Cerium(iii) yldiide complexes with divergent CO reactivity DOI Creative Commons
Alexander J. Gremillion, Hemant Kumar, Iker Del Rosal

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: 61(4), P. 752 - 755

Published: Dec. 12, 2024

Synthesis of cerium yldiide complexes and their reactivity with CO is demonstrated.

Language: Английский

A Lead(II) Substituted Triplet Carbene DOI Creative Commons
Fabian Dankert,

Julian Messelberger,

Abinash Swain

et al.

Published: July 26, 2024

Reaction of the pincer-type ligand L3 supported complex [L3PbBr][BArF24] (1) with Li[(C(=N2)TMS)] furnishes [L3Pb(C(=N2)TMS)][BArF24] (2). Diazo-compound 2 eliminates dinitrogen upon irradiation affording formal plumba-alkyne 3, which persists in cold fluoroarene solutions. Variable temperature UV/Vis and NMR spectroscopies combination quantum-chemical calculations identify 3 as a metal-substituted triplet carbene. In-crystallo [L3Pb(C(=N2)TMS)(tol)][BArF24] (2∙tol) provides snapshot intermolecular C–H bond insertion toluene (4).

Language: Английский

Citations

0
Cerium(iii) yldiide complexes with divergent CO reactivity DOI Creative Commons
Alexander J. Gremillion, Hemant Kumar, Iker Del Rosal

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: 61(4), P. 752 - 755

Published: Dec. 12, 2024

Synthesis of cerium yldiide complexes and their reactivity with CO is demonstrated.

Language: Английский

Citations

0