Oriented Halide Perovskite Nanostructures and Thin Films for Optoelectronics DOI Creative Commons
Jie Chen, Yang Zhou, Yongping Fu

et al.

Chemical Reviews, Journal Year: 2021, Volume and Issue: 121(20), P. 12112 - 12180

Published: July 12, 2021

Oriented semiconductor nanostructures and thin films exhibit many advantageous properties, such as directional exciton transport, efficient charge transfer separation, optical anisotropy, hence these are highly promising for use in optoelectronics photonics. The controlled growth of structures can facilitate device integration to improve optoelectronic performance benefit in-depth fundamental studies the physical properties materials. Halide perovskites have emerged a new family cost-effective materials next-generation high-power conversion efficiency photovoltaics versatile high-performance optoelectronics, light-emitting diodes, lasers, photodetectors, high-energy radiation imaging detectors. In this Review, we summarize advances fabrication halide perovskite with dimensionality crystallographic orientation, along their applications characteristics optoelectronics. We examine methods, mechanisms, strategies several technologically relevant structures, including nanowires, nanoplates, nanostructure arrays, single-crystal films, oriented films. highlight discuss photophysical remarkable Finally, survey remaining challenges provide perspective regarding opportunities further progress field.

Language: Английский

Metal Halide Perovskite for next-generation optoelectronics: progresses and prospects DOI Creative Commons
He Dong, Chenxin Ran, Weiyin Gao

et al.

eLight, Journal Year: 2023, Volume and Issue: 3(1)

Published: Jan. 4, 2023

Abstract Metal halide perovskites (MHPs), emerging as innovative and promising semiconductor materials with prominent optoelectronic properties, has been pioneering a new era of light management (ranging from emission, absorption, modulation, to transmission) for next-generation technology. Notably, the exploration fundamental characteristics MHPs their devices is main research theme during past decade, while in next it will be primarily critical promote implantation optoelectronics. In this review, we first retrospect historical milestones devices. Thereafter, introduce origin unique features MHPs, based on which highlight tunability these via regulating phase, dimensionality, composition, geometry MHPs. Then, show that owing convenient property control various target performance can designed. At last, emphasize revolutionary applications MHPs-based existing systems. This review demonstrates key role played development modern optoelectronics, expected inspire novel directions widespread

Language: Английский

Citations

209
Advances in the Application of Perovskite Materials DOI Creative Commons
Lixiu Zhang, Luyao Mei, Kaiyang Wang

et al.

Nano-Micro Letters, Journal Year: 2023, Volume and Issue: 15(1)

Published: July 10, 2023

Nowadays, the soar of photovoltaic performance perovskite solar cells has set off a fever in study metal halide materials. The excellent optoelectronic properties and defect tolerance feature allow to be employed wide variety applications. This article provides holistic review over current progress future prospects materials representative promising applications, including traditional devices (solar cells, light-emitting diodes, photodetectors, lasers), cutting-edge technologies terms neuromorphic (artificial synapses memristors) pressure-induced emission. highlights fundamentals, remaining challenges for each application, aiming provide comprehensive overview development status navigation research devices.

Language: Английский

Citations

197
Colloidal Metal‐Halide Perovskite Nanoplatelets: Thickness‐Controlled Synthesis, Properties, and Application in Light‐Emitting Diodes DOI
Clara Otero‐Martínez, Junzhi Ye, Jooyoung Sung

et al.

Advanced Materials, Journal Year: 2021, Volume and Issue: 34(10)

Published: Nov. 14, 2021

Abstract Colloidal metal‐halide perovskite nanocrystals (MHP NCs) are gaining significant attention for a wide range of optoelectronics applications owing to their exciting properties, such as defect tolerance, near‐unity photoluminescence quantum yield, and tunable emission across the entire visible wavelength range. Although optical properties MHP NCs easily through halide composition, they suffer from light‐induced phase segregation that limits use in devices. However, MHPs can be synthesized form colloidal nanoplatelets (NPls) with monolayer (ML)‐level thickness control, exhibiting strong confinement effects, thus enabling by controlling bromide or iodide‐based lead‐halide NPls. In addition, NPls exhibit narrow peaks, have high exciton binding energies, higher fraction radiative recombination compared bulk counterparts, making them ideal candidates light‐emitting diodes (LEDs). This review discusses state‐of‐the‐art NPls: synthetic routes, thickness‐controlled synthesis both organic–inorganic hybrid all‐inorganic NPls, linear nonlinear (including charge‐carrier dynamics), performance LEDs. Furthermore, challenges associated synthesis, environmental thermal stability, application efficient LEDs discussed.

