Abstract
Black
carbon
aerosols
absorb
radiation
and
their
absorptive
strength
is
influenced
by
particle
mixing
structures
coating
compositions.
Liquid-liquid
phase
separation
can
move
black
to
organic
coatings
which
affects
capacity,
but
it
unclear
conditions
favour
this
redistribution.
Here
we
combine
field
observations,
laboratory
experiments,
transmission
electron
microscopy
demonstrate
that
liquid-liquid
redistributes
from
inorganic
cores
under
a
wide
range
of
relative
humidity.
We
find
the
ratio
thickness
size
influences
When
lower
than
0.12,
over
90%
inside
salt
cores.
However,
when
exceeds
0.24,
most
redistributed
coatings,
due
change
in
its
affinity
for
phases.
Using
an
optical
calculation
model,
estimate
redistribution
reduces
absorption
enhancement
effect
28–34%.
suggest
climate
models
assuming
core-shell
structure
probably
overestimate
radiative
approximately
18%.
Environmental Science & Technology,
Journal Year:
2020,
Volume and Issue:
55(1), P. 44 - 64
Published: Dec. 18, 2020
The
global
expansion
of
harmful
cyanobacterial
blooms
(CyanoHABs)
poses
an
increasing
threat
to
public
health.
CyanoHABs
are
characterized
by
the
production
toxic
metabolites
known
as
cyanotoxins.
Human
exposure
cyanotoxins
is
challenging
forecast,
and
perhaps
least
understood
route
via
inhalation.
While
aerosolization
toxins
from
marine
algal
(HABs)
has
been
well
documented,
in
freshwater
systems
remains
understudied.
In
recent
years,
spray
aerosol
(SA)
produced
airshed
Laurentian
Great
Lakes
(United
States
Canada)
characterized,
suggesting
that
may
impact
atmospheric
loading
more
than
previously
understood.
Therefore,
further
investigation
regarding
on
human
respiratory
health
warranted.
This
review
examines
current
research
incorporation
cells
into
SA
aquatic
ecosystems
which
experience
HABs.
We
present
overview
cyanotoxin
fate
environment,
biological
SA,
existing
data
relevant
collection
methods,
adverse
outcomes
associated
with
npj Climate and Atmospheric Science,
Journal Year:
2020,
Volume and Issue:
3(1)
Published: Oct. 21, 2020
Abstract
Light-absorbing
carbonaceous
aerosols
(LACs),
including
black
carbon
and
light-absorbing
organic
(brown
carbon,
BrC),
have
an
important
role
in
the
Earth
system
via
heating
atmosphere,
dimming
surface,
modifying
dynamics,
reducing
snow/ice
albedo,
exerting
positive
radiative
forcing.
The
lifecycle
of
LACs,
from
emission
to
atmospheric
evolution
further
deposition,
is
key
their
overall
climate
impacts
uncertainties
determining
hygroscopic
optical
properties,
burden,
interactions
with
clouds,
deposition
on
snowpack.
At
present,
direct
observations
constraining
some
processes
during
LACs
(e.g.,
between
hydrometeors)
are
rather
limited.
Large
inconsistencies
directly
measured
LAC
properties
those
used
for
model
evaluations
also
exist.
Modern
models
starting
incorporate
detailed
aerosol
microphysics
evaluate
transformation
rates
water
solubility,
chemical
composition,
phases
which
shown
improved
performance.
However,
process-level
understanding
modeling
still
poor
particularly
BrC,
yet
be
sufficiently
assessed
due
lack
global-scale
measurements.
Appropriate
treatments
size-
composition-resolved
that
influence
both
aerosol–cloud
expected
advance
quantification
light
absorption
system.
This
review
summarizes
recent
advances
up-to-date
knowledge
highlighting
essential
issues
where
measurements
need
improvement.
Proceedings of the National Academy of Sciences,
Journal Year:
2021,
Volume and Issue:
118(16)
Published: April 15, 2021
Significance
Aerosol
particles
are
ubiquitous
in
the
atmosphere
and
play
an
important
role
air
quality
climate
system.
These
can
contain
mixtures
of
primary
organic
aerosol,
secondary
inorganic
aerosol.
