Electrochimica Acta, Journal Year: 2025, Volume and Issue: unknown, P. 146494 - 146494
Published: May 1, 2025
Language: Английский
Electrochimica Acta, Journal Year: 2025, Volume and Issue: unknown, P. 146494 - 146494
Published: May 1, 2025
Language: Английский
Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 161059 - 161059
Published: Feb. 1, 2025
Language: Английский
Citations
1Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 180445 - 180445
Published: April 1, 2025
Language: Английский
Citations
1Journal of Electronic Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 9, 2025
Language: Английский
Citations
0Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: 1016, P. 178918 - 178918
Published: Jan. 29, 2025
Language: Английский
Citations
0Angewandte Chemie International Edition, Journal Year: 2025, Volume and Issue: unknown
Published: March 7, 2025
Abstract Developing functional metal–organic frameworks (MOFs) with high electrical conductivity is crucial for their applications as advanced electronic materials. In this work, we the first time construct a new family of and highly conductive MOFs using metalloporphyrazine (MPz) ligands based on trimming‐π concept via cutting benzene ring from molecular metallopthalocynine (MPc). The deprotonation‐after‐coordination synthetic method affords crystalline MPz−Cu−NH square lattices. Four‐point probe measurements reveal room temperature MPz‐based ranging 3.5×10 −2 to 1.3×10 −1 S cm , two orders magnitude higher than MPc‐based MOF counterparts. Temperature‐dependent band structure analysis demonstrate ultra‐small activation energies potential metallic conducting behavior MOFs. Encapsulation aromatic guest molecules different electron‐donating ‐withdrawing features allows modulation CuPz−Cu−NH in wide range spanning magnitude. These built‐in MPz units exhibit identity‐dependent sensing performance, realize sensitive detection NH 3 NO 2 low driving voltage 0.1 V.
Language: Английский
Citations
0Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 538, P. 216704 - 216704
Published: April 19, 2025
Language: Английский
Citations
0ACS Materials Letters, Journal Year: 2025, Volume and Issue: unknown, P. 2056 - 2062
Published: April 29, 2025
Language: Английский
Citations
0Materials Science and Engineering B, Journal Year: 2025, Volume and Issue: 320, P. 118428 - 118428
Published: May 15, 2025
Language: Английский
Citations
0Inorganic Chemistry, Journal Year: 2025, Volume and Issue: unknown
Published: May 19, 2025
The novel Co(II) coordination polymer incorporating 2-iodo-4-sulfobenzoic acid (H2isba) and a pliable 1,4-bis(benzimidazole-1-methyl) benzene (bdbmb) ligand, {[Co(bdbmb)(H2O)4]·isba·2H2O·2DMA}n (Co(II)-CP), was synthesized. In addition, the composite of Co(II)-CP with short hydroxyl multiwalled carbon nanotubes (Co(II)-CP@HCNTs) prepared via an in situ preparation strategy. Amperometric current response reveals that glass electrodes (GCEs) Co(II)-CP@HCNTs exhibit highly sensitive electrochemical sensing toward NO2- Fe3+ corresponding electrolytes. demonstrate superior electrocatalytic performance oxidation Fe3+reduction to Co(II)-CP. mechanisms for were illustrated Hirshfeld surface analysis density states calculations. Furthermore, this methodology successfully implemented on miniaturized screen-printed electrode (SPE) platform. Among three tested electrodes, Co(II)-CP@HCNT-modified SPEs exhibited capabilities, showing ranges 0.002-20 mM nitrite 0.002-38 ferric ions, respectively. calculated detection limits reached 0.12 μM (δ = 0.00396 μA, N 10) 0.30 0.00201 10). Moreover, Co(II)-CP@HCNTs/SPE further validated through practical applications both analytes real-world samples respective
Language: Английский
Citations
0ACS Physical Chemistry Au, Journal Year: 2025, Volume and Issue: unknown
Published: March 4, 2025
Language: Английский
Citations
0