Stable
isotopes
(δ18O)
and
tritium
(3H)
are
frequently
used
as
tracers
in
environmental
sciences
to
estimate
the
age
distributions
of
water.
However,
it
has
previously
been
argued
that
seasonally
variable
tracers,
such
δ18O,
generally
systematically
fail
detect
tails
water
therefore
substantially
underestimate
ages
compared
radioactive
3H.
In
this
study
for
Neckar
river
basin
central
Europe
based
on
a
>20-year
record
hydrological,
3H
data,
we
scrutinized
above
postulate
together
with
potential
role
spatial
aggregation
effects
exacerbate
underestimation
ages.
This
was
done
by
comparing
inferred
from
δ18O
total
12
different
model
implementations,
including
lumped
parameter
sine-wave
(SW)
convolution
integral
models
(CO)
well
integrated
hydrological
combination
SAS-functions
(IM-SAS).
We
found
that,
indeed,
commonly
SW
CO
mean
transit
times
(MTT)
~
1–2
years
lower
than
those
obtained
same
models,
reaching
MTTs
10
years.
contrast,
several
implementations
IM-SAS
did
not
only
allow
simultaneous
representations
stream
flow
signals,
but
these
were
16
much
higher
similar
3H,
which
suggested
15
Characterized
posterior
distributions,
particular
parameters
control
age,
individually
constrained
or
observations,
exhibited
limited
differences
magnitudes
parts
temporal
variability
TTDs
response
changing
wetness
conditions.
suggests
both
lead
comparable
descriptions
how
is
routed
through
system.
These
findings
provide
evidence
allowed
us
reject
hypothesis
tracer
“cannot
see
older
about
4
years”
truncates
corresponding
leading
underestimations
Instead,
our
results
broad
equivalence
systems
characterized
at
least
15–20
The
question
degree
heterogeneity
can
further
adversely
affect
estimates
remains
unresolved
distributed
provided
inconclusive
results.
Overall,
demonstrates
reported
most
likely
result
use
other
per
se.
Rather,
be
largely
attributed
choices
approaches
complexity
considering
next
aspects.
Given
additional
vulnerability
due
potentially
other,
still
unknown
effects,
we,
therefore,
advocate
avoid
type
if
possible,
instead
adopt
SAS-based
formulations.
Water Resources Research,
Journal Year:
2022,
Volume and Issue:
58(11)
Published: Nov. 1, 2022
Abstract
Water
transit
time
is
now
a
standard
measure
in
catchment
hydrological
and
ecohydrological
research.
The
last
comprehensive
review
of
modeling
approaches
was
published
15+
years
ago.
But
since
then
the
field
has
largely
expanded
with
new
data,
theory
applications.
Here,
we
these
developments
focus
on
water‐age‐balance
data‐based
approaches.
We
discuss
compare
methods
including
StorAge‐Selection
functions,
well/partially
mixed
compartments,
water
age
tracking
through
spatially
distributed
models,
direct
estimates
from
controlled
experiments,
young
fractions,
ensemble
hydrograph
separation.
unify
some
heterogeneity
literature
that
crept
many
approaches,
an
attempt
to
clarify
key
differences
similarities
among
them.
Finally,
point
open
questions
research,
what
still
need
theory,
work,
community
practice.
Annual Review of Earth and Planetary Sciences,
Journal Year:
2023,
Volume and Issue:
51(1), P. 277 - 299
Published: Jan. 10, 2023
Landscapes
receive
water
from
precipitation
and
then
transport,
store,
mix,
release
it,
both
downward
to
streams
upward
vegetation.
How
they
do
this
shapes
floods,
droughts,
biogeochemical
cycles,
contaminant
the
health
of
terrestrial
aquatic
ecosystems.
Because
many
key
processes
occur
invisibly
in
subsurface,
our
conceptualization
them
has
often
relied
heavily
on
physical
intuition.
In
recent
decades,
however,
much
intuition
been
overthrown
by
field
observations
emerging
measurement
methods,
particularly
involving
isotopic
tracers.
