Emergent chiral and topological nanoarchitectonics in self-assembled supramolecular systems DOI
Han‐Xiao Wang, Xuefeng Zhu, Minghua Liu

et al.

Chemical Society Reviews, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

The fabrication of structures with designated topologies at the nanoscale is an intriguing issue, attributed to possibility both imparting unique properties functional materials and unravelling codes that lie in many natural systems. As a significant bottom-up approach, self-assembly strategy potent formulating various exquisite structures. While building common types miniaturized such as tubes, twists spheres has been investigated depth gain insight into intrinsic principles dictate their formation functions, preparation peculiar topological nanostructures still scattered unsystematic. In parallel, chirality among most ubiquitous phenomena fundamental significance nature close relationship origin life. Essentially, represents type orderliness thus may interplay orchestrated serendipitous way. this review, we describe development constructing emergent chiral nanoarchitectures via method, mainly focusing on including toroids, catenanes, Möbius strips, spirals fractals. addition, other involving toruloids/kebabs, trumpets bamboos, screws, dendritic lamellar are also exemplified. design blocks self-assembling strategies towards these target architectures highlighted effort provide overview feasible approaches facilitate tailored construction mesoscopic

Language: Английский

Emergent chiral and topological nanoarchitectonics in self-assembled supramolecular systems DOI
Han‐Xiao Wang, Xuefeng Zhu, Minghua Liu

et al.

Chemical Society Reviews, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

The fabrication of structures with designated topologies at the nanoscale is an intriguing issue, attributed to possibility both imparting unique properties functional materials and unravelling codes that lie in many natural systems. As a significant bottom-up approach, self-assembly strategy potent formulating various exquisite structures. While building common types miniaturized such as tubes, twists spheres has been investigated depth gain insight into intrinsic principles dictate their formation functions, preparation peculiar topological nanostructures still scattered unsystematic. In parallel, chirality among most ubiquitous phenomena fundamental significance nature close relationship origin life. Essentially, represents type orderliness thus may interplay orchestrated serendipitous way. this review, we describe development constructing emergent chiral nanoarchitectures via method, mainly focusing on including toroids, catenanes, Möbius strips, spirals fractals. addition, other involving toruloids/kebabs, trumpets bamboos, screws, dendritic lamellar are also exemplified. design blocks self-assembling strategies towards these target architectures highlighted effort provide overview feasible approaches facilitate tailored construction mesoscopic

Language: Английский

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