Balancing the Activity and Stability of Iron‐Based Catalysts via Mixed Oxide Species Formation for Electrocatalytic Biomass Hydrogenation DOI
Xinyu Zhang,

Sheng‐Song Yu,

Xiao‐Xuan Shu

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: May 5, 2025

Abstract Electrochemical biomass conversion offers a promising approach for organic synthesis and upgrading. Iron‐based catalyst hold considerable promise in this domain, however, challenges related to stability under electrocatalytic conditions limit their broader application. In work, an iron‐based integrated foam (FeO x /Fe‐IF) electrode fabricated via thermal treatment process is presented, which generates highly active stable mixed oxide species situ. The structural composition enables FeO /Fe‐IF exhibit outstanding activity 5‐hydroxymethylfurfural (5‐HMF) electroreduction, achieving near‐complete with high selectivity toward 2,5‐dihydroxymethylfuran (DHMF). Remarkably, maintains durability 5‐HMF approaching 100% DHMF around 92% over ten successive cycles. situ spectroscopic analyses reveal that Fe 2 O 3 effectively stabilize 4 sites, ensuring sustained catalytic performance. kinetic isotope studies suggest electrochemical hydrogenation (ECH) mechanism, where adsorbed hydrogen (*H) (*HMF) interact produce DHMF. Additionally, the demonstrates adaptability across broad pH range (7–14), efficiency continuous flow‐cell synthesis, great hydrogenating other biomass‐derived chemicals, underscoring versatility of /Fe‐IF. This work provides valuable insights designing efficient electrocatalysts conversion.

Language: Английский

Interfacial water regulation for water-participating electrocatalytic hydrogenation reactions DOI
Yanmei Huang, Ying Gao, Bin Zhang

et al.

Chem, Journal Year: 2025, Volume and Issue: unknown, P. 102533 - 102533

Published: April 1, 2025

Language: Английский

Citations

0
Balancing the Activity and Stability of Iron‐Based Catalysts via Mixed Oxide Species Formation for Electrocatalytic Biomass Hydrogenation DOI
Xinyu Zhang,

Sheng‐Song Yu,

Xiao‐Xuan Shu

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: May 5, 2025

Abstract Electrochemical biomass conversion offers a promising approach for organic synthesis and upgrading. Iron‐based catalyst hold considerable promise in this domain, however, challenges related to stability under electrocatalytic conditions limit their broader application. In work, an iron‐based integrated foam (FeO x /Fe‐IF) electrode fabricated via thermal treatment process is presented, which generates highly active stable mixed oxide species situ. The structural composition enables FeO /Fe‐IF exhibit outstanding activity 5‐hydroxymethylfurfural (5‐HMF) electroreduction, achieving near‐complete with high selectivity toward 2,5‐dihydroxymethylfuran (DHMF). Remarkably, maintains durability 5‐HMF approaching 100% DHMF around 92% over ten successive cycles. situ spectroscopic analyses reveal that Fe 2 O 3 effectively stabilize 4 sites, ensuring sustained catalytic performance. kinetic isotope studies suggest electrochemical hydrogenation (ECH) mechanism, where adsorbed hydrogen (*H) (*HMF) interact produce DHMF. Additionally, the demonstrates adaptability across broad pH range (7–14), efficiency continuous flow‐cell synthesis, great hydrogenating other biomass‐derived chemicals, underscoring versatility of /Fe‐IF. This work provides valuable insights designing efficient electrocatalysts conversion.

Language: Английский

Citations

0