Here
we
summarize
surprises
that
have
transformed
understanding
hydrological
at
scale
hillslopes
drainage
basins.
These
forced
a
shift
perspective
process
conceptualizations
are
relatively
static,
homogeneous,
linear,
stationary
ones
predominantly
dynamic,
heterogeneous,
nonlinear,
nonstationary.
▪Surprising
novel
measurements
transforming
functioning
landscapes.▪Even
during
storm
peaks,
streamflow
is
composed
mostly
stored
landscape
for
weeks,
months,
or
years.▪Streamflow
tree
uptake
originate
different
subsurface
storages
seasons’
precipitation.▪Stream
networks
dynamically
extend
retract
as
wets
dries,
stream
reaches
lose
flow
into
underlying
aquifers.
Ecohydrology,
Journal Year:
2022,
Volume and Issue:
15(3)
Published: March 16, 2022
Abstract
The
stable
isotopes
of
hydrogen
and
oxygen
in
xylem
water
are
often
used
to
investigate
tree
sources.
But
this
traditional
approach
does
not
acknowledge
the
contribution
stored
phloem
transpiration
how
may
affect
source
interpretations.
Additionally,
there
is
a
prevailing
assumption
that
no
isotope
fractionation
during
transport.
Here,
we
systematically
sampled
at
daily
subdaily
resolutions
large
lysimeter
planted
with
Salix
viminalis
.
Stem
diurnal
change
storage
rates
were
also
measured.
Our
results
show
significantly
less
enriched
heavy
than
water.
At
resolution,
observed
larger
isotopic
difference
between
refilling
under
periods
deficit.
These
findings
contrast
expectation
heavy‐isotope
due
downward
transport
leaf
signatures.
Because
previous
evidence
aquaporin
mediated
higher
osmotic
permeability
lighter
isotopologues
across
aquaporins,
propose
radial
xylem–phloem
boundary
drive
relative
depletion
their
enrichment
xylem.
Hydrology and earth system sciences,
Journal Year:
2023,
Volume and Issue:
27(16), P. 3083 - 3114
Published: Aug. 24, 2023
Abstract.
Stable
isotopes
(δ18O)
and
tritium
(3H)
are
frequently
used
as
tracers
in
environmental
sciences
to
estimate
age
distributions
of
water.
However,
it
has
previously
been
argued
that
seasonally
variable
tracers,
such
δ18O,
generally
systematically
fail
detect
the
tails
water
therefore
substantially
underestimate
ages
compared
radioactive
3H.
In
this
study
for
Neckar
River
basin
central
Europe
based
on
a
>20-year
record
hydrological,
δ18O
3H
data,
we
scrutinized
above
postulate
together
with
potential
role
spatial
aggregation
effects
exacerbating
underestimation
ages.
This
was
done
by
comparing
inferred
from
total
21
different
model
implementations,
including
time-invariant,
lumped-parameter
sine-wave
(SW)
convolution
integral
(CO)
models
well
StorAge
Selection
(SAS)-function
(P-SAS)
integrated
hydrological
combination
SAS
functions
(IM-SAS).
We
found
that,
indeed,
commonly
SW
CO
mean
transit
times
(MTTs)
∼
1–2
years
lower
than
those
obtained
same
models,
reaching
MTTs
∼10
years.
contrast,
several
implementations
P-SAS
IM-SAS
not
only
allowed
simultaneous
representations
storage
variations
streamflow
stream
signals,
but
these
were,
11–17
years,
also
much
higher
similar
3H,
which
suggested
11–13
Characterized
parameter
posterior
distributions,
particular
parameters
control
age,
individually
constrained
or
observations
exhibited
limited
differences
magnitudes
parts
temporal
variability
time
(TTDs)
response
changing
wetness
conditions.
suggests
both
lead
comparable
descriptions
how
is
routed
through
system.
