Cited by Reaction Engineering of the Hydrogenolysis of Liquid n-Alkanes: Comparison of Flow and Batch Reaction Systems

Selective Upcycling of Polyolefins into High-Value Nitrogenated Chemicals DOI

Binzhi Zhao,

Zhibin Hu,

Yichen Sun

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 6, 2024

The selective upcycling of polyolefins to create products increased value has emerged as an innovative approach carbon resource stewardship, drawing significant scientific and industrial interest. Although recent advancements in recycling technology have facilitated the direct conversion hydrocarbons or oxygenated compounds, synthesis nitrogenated compounds from such waste not yet been disclosed. Herein, we demonstrate a novel for by efficiently transforming range postconsumer plastic into nitriles amides. This process leverages catalytic properties manganese dioxide combination with inexpensive nitrogen source, urea, make it both practical economically viable. Our only opens new avenues creation chemicals polyolefin but also underscores critical importance valorizing resources originally derived fossil fuels. study provides strategy sustainable polyolefins.

Language: Английский

Citations

Advanced Catalysts for the Chemical Recycling of Plastic Waste DOI

Jibo Qin,

Feiyan Wu, Yibo Dou

et al.

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 2, 2025

Abstract Plastic products bring convenience to various aspects of the daily lives due their lightweight, durability and versatility, but massive accumulation post‐consumer plastic waste is posing significant environmental challenges. Catalytic methods can effectively convert into value‐added feedstocks, with catalysts playing an important role in regulating yield selectivity products. This review explores latest advancements advanced applied thermal catalysis, microwave‐assisted photocatalysis, electrocatalysis, enzymatic catalysis reaction systems for chemical recycling valuable feedstocks. Specifically, pathways mechanisms involved plastics process are analyzed presented, strengths weaknesses employed across different described. In addition, structure‐function relationship these discussed. Herein, it provided insights design novel outline challenges future opportunities terms developing tackle “white pollution” crisis.

Language: Английский

Citations

Scalable Synthesis of Degradable Copolymers Containing α-Lipoic Acid via Miniemulsion Polymerization DOI

Parker T. Morris,

Kodai Watanabe,

Kaitlin R. Albanese

et al.

Journal of the American Chemical Society, Journal Year: 2024, Volume and Issue: 146(44), P. 30662 - 30667

Published: Oct. 28, 2024

A robust method is described to synthesize degradable copolymers under aqueous miniemulsion conditions using α-lipoic acid as a cheap and scalable building block. Simple formulations of (up 10 mol %),

Language: Английский

Citations

Preparation of peroxide initiator monomer containing degradable disulphide bond DOI

Fang Jiang,

Fang-Jung Huang,

Hongjun Yang

et al.

Materials Research Innovations, Journal Year: 2025, Volume and Issue: unknown, P. 1 - 5

Published: Feb. 27, 2025

A functional initiator monomer containing lipoic acid ester both with degradable disulphide bond and peroxide was designed synthesised. Here, the precursors are tert-butyl (isopropylbenzene) hydroperoxide, while dichloromethane (tetrahydrofuran) used as a solvent 4-dimethylaminopyridine (DMAP) N, N'-dicyclohexylcarbodiimide (DCC) were condensation agents. The structure purity of characterised by proton nuclear magnetic resonance (1H-NMR) high-performance liquid chromatography (HPLC). prepared is high over 90%. precursor material low-cost widely available, does not require special methods to purify product, which means it can be directly in synthesis vinyl polymers. Therefore, provides great application prospects for green environmentally friendly materials.

Language: Английский

Citations

Hydrogenolysis of Polyethylene by Metal–Organic Framework Confined Single-Site Ruthenium Catalysts DOI

Manav Chauhan,

Chhaya Thadhani,

Bharti Rana

et al.

Chemistry of Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 23, 2024

Language: Английский

Citations

High Molecular Weight Biobased Long-Chain Aliphatic Polyesters with Degradability: Insights into Mimicking Polyethylene DOI

Nagarjuna A. Mahadas,

Amir Suhail,

Martin Taylor Sobczak

et al.

Macromolecules, Journal Year: 2025, Volume and Issue: unknown

Published: April 6, 2025

Language: Английский

Citations

Synergistic Catalysis for Recycling and Upcycling of Plastics DOI

Hongshun Ran,

Xinyang Sun, Mengying Zheng

et al.

ACS Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 8551 - 8585

Published: May 7, 2025

Language: Английский

Citations

Chemical Innovations in Polymer Upcycling: Beyond Traditional Recycling DOI

Abhay Nanda Srivastva,

N. P. Saxena

Advances in sustainability science and technology, Journal Year: 2024, Volume and Issue: unknown, P. 171 - 183

Published: Dec. 18, 2024

Language: Английский

Citations

Heterogeneous catalysis strategies for polyolefin plastic upcycling: co-reactant-assisted and direct transformation under mild conditions DOI

Haokun Wang,

Sijie Huang,

Shik Chi Edman Tsang

et al.

Chemical Communications, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 18, 2024

Overview of polyolefin (PO) plastic upcycling under mild conditions, utilizing diverse co-reactants to produce distinct product distributions.

Language: Английский

Citations

Reaction Engineering of the Hydrogenolysis of Liquid n-Alkanes: Comparison of Flow and Batch Reaction Systems DOI

Zhuoming Feng, Siwon Lee, Raymond J. Gorte

et al.

Chemical Engineering Journal Advances, Journal Year: 2024, Volume and Issue: 21, P. 100701 - 100701

Published: Dec. 28, 2024

Language: Английский

Citations