Whole-Process Precision Chemistry for Clusters DOI Creative Commons
Jianping Xie

Precision Chemistry, Journal Year: 2024, Volume and Issue: 2(11), P. 559 - 562

Published: Oct. 30, 2024

Language: Английский

Surface decorated metal carbonyl clusters: bridging organometallic molecular clusters and atomically precise ligated nanoclusters DOI Creative Commons
Cristiana Cesari, Cristina Femoni, Francesca Forti

et al.

Dalton Transactions, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 1, 2025

In this Frontier Article, the work carried out within our research group in Bologna field of surface decorated metal carbonyl clusters will be outlined and put a...

Language: Английский

Citations

1
Structural Changes in Atomically Precise Ag29 Nanoclusters upon Sequential Attachment and Detachment of Secondary Ligands DOI

Jayoti Roy,

A. Das, Arijit Jana

et al.

ACS Nano, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 28, 2025

Elucidating the structural dynamics of ligand-stabilized noble metal nanoclusters (NCs) is critical for understanding their properties and developing applications. Ligand rearrangement at NC surfaces an important contributor to change. In this study, we investigate dynamic behavior ligand-protected [Ag29(L)12]3- NC's (L = 1,3-benzenedithiol) interacting with secondary ligand 2,2'-[1,4-phenylenebis (methylidynenitrilo)] bis[benzenethiol] (referred as L'). We specifically focus on characteristics NC-based adducts [Ag29(L)12]L'n3- where n ranges from 1 4. This probed experimentally by using a combination ultraviolet-visible (UV-vis) spectroscopy, high-resolution electrospray ionization mass spectrometry (ESI MS), ion mobility (IM MS) coupled collision-induced dissociation (MS2 IMS). Density functional theory (DFT) calculations infer comparatively weak noncovalent interactions between NCs attached ligands consistent fragmentation determined collision cross-sections (CCSs), which show monotonic CCS increase increasing number L' (n 1-4). From detailed analysis predicted structures, progressive expansion Ag-S staple framework precursor are added. Interestingly, detachment gas-phase collisional heating yields structures retain "footprints" detached millisecond time scale.

Language: Английский

Citations

0
Electro-Fenton Degradation of Rhodamine B with in-situ H2O2 Generation by Au Nanoparticles Modified Reduced Graphene Oxide DOI
Tian Wang, Wei Wang, Yunqing Zhu

et al.

Journal of environmental chemical engineering, Journal Year: 2025, Volume and Issue: unknown, P. 115685 - 115685

Published: Feb. 1, 2025

Language: Английский

Citations

0
Gold clusters: A promising NIR-II probe for bioimaging and biosensing DOI
Jiaqi Sun,

Wanyu Cheng,

Xu Liu

et al.

Coordination Chemistry Reviews, Journal Year: 2025, Volume and Issue: 533, P. 216544 - 216544

Published: Feb. 24, 2025

Language: Английский

Citations

0
Halide‐Directed Ligand Engineering Enables Expedient, Controlled and Divergent Syntheses of Diphosphine‐Protected Au Nanoclusters DOI Open Access
Ying‐Zhou Li,

ZHANZHUANG LIU,

Wenyan Liu

et al.

Small, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 25, 2025

Despite substantial progress in ligand engineering, the efforts field of Au nanoclusters have been concentrated almost exclusively on organic ligands. Halides, most typical auxiliary inorganic ligands widely present clusters, remain virtually unexplored, particularly regarding their effects cluster construction. Herein, diphosphine Ph2P(CH2)nPPh2 (Ln, n = 1-6) is chosen as co-protecting and a comparative analysis influential roles halide ions (Cl-, Br-, I-) guiding synthesis conducted. A simple yet efficient halide-directed synthetic approach has developed series nanoclusters, including known [Au18(L1)6Br4]2+, [Au13(L2)5Cl2]3+ [Au8(L3)4Cl2]2+ that however crystallized new polymorphic forms, well reduction-active [Au18(L1)6Cl4]2+, luminescence-enhanced [Au14(L3)5Br4]2+ core-isomeric [Au11(Ln)4X2]+ (n 4-6; X Cl, Br, I), are obtained more expedient controllable manner. This work clearly demonstrates non-negligible directing synthesis, provides an easier access to diverse diphosphine-protected nanoclusters. approach, promising gram-scale expected further extend scope holds promise for advancing diversified syntheses broader range ligand-protected metal

Language: Английский

Citations

0
Solvent-regulated Synthesis of Copper Nanocluster Assemblies and Its Application in Light-emitting Diodes DOI
Taiqun Yang, Cheng Ye, Shen Zhou

et al.

Acta Chimica Sinica, Journal Year: 2025, Volume and Issue: 83(2), P. 87 - 87

Published: Jan. 1, 2025

Language: Английский

Citations

0
Recent advances in fluorescent nanomaterials designed for biomarker detection and imaging DOI Creative Commons
Xuming Sun, Tong Xiang,

Linyan Xie

et al.

Materials Today Bio, Journal Year: 2025, Volume and Issue: unknown, P. 101763 - 101763

Published: April 1, 2025

Language: Английский

Citations

0
Atomically Precise Fcc-Amorphous Homometal Heterojunction with ∼1 nm Size DOI Creative Commons

Shengli Zhuang,

Dong Chen, Pu Wang

et al.

Precision Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: April 29, 2025

Language: Английский

Citations

0
Whole-Process Precision Chemistry for Clusters DOI Creative Commons
Jianping Xie

Precision Chemistry, Journal Year: 2024, Volume and Issue: 2(11), P. 559 - 562

Published: Oct. 30, 2024

Language: Английский

Citations

0