These
findings
provide
evidence
us
reject
hypothesis
tracer
“cannot
see
older
about
4
years”
truncates
corresponding
leading
underestimations
Instead,
our
results
broad
equivalence
systems
characterized
at
least
15–20
The
question
degree
heterogeneity
can
further
adversely
affect
estimates
remains
unresolved
lumped
distributed
provided
inconclusive
results.
Overall,
demonstrates
reported
most
likely
result
use
other
per
se.
Rather,
largely
be
attributed
choices
approaches
complexity
considering
transient
conditions
next
aspects.
Given
additional
vulnerability
due
potentially
still
unknown
effects,
advocate
avoiding
type
if
possible
instead
adopting
SAS-based
time-variant
formulations
models.
Biogeosciences,
Journal Year:
2022,
Volume and Issue:
19(9), P. 2465 - 2485
Published: May 12, 2022
Abstract.
The
partitioning
of
water
fluxes
in
the
critical
zone
is
great
interest
due
to
implications
for
understanding
cycling
and
quantifying
availability
various
ecosystem
services.
We
used
tracer-aided
ecohydrological
model
EcH2O-iso
use
stable
isotopes
help
evaluate
water,
energy,
biomass
dynamics
at
an
intensively
monitored
study
plot
under
two
willow
trees,
a
riparian
species,
Berlin,
Germany.
Importantly,
we
assessed
value
situ
soil
plant
isotope
data
helping
quantify
xylem
sources
transit
times,
with
coupled
estimates
temporal
ages
root
uptake
water.
willows
showed
high
through
evapotranspiration,
limited
percolation
summer
precipitation
deeper
layers
dominance
shallow
(>80
%
upper
10
cm,
70
%–78
transpiration/evapotranspiration).
Lower
evapotranspiration
grass
(52
%–55
transpiration/evapotranspiration)
resulted
higher
moisture
storage,
greater
evaporation,
more
Biomass
allocation
was
predominantly
foliage
growth
(57
78
willow).
Shallow
age
estimated
be
similar
(15–17
d).
Considering
potential
times
substantial
improvement
model's
capability
simulate
isotopic
composition
demonstrates
using
aid
modelling.
Root
predominately
derived
from
events
(56
%)
had
average
35
d,
transport
taking
least
6.2–8.1
d.
By
evaluating
mass
balances
along
partitioning,
energy
budgets,
allocation,
proved
useful
tool
assessing
within
resolution,
particularly
transport,
which
are
all
necessary
short-
long-term
assessment
growth.
Water Resources Research,
Journal Year:
2023,
Volume and Issue:
59(3)
Published: Feb. 17, 2023
Abstract
Reduction‐oxidation
cycles
measured
through
soil
redox
potential
(
E
h
)
are
associated
with
dynamic
microbial
activity.
Understanding
changes
in
the
composition
of,
and
resource
use
by,
communities
requires
predictability
under
shifting
hydrologic
drivers.
Here,
50‐cm
column
installations
manipulated
to
vary
geochemical
conditions,
extensively
monitored
by
a
dense
instrumental
deployment
record
depth‐time
variation
of
physical
biogeochemical
conditions.
We
contrast
measurements
,
saturation
key
compounds
water
samples
(probing
majority
metabolisms)
computations
relevant
state
variables,
investigate
interplay
between
moisture
dynamics.
Our
results
highlight
importance
joint
spatially
resolved
flow/transport
processes,
worth
contrasting
experiments
for
sufficient
understanding
dynamics,
minimum
amount
biogeochemistry
needed
characterize
dynamics
electron
donors/acceptors
that
responsible
patterns
not
directly
explained
oxic/anoxic
transitions.
As
an
example,
concentrations
sulfate,
ammonium
iron
II
suggest
coexistence
both
oxic
anoxic
find
local
velocity
(a
threshold
value
time
derivative
saturation)
exerts
significant
hysteretic
control
on
oxygen
intrusion
cycling
potentials,
approaches
using
single
level
as
determinant
findings
improve
our
ability
target
how
where
hotspots
activity
develop
within
communities.
