Strategies for effective nitrous oxide capture: From materials to mechanisms
Peiwen Xu,
No information about this author
Zhe Li,
No information about this author
Xuanhao Wu
No information about this author
et al.
Coordination Chemistry Reviews,
Journal Year:
2025,
Volume and Issue:
535, P. 216627 - 216627
Published: March 17, 2025
Language: Английский
Click Chemistry: Reactions of a Diazomethyl Anion with Unsaturated Bonds†
Rui Wei,
No information about this author
F.‐C. HUANG,
No information about this author
Xiaofang Lan
No information about this author
et al.
Chinese Journal of Chemistry,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 16, 2025
Comprehensive
Summary
The
reactions
of
potassium
diazaphospholidinyl
diazomethylide
with
phenylacetylene,
acetonitrile,
adamantyl
phosphaalkyne,
and
styrene
promptly
form
pyrazolide,
triazolide,
diazaphospholide,
pyrazolinide,
respectively.
reaction
mechanisms
have
been
studied
using
DFT
calculations.
While
the
phenylacetylene
proceed
via
stepwise
pathways,
those
acetonitrile
phosphaalkyne
follow
concerted
pathways.
Additionally,
pyrazolide
product
readily
undergoes
N
‐functionalization,
yielding
methyl
pyrazole,
germanyl
copper
complexes.
Language: Английский
Three-component modular synthesis of chiral 1,3-dioxoles via Rh-catalyzed carbenic olefination cascade
Shi‐Sheng Huang,
No information about this author
Jilong Luo,
No information about this author
Ping Chen
No information about this author
et al.
Chemical Science,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Jan. 1, 2024
Chiral
1,3-dioxoles
are
efficiently
assembled
from
readily
available
I
III
/P
V
hybrid
ylides
reagents,
aldehydes
and
carboxylic
acids
via
Rh-catalyzed
carbenic
olefination
cascade.
Language: Английский