradaic (FE) reach up 81.8 % media (pH=2) total current density 410 mA cm −2 over n‐butylamine Cu. Especially FE alcohols 52.6 %, higher than those reported electroreduction In addition, single‐pass towards production 60 %. Detailed studies demonstrate molecule on surface Cu cannot only enhance formation, adsorption coverage *CO, also provide hydrophobic environment, result

Language: Английский

Citations

9
Accelerated Solar-Driven Polyolefin Degradation via Self-Activated Hydroxy-Rich ZnIn2S4 DOI
Haoze Li, Shan Jiang,

Shan He

et al.

Nano Letters, Journal Year: 2024, Volume and Issue: 24(37), P. 11624 - 11631

Published: Sept. 3, 2024

Degradation of polyolefin (PE) plastic by a traditional chemical method requires high pressure and temperature but generates complex products. Here, sulfur vacancy-rich ZnIn

Language: Английский

Citations

8
Solid Electrolytes for Low-Temperature Carbon Dioxide Valorization: A Review DOI
Na Chu, Yong Jiang, Raymond Jianxiong Zeng

et al.

Environmental Science & Technology, Journal Year: 2024, Volume and Issue: 58(25), P. 10881 - 10896

Published: June 11, 2024

One of the most promising approaches to address global challenge climate change is electrochemical carbon capture and utilization. Solid electrolytes can play a crucial role in establishing chemical-free pathway for CO2. Furthermore, they be applied electrocatalytic CO2 reduction reactions (CO2RR) increase utilization, produce high-purity liquid chemicals, advance hybrid electro-biosystems. This review article begins by covering fundamentals processes capture, emphasizing advantages utilizing solid electrolytes. Additionally, it highlights recent advancements use polymer electrolyte or layer CO2RR with multiple functions. The also explores avenues future research fully harness potential electrolytes, including integration performance assessment under realistic conditions. Finally, this discusses opportunities challenges, aiming contribute establishment green sustainable society through valorization.

Language: Английский

Citations

7
Adjustable Selectivity for CO2 Electroreduction to Ethylene or Ethanol by Regulating Interphases Between Copper and Tin Oxides DOI Open Access
Huan Liu, Cheng‐Han Yang,

Tong Bian

et al.

Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 10, 2025

Abstract Enhancing the selectivity of C 2 products and revealing reaction mechanisms in CO electroreduction (CO RR) remain challenging. Regulating interphases catalysts is one most promising pathways. Herein, between copper (Cu) tin (Sn) oxides are regulated by controlling degree reduction during self‐assembly process, which exhibits obvious different to ethylene ethanol, respectively. The interphase Cu‐SnO ethanol as high 74.6%, while Cu O‐SnO shows 71.4% at –0.6 V versus RHE. In situ Fourier‐transform infrared spectroscopy measurements density functional theory calculations demonstrate that strong electron interaction, preferentially forming key *COH intermediates for asymmetrical C─C coupling produce ethanol. contrast, possesses oxygen vacancies both sites, thus enriching *CO symmetrical interphase. findings this work offer an advanced strategy regulating adjust RR.

Language: Английский

Citations

1
Progress in Cu‐Based Catalyst Design for Sustained Electrocatalytic CO2 to C2+ Conversion DOI Creative Commons
Dan Li, Jin‐Yuan Liu, Bin Wang

et al.

Advanced Science, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 27, 2025

Abstract The electrocatalytic conversion of CO 2 into valuable multi‐carbon (C 2+ ) products using Cu‐based catalysts has attracted significant attention. This review provides a comprehensive overview recent advances in catalyst design to improve C selectivity and operational stability. It begins with an analysis the fundamental reaction pathways for formation, encompassing both established emerging mechanisms, which offer critical insights design. In situ techniques, essential validating these by real‐time observation intermediates material evolution, are also introduced. A key focus this is placed on how enhance through manipulation, particularly emphasizing catalytic site construction promote C─C coupling via increasing * coverage optimizing protonation. Additionally, challenge maintaining activity under conditions discussed, highlighting reduction active charged Cu species materials reconstruction as major obstacles. To address these, describes strategies preserve sites control including novel utilization mitigation reconstruction. By presenting developments challenges ahead, aims guide future conversion.

Language: Английский

Citations

1
Tandem design on electrocatalysts and reactors for electrochemical CO2 reduction DOI
Mingzhi Wang,

Wensheng Fang,

Deyu Zhu

et al.

CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION), Journal Year: 2025, Volume and Issue: 69, P. 1 - 16

Published: Feb. 1, 2025

Language: Английский

Citations

1
Selective Electrochemical Reduction of CO2 to Ethanol on a Heteroatom-Coordinated Dual-Atom Catalyst of Fe/Cu-NC DOI Creative Commons
Fikiru Temesgen Angerasa, Endalkachew Asefa Moges, Chia-Yu Chang

et al.

Chemistry of Materials, Journal Year: 2025, Volume and Issue: unknown

Published: March 19, 2025

Language: Английский

Citations

1