Advances in catalysis, Journal Year: 2024, Volume and Issue: unknown, P. 181 - 256
Published: Jan. 1, 2024
Language: Английский
Advances in catalysis, Journal Year: 2024, Volume and Issue: unknown, P. 181 - 256
Published: Jan. 1, 2024
Language: Английский
Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 5, 2025
Abstract Electrocatalytic CO 2 reduction (CO RR) is rapidly emerging as a promising sustainable strategy for transforming into valuable fuels and chemical feedstocks, crucial step toward carbon‐neutral society. The efficiency, selectivity, stability of RR are heavily influenced by the chosen catalyst operating conditions used. Despite substantial advances in development catalysts, there scarcity comprehensive reviews focusing on influence different environments performance. This review offers detailed examination internal external environmental control strategies designed to enhance efficiency. fundamental reaction mechanisms through situ operational techniques, paired with theoretical analyses, discussed while also identifying key challenges future research directions technology. By delivering overview current state field, this highlights critical role control, mechanistic insights, practical considerations needed successful commercialization
Language: Английский
Citations
2Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 26, 2025
Abstract Achieving close integration and strong electronic communication between molecular catalysts conductive substrates is crucial for developing the stability catalytic activity of nanomaterials. However, constructing heterostructure catalyst usually need complex demanding synthesis processes. Herein, a facile universal “molecular nanojunction” strategy developed to prepare with high by improving coplanarity nanojunction facilitating efficient electron transfer. The density function theory (DFT) calculations in situ characterization indicate that reduces excessive * OH adsorption accelerates deprotonation process, thereby promoting oxygen generation. shows better evolution reaction (OER) performance than most reported catalysts. What's more, are applied alkaline anion exchange membrane (AEM) electrolysis cells, exhibiting excellent performance.
Language: Английский
Citations
1Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown, P. 137492 - 137492
Published: March 1, 2025
Language: Английский
Citations
1Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 178780 - 178780
Published: Jan. 1, 2025
Language: Английский
Citations
0Journal of Energy Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: April 1, 2025
Language: Английский
Citations
0Small, Journal Year: 2025, Volume and Issue: unknown
Published: April 16, 2025
Abstract This study presents a two‐step wet‐chemistry method for synthesizing AuAgCu x nanoparticles (NPs) using AuAg NP seeds. In‐depth research investigates how composition and temperature interact to drive phase transformations, linking composition, structure, catalytic function. These findings reveal that the alloying process exhibits unique composition‐dependent behavior under heat treatment, resulting in transformation sequence progresses from ternary alloy binary alloy, ultimately an ordered structure as varies. In this process, silver tends migrate away stable diffusing outward surface, while copper diffuses inward, forming AuCu alloy. CO 2 reduction experiments demonstrate Faradaic efficiency of (FE ) can be finely tuned throughout entire system. Additionally, these results highlight crucial roles density grain boundaries (GB) enhancing overall activity. work not only sheds light on complex interactions within systems but also provides valuable insights designing more efficient electrochemical catalysts reduction.
Language: Английский
Citations
0ChemElectroChem, Journal Year: 2025, Volume and Issue: unknown
Published: April 22, 2025
Electrochemical CO 2 reduction (CO R) to value‐added products using renewable electricity offers a promising approach toward achieving carbon neutrality. Among various electrocatalysts, molecular catalysts, particularly transition metal complexes, stand out due the high selectivity for single specific and desirable tunability, enabling rational optimization of catalytic performance. However, their practical application is hindered by low operating current densities challenges in catalyst recycling. To address these limitations, immobilizing catalysts on electrode surfaces has emerged as an effective strategy integrating selective into heterogeneous catalysis. This mini review focuses distinct category heterogenized catalysts—those molecularly dispersed supported substrates or surfaces‐which exhibit remarkable activity at single‐molecule level ability drive deep (beyond two electrons) under certain conditions. Recent progress this field comprehensively discussed, emphasizing critical impacts molecule‐level dispersion catalyst‐support interactions electronic properties, multi‐electron transfer kinetics, overall Moreover, overview potential applications beyond electrochemical R provided end. aims offer valuable insights future design efficient scalable electrocatalysts sustainable conversion.
Language: Английский
Citations
0Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: unknown, P. 137881 - 137881
Published: May 1, 2025
Language: Английский
Citations
0ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown
Published: May 28, 2025
Electrochemical reduction of carbon dioxide (CO2RR) is a promising strategy for mitigating global warming and producing value-added products simultaneously. Molecular catalysts, such as cobalt phthalocyanine (CoPc), are known to be effective in converting (CO2) monoxide (CO). However, it still challenging improve the reaction rate selectivity this conversion. Herein, we report simple coadsorption promote CoPc-catalyzed CO2RR CO by coadsorbing melamine molecules together with CoPc onto surface nanotubes (CNTs). The led an increase output current density 2.6-fold at overpotential -1.23 V vs Ag|AgCl. Moreover, Faraday efficiency (FE) toward increased 92% H-type cell, contrast FE 85% absence coadsorption. further improved 99% flow cell system. It was revealed that could modulate adsorption *CO intermediates decrease energy barrier CO2 CO. More importantly, only solution-based process employed whole procedure no organic synthesis involved, making our method highly simple, convenient, environment friendly. This work paves way modulating activity molecular catalysts CO2RR.
Language: Английский
Citations
0Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(48), P. 33948 - 33957
Published: Jan. 1, 2024
Metal complexes have been thoroughly studied for various electrochemical reactions.
Language: Английский
Citations
2