Chinese Chemical Letters, Journal Year: 2024, Volume and Issue: unknown, P. 110752 - 110752
Published: Dec. 1, 2024
Language: Английский
Chinese Chemical Letters, Journal Year: 2024, Volume and Issue: unknown, P. 110752 - 110752
Published: Dec. 1, 2024
Language: Английский
ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 5412 - 5425
Published: March 18, 2025
Language: Английский
Citations
1Carbon letters, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 11, 2025
Language: Английский
Citations
0Materials Today Chemistry, Journal Year: 2025, Volume and Issue: 46, P. 102722 - 102722
Published: April 24, 2025
Language: Английский
Citations
0DeCarbon, Journal Year: 2025, Volume and Issue: unknown, P. 100111 - 100111
Published: April 1, 2025
Language: Английский
Citations
0The Journal of Physical Chemistry C, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 23, 2025
Language: Английский
Citations
0ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 2305 - 2314
Published: Jan. 24, 2025
Language: Английский
Citations
0Wiley Interdisciplinary Reviews Computational Molecular Science, Journal Year: 2025, Volume and Issue: 15(1)
Published: Jan. 1, 2025
ABSTRACT The catalytic CO 2 hydrogenation to produce valuable fuels and chemicals holds immense importance in addressing energy scarcity environmental degradation. Given that the real reaction system is complex dynamic, structure of catalysts might experience dynamic evolution under conditions. It implies active sites only generated during process. induction factor could be reactants, intermediates, products, other local chemical environments. Utilizing in‐situ/operando characterization techniques allows for real‐time observation process, further combining multiscale theoretical simulations can effectively reveal refined mechanisms. Herein, we summarized latest advancements understanding mechanisms process C 1 products (CH 3 OH, CO, CH 4 ). evolutions catalyst morphology, size, valence state, interface between component support were discussed, respectively. Future research benefit from more in‐situ simulation explore microstructure mechanism, aiming high conversion selectivity reactions.
Language: Английский
Citations
0Analytical Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: March 25, 2025
Accurately sensing the spatial distribution of temperature, one most fundamental parameters, is crucial for understanding mechanism physicochemical process in confined space. However, traditional methods temperature measurement often show a very limited resolution and sensitivity. Herein, we develop surface-enhanced Raman spectroscopy (SERS) nanosensor to measure within hollow carbon nanospheres (HCNSs) study light-promoted Fenton-like catalyzed by Fe single-atom anchored on HCNSs. Based temperature-dependent SERS spectra phenyl isocyanide adsorbed Au nanoparticles, gradient nanocavity surface HCNSs, induced light-irradiation, sensed with sensitivity 0.8 °C. Furthermore, combining local reaction kinetics-temperature relationship, clarify that oxidation phenol peroxymonosulfate occurs at thus providing sound evidence homogeneous mechanism. Besides new strategy submicrometer resolution, this work also shows feasibility through locating reactive site.
Language: Английский
Citations
0Molecular Catalysis, Journal Year: 2025, Volume and Issue: 579, P. 115059 - 115059
Published: April 1, 2025
Language: Английский
Citations
0ChemCatChem, Journal Year: 2025, Volume and Issue: unknown
Published: April 1, 2025
Abstract CO 2 is a major contributor to global warming, leading severe environment and human health consequences. Catalytic hydrogenation has emerged as one of the most promising strategies mitigate emissions. However, catalytic performance existing catalysts remains suboptimal. Recent studies have highlighted potential oxygen vacancy (OV) engineering enhance by activating reactants, accelerating electron transport, tuning surface chemical properties catalysts. Despite its importance, comprehensive review OV in reactions lacking. This systematically examines recent advancements for design novel materials reactions. It covers key aspects such construction methods, characterization techniques, functions OVs. Additionally, addresses challenges catalyst synthesis characterization, while outlining future directions field. aims provide valuable insights development highly efficient
Language: Английский
Citations
0