Synthesis and Characterization of Monomeric Triarylbismuthine Oxide DOI Creative Commons
Jennifer Kuziola, Hye Won Moon, Markus Leutzsch

et al.

Angewandte Chemie, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 22, 2024

Abstract The synthesis and isolation of a bismuth‐based analogue the venerable triphenylphosphine oxide (Ph 3 PO) has remained chimera to synthetic chemists for many years, due its predicted high reactivity instability. Through hydrolysis cationic fluorotriarylbismuthonium(V) salt, we report here unique hydroxytriarylbismuth(V) complexes, which served as precursor formation elusive monomeric triarylbismuthine Dipp Bi=O. Combined spectroscopic, crystallographic computational studies provided insight into bonding situation first triorganobismuth complex. Bi=O Mes BiO⋅LiBAr F complex exhibits O‐atom transfer reactivity, an uncommon feature Ar Pn=O.

Language: Английский

Synthesis and Characterization of Monomeric Triarylbismuthine Oxide DOI Creative Commons
Jennifer Kuziola, Hye Won Moon, Markus Leutzsch

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 22, 2024

Abstract The synthesis and isolation of a bismuth‐based analogue the venerable triphenylphosphine oxide (Ph 3 PO) has remained chimera to synthetic chemists for many years, due its predicted high reactivity instability. Through hydrolysis cationic fluorotriarylbismuthonium(V) salt, we report here unique hydroxytriarylbismuth(V) complexes, which served as precursor formation elusive monomeric triarylbismuthine Dipp Bi=O. Combined spectroscopic, crystallographic computational studies provided insight into bonding situation first triorganobismuth complex. Bi=O Mes BiO⋅LiBAr F complex exhibits O‐atom transfer reactivity, an uncommon feature Ar Pn=O.

Language: Английский

Citations

1
Synthesis and Characterization of Monomeric Triarylbismuthine Oxide DOI Creative Commons
Jennifer Kuziola, Hye Won Moon, Markus Leutzsch

et al.

Angewandte Chemie, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 22, 2024

Abstract The synthesis and isolation of a bismuth‐based analogue the venerable triphenylphosphine oxide (Ph 3 PO) has remained chimera to synthetic chemists for many years, due its predicted high reactivity instability. Through hydrolysis cationic fluorotriarylbismuthonium(V) salt, we report here unique hydroxytriarylbismuth(V) complexes, which served as precursor formation elusive monomeric triarylbismuthine Dipp Bi=O. Combined spectroscopic, crystallographic computational studies provided insight into bonding situation first triorganobismuth complex. Bi=O Mes BiO⋅LiBAr F complex exhibits O‐atom transfer reactivity, an uncommon feature Ar Pn=O.

Language: Английский

Citations

0