Three-component modular synthesis of chiral 1,3-dioxoles via Rh-catalyzed carbenic olefination cascade DOI Creative Commons

Shi‐Sheng Huang,

Jilong Luo,

Ping Chen

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

Chiral 1,3-dioxoles are efficiently assembled from readily available I III /P V hybrid ylides reagents, aldehydes and carboxylic acids via Rh-catalyzed carbenic olefination cascade.

Language: Английский

Strategies for effective nitrous oxide capture: From materials to mechanisms DOI
Peiwen Xu, Zhe Li, Xuanhao Wu

et al.

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 535, P. 216627 - 216627

Published: March 17, 2025

Language: Английский

Citations

0
Click Chemistry: Reactions of a Diazomethyl Anion with Unsaturated Bonds† DOI
Rui Wei,

F.‐C. HUANG,

Xiaofang Lan

et al.

Chinese Journal of Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 16, 2025

Comprehensive Summary The reactions of potassium diazaphospholidinyl diazomethylide with phenylacetylene, acetonitrile, adamantyl phosphaalkyne, and styrene promptly form pyrazolide, triazolide, diazaphospholide, pyrazolinide, respectively. reaction mechanisms have been studied using DFT calculations. While the phenylacetylene proceed via stepwise pathways, those acetonitrile phosphaalkyne follow concerted pathways. Additionally, pyrazolide product readily undergoes N ‐functionalization, yielding methyl pyrazole, germanyl copper complexes.

Language: Английский

Citations

0
Three-component modular synthesis of chiral 1,3-dioxoles via Rh-catalyzed carbenic olefination cascade DOI Creative Commons

Shi‐Sheng Huang,

Jilong Luo,

Ping Chen

et al.

Chemical Science, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

Chiral 1,3-dioxoles are efficiently assembled from readily available I III /P V hybrid ylides reagents, aldehydes and carboxylic acids via Rh-catalyzed carbenic olefination cascade.

Language: Английский

Citations

0