Stereoinduction without direction: the long arm of ionic chiral ligands
Wenyang Hong,
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Ivan Keng Wee On,
No information about this author
Ye Zhu
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et al.
Trends in Chemistry,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 1, 2025
Language: Английский
Catalytic Asymmetric Electrophilic Chlorocarbocyclization of Alkenes Using ipso-Carbon Nucleophiles
Fuming Zhong,
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Zongren Ye,
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Tong Zhao
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et al.
ACS Catalysis,
Journal Year:
2025,
Volume and Issue:
unknown, P. 9452 - 9463
Published: May 19, 2025
Language: Английский
Progress in the Asymmetric Dearomatization Reactions of Arenols
Yong You,
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Siyi Yu,
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Qun Li
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et al.
ACS Catalysis,
Journal Year:
2025,
Volume and Issue:
unknown, P. 9503 - 9543
Published: May 20, 2025
Language: Английский
Catalytic Asymmetric Intramolecular Domino Allylic O-Alkylation/Allylic Dearomatization of Allyl Aryl Ethers
Yun-Qiao Zhang,
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Yinglong Li,
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Kun Wang
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et al.
Organic Letters,
Journal Year:
2025,
Volume and Issue:
unknown
Published: June 2, 2025
An
intramolecular
asymmetric
allylic
O-alkylation/allylic
dearomative
spirocyclization
cascade
has
been
successfully
developed
with
allyl
aryl
ethers.
In
the
presence
of
palladium
and
a
phosphoramidite
ligand,
series
spirocyclohexadienones
an
exocyclic
double
bond
were
obtained
in
up
to
98%
yield
ee.
The
alkylation
mechanism
was
elucidated
through
control
experiments.
addition,
scale-up
reaction
further
transformations
spirocyclic
products
also
performed,
demonstrating
potential
application
this
method.
Language: Английский