Bi(III)-Catalyzed Newman–Kwart Rearrangement for Synthesizing S-Heteroaryl Thiocarbamates DOI

Yuma Okuda,

Keita Yamazaki, Tetsuhiro Nemoto

et al.

The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 20, 2025

Newman-Kwart rearrangement (NKR) is a useful method for synthesizing S-aryl thiocarbamates from O-aryl thiocarbamates. Harsh temperature conditions are required, however, leading to substrate degradation and side reactions. Moreover, reactions using heteroaromatic substrates quite rare. Herein, we report Bi(OTf)3-catalyzed NKR under ambient conditions. The reaction extended not only aza-arene but also thiophene substrates.

Language: Английский

Trendbericht Anorganische Chemie 2024: Hauptgruppen‐ und Molekülchemie DOI Open Access
Josh Abbenseth, Frank Tambornino

Nachrichten aus der Chemie, Journal Year: 2025, Volume and Issue: 73(2), P. 46 - 55

Published: Jan. 31, 2025

Abstract Das erste heterobimetallische Dimetallocen; mit sterisch anspruchsvollen Liganden lassen sich einfach‐koordinierte Hauptgruppenverbindungen der Gruppen 13 bis 15 herstellen; neue Diazoverbindungen erlauben es, B‐R‐Einheiten und Kohlenstoffatome zu übertragen.

Citations

0
Bi(III)-Catalyzed Newman–Kwart Rearrangement for Synthesizing S-Heteroaryl Thiocarbamates DOI

Yuma Okuda,

Keita Yamazaki, Tetsuhiro Nemoto

et al.

The Journal of Organic Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 20, 2025

Newman-Kwart rearrangement (NKR) is a useful method for synthesizing S-aryl thiocarbamates from O-aryl thiocarbamates. Harsh temperature conditions are required, however, leading to substrate degradation and side reactions. Moreover, reactions using heteroaromatic substrates quite rare. Herein, we report Bi(OTf)3-catalyzed NKR under ambient conditions. The reaction extended not only aza-arene but also thiophene substrates.

Language: Английский

Citations

0