We
show
that
such
internally
mixed
three
liquid
phases.
also
demonstrate
presence
phases
impacts
time
needed
for
to
reach
equilibrium
with
surrounding
gas
phase
likely
ability
activate
into
cloud
droplets.
A
framework
is
presented
predicting
conditions
formation
atmosphere.
results
will
lead
improved
representations
aerosols
models
predictions.
Tellus B,
Journal Year:
2022,
Volume and Issue:
74(1), P. 24 - 24
Published: March 25, 2022
This
review
presents
how
the
boreal
and
tropical
forests
affect
atmosphere,
its
chemical
composition,
function,
further
that
affects
climate
and,
in
return,
ecosystems
through
feedback
processes.
Observations
from
key
tower
sites
standing
out
due
to
their
long-term
comprehensive
observations:
The
Amazon
Tall
Tower
Observatory
Central
Amazonia,
Zotino
Siberia,
Station
Measure
Ecosystem-Atmosphere
Relations
at
Hyytiäla
Finland.
is
complemented
by
short-term
observations
networks
large
experiments.
discusses
atmospheric
chemistry
observations,
aerosol
formation
processing,
physiochemical
aerosol,
cloud
condensation
nuclei
properties
finds
surprising
similarities
important
differences
two
ecosystems.
concentrations
are
similar,
particularly
concerning
main
components,
both
dominated
an
organic
fraction,
while
ecosystem
has
generally
higher
of
inorganics,
influence
long-range
transported
air
pollution.
emissions
biogenic
volatile
compounds
isoprene
monoterpene
regions,
respectively,
being
precursors
fraction.
modeling
studies
show
change
deforestation
such
carbon
hydrological
cycles
Amazonia
changing
neutrality
precipitation
downwind.
In
Africa,
so
far
maintaining
sink.
It
urgent
better
understand
interaction
between
these
major
ecosystems,
climate,
which
calls
for
more
observation
sites,
providing
data
on
water,
carbon,
other
biogeochemical
cycles.
essential
finding
a
sustainable
balance
forest
preservation
reforestation
versus
potential
increase
food
production
biofuels,
critical
services
global
stability.
Reducing
warming
vital
forests.
Reviews of Geophysics,
Journal Year:
2022,
Volume and Issue:
60(2)
Published: April 21, 2022
Abstract
Atmospheric
ice‐nucleating
particles
(INPs)
play
a
critical
role
in
cloud
freezing
processes,
with
important
implications
for
precipitation
formation
and
radiative
properties,
thus
weather
climate.
Additionally,
INP
emissions
respond
to
changes
the
Earth
System
climate,
example,
desertification,
agricultural
practices,
fires,
therefore
may
introduce
climate
feedbacks
that
are
still
poorly
understood.
As
knowledge
of
nature
origins
INPs
has
advanced,
regional
global
weather,
system
models
have
increasingly
begun
link
ice
processes
model‐simulated
aerosol
abundance
types.
While
these
recent
advances
exciting,
coupling
simulated
also
makes
physics
simulations
susceptible
uncertainties
simulation
INPs,
which
constrained
by
observations.
Advancing
predictability
reasonable
spatiotemporal
resolution
will
require
an
increased
focus
on
research
bridges
measurement
modeling
communities.
This
review
summarizes
current
state
identifies
gaps
from
both
observational
perspectives.
In
particular,
we
emphasize
needs
two
key
areas:
(a)
closure
between
quantities
(b)
skillful
within
existing
models.
We
discuss
various
particle
types
briefly
challenges
faced
understanding
impacts
present‐day
Finally,
identify
priority
directions
observations
improve
their
interactions
System.
Reviews of Modern Physics,
Journal Year:
2023,
Volume and Issue:
95(4)
Published: Oct. 12, 2023
The
pandemic
of
coronavirus
disease
2019
has
led
to
a
renewed
focus
on
the
physicochemical
properties
droplets
and
aerosol
particles
that
are
exhaled
during
breathing,
speaking,
singing,
coughing,
sneezing.
In
this
article,
respiratory
particles,
including
their
number
concentrations
size
distributions,
as
well
formation
mechanisms
at
different
sites
in
system,
reviewed.
data
literature
synthesized
via
parametrization
particle
distribution
using
log-normal
modes
related
origin
sites.
