Electrocatalytic Production of a Liquid Organic Hydrogen Carrier with Anodic Valorization of the Process: Review and Outlook DOI Creative Commons
Jiaqi Wang, Yongdan Li,

Christin Hummel

et al.

Energy & Fuels, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 25, 2024

Green hydrogen plays a crucial role in decarbonization and the future of low-carbon society. Still, its transport/distribution cost production, mainly realized by electrolysis, are major hurdles. Liquid H2 carriers reduce costs but add further expenses for their production. To address this challenge, we proposed novel strategy electrocatalytic production liquid organic carrier with anodic valorization process. This review summarizes state art outlooks new concept. The process is briefly introduced, main components discussed. Subsequently, oxidation from to processes, together paired processes reactors, analyzed, highlighting challenges prospects.

Language: Английский

Harnessing the Potential of UU 200/Bi4O8 Nanocomposite to Optimize Energy Efficiency in Supercapacitor and Electrocatalysis Application DOI

S. Sarmila,

S. Vadivel,

P. Sujita

et al.

Applied Organometallic Chemistry, Journal Year: 2025, Volume and Issue: 39(1)

Published: Jan. 1, 2025

ABSTRACT In the pursuit of sustainable energy solutions, spotlight shines on advancement effective storage systems and green hydrogen production. this work, UU 200 (UU: Uppsala University) metal–organic framework (MOF)/bismuth oxide (Bi 4 O 8 ), termed 200/Bi nanocomposite, has been synthesized utilized as an electrode material for supercapacitor applications electrocatalyst evolution reaction (HER). XRD, Raman, FT‐IR, XPS tests showed that nanocomposite was successfully formed. The SEM TEM images revealed exhibits a mixed rod spherical structure. performance pure examined through cyclic voltammetry (CV), galvanostatic charge–discharge (GCD), electrochemical impedance (EIS) measurements. Interestingly, delivered maximum specific capacitance value 220 F g −1 at 1 A . Furthermore, potential extended beyond its capability to electrocatalytic HER process. performances were assessed linear sweep (LSV), CV, chronoamperometry (CA), EIS analysis. overpotential (ɳ) 130 mV Tafel slope 131 dec indicate supremacy in advanced applications. excellent water‐splitting performance, allowing it acquire future needs.

Language: Английский

Citations

1
Palladium Married with MBene Multilayers: Enabling Intensified Hydrogen Spillover for Efficient Nitrite‐to‐Ammonia Electroreduction DOI
Jiayi Zhang, Qiaoshi Zeng, Xinzhi Wang

et al.

Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 8, 2025

Abstract Electrochemical nitrite reduction reaction (NO 2 RR) has emerged as a promising alternative approach for ammonia (NH 3 ) production, offering both energy efficiency and environmental sustainability. The rational regulation of active hydrogen (*H) is pivotal NO − ‐to‐NH conversion, yet it remains significant challenge in the context RR. In this study, molybdenum boride (MBene) multilayers are introduced an electronic support to integrate with palladium (Pd) nanoparticles, creating dual catalytic sites that effectively balance adsorption *H *NO , thereby enabling synergistic catalysis Theoretical experimental analyses revealed efficiently generated on Pd subsequently undergoes spillover ‐adsorbed MBene surfaces, facilitating accelerated hydrogenation NH synthesis. Consequently, Pd/MBene catalyst demonstrated exceptional performance, achieving high Faradaic 89%, yield rate 16.9 mg h −1 cat remarkable cycling stability at low applied potential ‐0.3 V versus RHE. Motivated by outstanding RR further utilized cathode construct Zn‐nitrite formaldehyde‐nitrite batteries. These systems functionality simultaneous production electricity generation, highlighting versatile efficient sustainable conversion.

Language: Английский

Citations

0
Electricity-driven organic hydrogenation using water as the hydrogen source DOI Creative Commons
Bidyut Kumar Kundu, Yujie Sun

Chemical Science, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

Employing water as a hydrogen source is an attractive and sustainable option in electricity-driven organic hydrogenation, which can overcome the drawbacks associated with traditional sources like H 2 .

Language: Английский

Citations

3
Progress and perspectives on electrocatalytic transmembrane hydrogenation DOI
Xianlong Zhou,

Xi Yu,

Bo You

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(32), P. 20527 - 20541

Published: Jan. 1, 2024

This review summarizes the developments of Pd membrane reactors to drive electrochemical hydrogenation unsaturated compounds including gaseous reagents. It highlights design Pd-based catalysts and their utilization hydrogenation.

Language: Английский

Citations

1
Experimental and theoretical validation for transmutation of palladium at electrochemical interfaces DOI Creative Commons
Trilochan Gadly, S. Phapale,

Sunita Gamre

et al.

Scientific Reports, Journal Year: 2024, Volume and Issue: 14(1)

Published: Sept. 11, 2024

Language: Английский

Citations

1
Advances in Palladium-Based Membrane Research: High-Throughput Techniques and Machine Learning Perspectives DOI Open Access

Eric Kolor,

Muhammad Usman, Sasipa Boonyubol

et al.

Processes, Journal Year: 2024, Volume and Issue: 12(12), P. 2855 - 2855

Published: Dec. 12, 2024

The separation of high-purity hydrogen from mixed gasses using dense metallic alloy membranes is essential for advancing a hydrogen-based economy. Palladium-based exhibit outstanding catalytic activity and theoretically infinite selectivity, but their high cost limited performance in contaminant-rich environments restrict widespread use. This study addresses these limitations by exploring strategies to develop cost-effective, high-performance alternatives. Key challenges include the vast compositional design space, lack systematic principles, slow pace traditional material development. review emphasizes potential high-throughput combinatorial techniques, such as composition-spread films statistical experiments (DoE), combined with machine learning materials informatics, accelerate discovery, optimization, characterization palladium-based membranes. These approaches reduce development time costs while improving efficiency. Focusing on critical properties surface activity, resistance chemical physical stresses, incorporation low-cost base metals, this introduces domain-specific descriptors address data scarcity improve screening. By integrating computational experimental methods, future research can identify hidden correlations expedite rational next-generation

Language: Английский

Citations

1
Development of a highly efficient electrocatalytic hydrogenation and dehalogenation system using a flow cell with a Pd tube cathode DOI

Hiroaki Tajima,

Hideki Ishii, Shinsuke Inagi

et al.

Green Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

A novel flow and circulation electrolytic system has been developed for the highly efficient cathodic hydrogenation of unsaturated compounds dehalogenation various aromatic halides.

Language: Английский

Citations

0
Electrocatalytic Production of a Liquid Organic Hydrogen Carrier with Anodic Valorization of the Process: Review and Outlook DOI Creative Commons
Jiaqi Wang, Yongdan Li,

Christin Hummel

et al.

Energy & Fuels, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 25, 2024

Green hydrogen plays a crucial role in decarbonization and the future of low-carbon society. Still, its transport/distribution cost production, mainly realized by electrolysis, are major hurdles. Liquid H2 carriers reduce costs but add further expenses for their production. To address this challenge, we proposed novel strategy electrocatalytic production liquid organic carrier with anodic valorization process. This review summarizes state art outlooks new concept. The process is briefly introduced, main components discussed. Subsequently, oxidation from to processes, together paired processes reactors, analyzed, highlighting challenges prospects.

Language: Английский

Citations

0