Boosting 2D Black Phosphorus Ambient Stability: Noncovalent Functionalization Using Viologen Molecules
Small,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 21, 2025
Black
phosphorus
nanosheets
(BPNSs)
have
recently
emerged
as
a
valuable
addition
to
the
diverse
family
of
2D
materials,
holding
promises
for
wide
range
applications.
However,
their
practical
use
is
limited
by
poor
stability
under
ambient
conditions,
they
degrade
quickly
when
exposed
light,
air,
or
moisture.
Noncovalent
functionalization
offers
promising
approach
address
these
challenges.
Herein,
viologen
derivatives
are
incorporated
into
BPNS
suspension
in
acetonitrile,
resulting
formation
two
hybrid
materials.
These
hybrids
subsequently
stored
conditions
track
degradation
over
time.
The
behavior
functionalized
BPNSs
analyzed
and
compared
that
pristine
both
nitrogen
environments,
using
X-ray
photoelectron
spectroscopy.
Interestingly,
viologen-based
systems
exhibited
varying
degrees
protection
efficiency,
attributed
differences
average
adsorption
energies
aggregation
kinetics
with
BPNSs.
Methyl
viologen-functionalized
showed
markedly
reduced
less
pronounced
samples
protected
environment.
This
study
introduces
strategy
enhancing
BPNSs,
making
them
more
resistant
decomposition
potentially
suitable
energy
storage
applications
optoelectronic
devices.
Language: Английский
Contrast analysis for rapid characterization of 2D WTe2 structures
Agnese Spustaka,
No information about this author
Andrejs Terehovs,
No information about this author
Aris Jansons
No information about this author
et al.
APL Materials,
Journal Year:
2025,
Volume and Issue:
13(4)
Published: April 1, 2025
Two-dimensional
(2D)
layered
materials,
particularly
transition
metal
dichalcogenides,
exhibit
unique
electronic
and
optical
properties.
Among
these,
tungsten
ditelluride
(WTe2)
has
garnered
attention
for
its
semi-metallic
behavior
topologically
nontrivial
band
structure,
making
it
a
promising
candidate
advanced
nanoelectronic
applications.
A
significant
challenge,
however,
lies
in
achieving
scalable
characterization,
determining
thickness
coverage
of
WTe2
structures.
Existing
methods
are
often
limited
by
time
constraints
lack
suitability
high-throughput
workflows.
This
study
introduces
refined
workflow
combining
imaging,
segmentation,
contrast
analysis
to
address
these
limitations.
Calculated
values
normalized
were
correlated
with
thicknesses
determined
atomic
force
microscopy
found
scale
linearly.
The
proposed
provides
scalable,
adaptable
solution
2D
material
characterization.
Language: Английский
Effect of Substrate on Sulfur Vacancy Defect-Mediated Photoluminescence in Two-Dimensional MoS2
The Journal of Physical Chemistry C,
Journal Year:
2025,
Volume and Issue:
129(17), P. 8294 - 8302
Published: April 18, 2025
Chalcogen
vacancy
defects
in
monolayer
transition
metal
dichalcogenides
form
in-gap
states
that
can
trap
excitons,
leading
to
defect-mediated
photoluminescence
(PL)
emission.
Here,
we
show
room-temperature
(RT,
300
K)
PL
from
sulfur
vacancies
defective
MoS2
is
sensitive
doping
dielectric
substrates
such
as
SiO2
and
HfO2.
The
observed
for
on
untreated
HfO2
but
quenched
SiO2,
which
attributed
electron
of
SiO2.
Electron
confirmed
by
Raman
synchrotron
X-ray
photoelectron
spectroscopy.
Annealing
the
substrate
modifies
its
surface
states,
reflected
recovery
role
substrate-induced
vacancy-mediated
further
supported
gate-dependent
measurements.
Our
results
suggest
excess
electrons
fill
defect
energy
MoS2,
reducing
probability
photoexcited
carrier
occupation
subsequent
Language: Английский
Growth and magnetotransport properties of semi-metallic WTe2 nanoribbons
APL Materials,
Journal Year:
2025,
Volume and Issue:
13(4)
Published: April 1, 2025
Exploring
exotic
quantum
states
requires
high-quality
materials.
Tungsten
ditelluride
(WTe2),
a
type-II
Weyl
semimetal,
is
an
important
platform
for
studying
these
states.
Recent
discoveries,
including
the
spin
Hall
effect,
higher-order
topological
insulator
(TI)
states,
and
induced
superconductivity,
have
been
made
on
exfoliated
flakes.
However,
this
method
of
sample
fabrication
limited
by
its
lack
scalability.
For
studies
TI
1D
ribbon-shaped
WTe2
materials
with
reduced
dimensionality
are
great
importance.
Here,
we
present
simple
approach
growing
nanoribbons
from
WO3
thin
films.
Magnetotransport
studies,
effect
measurements,
presence
large
magnetoresistance
at
low
temperatures
confirm
good
quality
semi-metallic
nature
fabricated
nanoribbons,
which
crucial
fundamental
one-dimensional
topologically
protected
Language: Английский