Environmental Science Processes & Impacts,
Journal Year:
2022,
Volume and Issue:
25(2), P. 133 - 150
Published: April 7, 2022
Per-
and
polyfluoroalkyl
substances
(PFAS)
are
persistent
organic
pollutants
of
concern
to
human
health.
These
synthetic
chemicals
in
widespread
use
for
consumer
products,
firefighting
foams,
industrial
applications.
They
have
been
detected
all
over
the
globe,
including
at
remote
locations
distant
from
any
possible
point
sources.
One
mechanism
long-range
transport
PFAS
is
through
sorption
aerosol
particles
atmosphere.
can
be
transferred
sea
surface
spray
wave
breaking
bubble
bursting,
emitted
atmosphere
gas
phase
sorb
particulate
matter
gas-particle
partitioning.
Here
we
present
a
comprehensive
review
global
measurements
on
ambient
dating
back
first
reports
early
2000s.
We
summarize
findings
historically
important
C8
species,
perfluorooctanoic
acid
(PFOA)
perfluorooctane
sulfonic
(PFOS),
detection
isomers
size-segregated
measurements,
as
well
studies
newer
emerging
PFAS.
conclude
that
long-term
monitoring
should
expanded
include
more
measurement
sites
under-sampled
regions
world
further
non-targeted
work
identify
novel
structures
needed
manufacturing
regulations
continue
evolve.
International Journal of Molecular Sciences,
Journal Year:
2023,
Volume and Issue:
24(5), P. 4345 - 4345
Published: Feb. 22, 2023
The
leading
mechanisms
through
which
air
pollutants
exert
their
damaging
effects
are
the
promotion
of
oxidative
stress,
induction
an
inflammatory
response,
and
deregulation
immune
system
by
reducing
its
ability
to
limit
infectious
agents'
spreading.
This
influence
starts
in
prenatal
age
continues
during
childhood,
most
susceptible
period
life,
due
a
lower
efficiency
damage
detoxification,
higher
metabolic
breathing
rate,
enhanced
oxygen
consumption
per
unit
body
mass.
Air
pollution
is
involved
acute
disorders
like
asthma
exacerbations
upper
respiratory
infections,
including
bronchiolitis,
tuberculosis,
pneumoniae.
Pollutants
can
also
contribute
onset
chronic
asthma,
they
lead
deficit
lung
function
growth,
long-term
damage,
eventually
illness.
abatement
policies,
applied
last
decades,
contributing
mitigating
quality
issues,
but
more
efforts
should
be
encouraged
improve
childhood
disease
with
possible
positive
on
function.
narrative
review
aims
summarize
recent
studies
links
between
npj Climate and Atmospheric Science,
Journal Year:
2024,
Volume and Issue:
7(1)
Published: March 8, 2024
Abstract
Atmospheric
soot
and
organic
particles
from
fossil
fuel
combustion
biomass
burning
modify
Earth’s
climate
through
their
interactions
with
solar
radiation
modifications
of
cloud
properties
by
acting
as
condensation
nuclei
ice
nucleating
particles.
Recent
advancements
in
understanding
individual
microscopic
composition
have
led
to
heightened
interest
microphysical
properties.
This
review
article
provides
an
overview
current
advanced
measurements
offers
insights
into
future
avenues
for
studying
these
To
quantify
morphology
ageing,
fractal
dimension
(
D
f
)
is
a
commonly
employed
quantitative
metric
which
allows
characterize
morphologies
aggregates
relation
ageing
factors
like
internal
mixing
state,
core-shell
structures,
phase,
heterogeneity.
Models
been
developed
incorporate
diversity
metrics
aged
particles,
enabling
assessment
optical
absorption
radiative
forcing
effects.
The
are
complex
they
influenced
particle
sources,
process,
meteorological
conditions.
Furthermore,
soluble
exhibit
diverse
forms
can
engage
liquid–liquid
phase
separation
sulfate
nitrate
components.
Primary
carbonaceous
such
tar
balls
warrant
further
attention
due
strong
light
absorbing
properties,
presence
toxic
constituents,
small
size,
impact
human
health.
Future
research
needs
include
both
atmospheric
modeling
approaches,
focusing
on
changes
the
structures
ensembles,
effects
dynamics