Water Resources Research,
Journal Year:
2023,
Volume and Issue:
59(3)
Published: Feb. 21, 2023
Abstract
Stable
isotopes
of
water
are
ideal
tracers
to
integrate
into
process‐based
models,
advancing
ecohydrological
understanding.
Current
tracer‐aided
modeling
is
mostly
conducted
in
relatively
small‐scale
catchments,
due
limited
tracer
data
availability
and
often
highly
damped
stream
isotope
signals
larger
catchments
(>100
km
2
).
Recent
model
developments
have
prioritized
better
spatial
representation,
offering
new
potential
for
upscaling
modeling.
Here,
we
adapted
the
fully
distributed
EcH
O‐iso
Selke
catchment
(456
,
Germany),
incorporating
monthly
sampled
from
seven
sites
between
2012
2017.
Parameter
sensitivity
analysis
indicated
that
information
content
was
generally
complementary
discharge
more
sensitive
runoff
partitioning,
soil
energy
dynamics.
Multi‐criteria
calibrations
revealed
inclusion
could
significantly
improve
performance
during
validations
simulations,
resulting
reasonable
estimates
seasonality
ages.
However,
capturing
isotopic
non‐linear
near‐surface
processes
remained
challenging
upscaled
model,
but
still
allowed
plausible
simulation
ages
reflecting
non‐stationarity
transport
mixing.
The
detailed
also
helped
unravel
spatio‐temporally
varying
patterns
storage‐flux‐age
interactions
their
interplay
under
severe
drought
conditions.
Embracing
challenges,
this
study
demonstrated
even
coarsely
can
be
value
aiding
consequent
process
representation
catchments.
derived
innovative
insights
functioning
at
scales
commensurate
with
management
decision
making,
particular
importance
guiding
science‐based
measures
tackling
environmental
changes.
Science,
Journal Year:
2025,
Volume and Issue:
387(6731), P. 290 - 296
Published: Jan. 16, 2025
Soil
water
sustains
terrestrial
life,
yet
its
fate
is
uncertain
under
a
changing
climate.
We
conducted
deuterium
labeling
experiment
to
determine
whether
elevated
atmospheric
carbon
dioxide
(CO
2
),
warming,
and
drought
impact
soil
storage
transport
in
temperate
grassland.
Elevated
CO
created
wetter
rootzone
compared
with
ambient
conditions,
whereas
warming
decreased
moisture.
remained
well
mixed
all
global
change
treatments
except
for
summer
combined
.
These
caused
the
grassland
conserve
restricted
flow
large,
rapidly
draining
pores
without
mixing
small,
slowly
pores.
Our
results
suggest
that
warmer,
more
-rich
climate
can
severely
alter
ecohydrology
by
constraining
postdrought
use.
Water Resources Research,
Journal Year:
2024,
Volume and Issue:
60(8)
Published: Aug. 1, 2024
Abstract
The
depth‐wise
distribution
of
root
water
uptake
is
typically
inferred
through
linear
mixing
models
that
utilize
knowledge
stable
isotopes
in
soil
and
plants.
However,
these
existing
often
represent
the
profile
discrete
segments,
potentially
introducing
significant
uncertainty
bias
into
results.
In
this
study,
we
introduced
a
novel
model
combines
Bayesian
framework
with
continuous
pattern,
named
CrisPy.
To
evaluate
performance
CrisPy,
conducted
virtual
field‐based
tests
under
several
types
prior
information.
CrisPy
showed
accurate
robust
reconstruction
true
various
information
settings
test.
By
contrast,
model,
MixSIAR
was
greatly
influenced
by
deviated
from
profile.
mean
squared
error
proportions
ranged
3.6%
to
7.4%,
while
exhibited
values
6.3%–15.2%.
Furthermore,
posterior
predictive
checking
indicated
effectively
reconstructed
standard
deviations
plant
isotopic
compositions
both
tests.
MixSIAR,
however,
underestimated
overestimated
deviation
compositions.
These
findings
collectively
support
enhanced
accuracy,
greater
robustness,
reduced
comparison
MixSIAR.
Therefore,
provides
powerful
tool
for
partitioning
sources.