Activation and C‒C Coupling of Aryl Iodides via Bismuth Photocatalysis DOI Creative Commons
Mauro Mato, Alexios Stamoulis, Paolo Cleto Bruzzese

et al.

Angewandte Chemie, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 22, 2024

Abstract Within the emerging field of bismuth redox catalysis, catalytic formation C−C bonds using aryl halides would be highly desirable; yet such a process remains synthetic challenge. Herein, we present chemoselective bismuth‐photocatalyzed activation and subsequent coupling (hetero)aryl iodides with pyrrole derivatives to access C(sp 2 )−C(sp ) linkages through C−H functionalization. This unique reactivity is result complex featuring two state‐dependent interactions light, which 1) activates Bi(I) for oxidative addition via MLCT, 2) promotes homolytic cleavage Bi(III) intermediates LLCT process.

Language: Английский

Construction of Multiple Nonpolar SF6 Nano‐Traps by Highly Stable Pyrazole‐Based MOFs for SF6 Recovery DOI Open Access

Qichen Fan,

Jinze Yao,

Siyao Zhao

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 7, 2025

Abstract Sulfur hexafluoride (SF 6 ), widely used in electric power systems, is one of the most potent greenhouse gases. Efficient separation SF /N 2 by adsorptive technology based on porous materials great significance industry yet remains a daunting challenge. Herein, novel strategy introduced to construct unique pore channels with multiple nano‐traps precisely selecting bipyrazole ligands design nonpolar surface microporous metal−organic frameworks (MOFs), which significantly enhances material's affinity for . A series ultra‐stable bipyrazole‐based MOFs, M(BPZ) (M═Co, Ni, Zn), are synthesized and investigated. Among these three materials, Co(BPZ) Zn(BPZ) show excellent uptakes 2.47 2.39 mmol g −1 at 298 K 0.1 bar while exhibits highest (10/90, v/v) IAST selectivity 748. Breakthrough experiments reveal that mixtures can be efficiently separated high (≥99.5 %) productivity 46.1 L kg Theoretical calculations suggest preferably adsorbs through S−F··· π (pyrazole rings) van der Waals interactions. This work provides straightforward approach exploring adsorbents efficient separation.

Language: Английский

Citations

3
Activation and C‒C Coupling of Aryl Iodides via Bismuth Photocatalysis DOI Creative Commons
Mauro Mato, Alexios Stamoulis, Paolo Cleto Bruzzese

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 22, 2024

Within the emerging field of bismuth redox catalysis, catalytic formation C-C bonds using aryl halides would be highly desirable; yet such a process remains synthetic challenge. Herein, we present chemoselective bismuth-photocatalyzed activation and subsequent coupling (hetero)aryl iodides with pyrrole derivatives to access C(sp

Language: Английский

Citations

2
Activation and C‒C Coupling of Aryl Iodides via Bismuth Photocatalysis DOI Creative Commons
Mauro Mato, Alexios Stamoulis, Paolo Cleto Bruzzese

et al.

Angewandte Chemie, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 22, 2024

Abstract Within the emerging field of bismuth redox catalysis, catalytic formation C−C bonds using aryl halides would be highly desirable; yet such a process remains synthetic challenge. Herein, we present chemoselective bismuth‐photocatalyzed activation and subsequent coupling (hetero)aryl iodides with pyrrole derivatives to access C(sp 2 )−C(sp ) linkages through C−H functionalization. This unique reactivity is result complex featuring two state‐dependent interactions light, which 1) activates Bi(I) for oxidative addition via MLCT, 2) promotes homolytic cleavage Bi(III) intermediates LLCT process.

Language: Английский

Citations

0