Language: Английский

Citations

183
Ion Migration in Perovskite Light‐Emitting Diodes: Mechanism, Characterizations, and Material and Device Engineering DOI
Nan Li,

Yongheng Jia,

Yuwei Guo

et al.

Advanced Materials, Journal Year: 2021, Volume and Issue: 34(19)

Published: Nov. 30, 2021

In recent years, perovskite light-emitting diodes (PeLEDs) have emerged as a promising new lighting technology with high external quantum efficiency, color purity, and wavelength tunability, well as, low-temperature processability. However, the operational stability of PeLEDs is still insufficient for their commercialization. The generation migration ionic species in metal halide perovskites has been widely acknowledged primary factor causing performance degradation PeLEDs. Herein, this topic systematically discussed by considering fundamental engineering aspects ion-related issues PeLEDs, including material processing origins ion generation, mechanisms driving migration, characterization approaches probing distributions, effects on device stability, strategies management Finally, perspectives remaining challenges future opportunities are highlighted.

Language: Английский

Citations

156
Lead‐Free Halide Perovskite Materials and Optoelectronic Devices: Progress and Prospective DOI Creative Commons
Iago López‐Fernández, Donato Valli,

Chunyun Wang

et al.

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 34(6)

Published: Oct. 27, 2023

Abstract Halide perovskites, in the form of thin films and colloidal nanocrystals, have recently taken semiconductor optoelectronics research by storm, emerged as promising candidates for high‐performance solar cells, light‐emitting diodes (LEDs), lasers, photodetectors, radiation detectors. The impressive optical optoelectronic properties, along with rapid increase efficiencies cells LEDs, greatly attracted researchers across many disciplines. However, most advances made so far terms preparation (colloidal nanocrystals films), devices highest are based on Pb‐based halide which raised concerns over their commercialization due to toxicity Pb. This has triggered search lower‐toxicity Pb‐free perovskites led significant progress last few years. In this roadmap review, different expertise joined together summarize latest progress, outstanding challenges, future directions perovskite regarding synthesis, spectroscopy, devices, guide currently working area well those that will join field future.

Language: Английский

Citations

130
Photonic van der Waals integration from 2D materials to 3D nanomembranes DOI
Yuan Meng, Jiangang Feng, Sangmoon Han

et al.

Nature Reviews Materials, Journal Year: 2023, Volume and Issue: 8(8), P. 498 - 517

Published: April 21, 2023

Language: Английский

Citations

117
Synergy of 3D and 2D Perovskites for Durable, Efficient Solar Cells and Beyond DOI
Isaac Metcalf, Siraj Sidhik,

Hao Zhang

et al.

Chemical Reviews, Journal Year: 2023, Volume and Issue: 123(15), P. 9565 - 9652

Published: July 10, 2023

Three-dimensional (3D) organic-inorganic lead halide perovskites have emerged in the past few years as a promising material for low-cost, high-efficiency optoelectronic devices. Spurred by this recent interest, several subclasses of such two-dimensional (2D) begun to play significant role advancing fundamental understanding structural, chemical, and physical properties perovskites, which are technologically relevant. While chemistry these 2D materials is similar that 3D their layered structure with hybrid interface induces new emergent can significantly or sometimes subtly be important. Synergistic realized systems combine different exhibiting dimensionalities exploiting intrinsic compatibility. In many cases, weaknesses each alleviated heteroarchitectures. For example, 3D-2D demonstrate novel behavior neither would capable separately. This review describes how structural differences between give rise disparate properties, discusses strategies realizing mixed-dimensional various architectures through solution-processing techniques, presents comprehensive outlook use solar cells. Finally, we investigate applications beyond photovoltaics offer our perspective on perovskite semiconductor unrivaled tunability, efficiency, relevant durability.

Language: Английский

Citations

112
Zwitterions Narrow Distribution of Perovskite Quantum Wells for Blue Light‐Emitting Diodes with Efficiency Exceeding 15% DOI
S.C. Liu, Zhenyu Guo, Xianxin Wu

et al.

Advanced Materials, Journal Year: 2022, Volume and Issue: 35(3)

Published: Nov. 18, 2022

While quasi-two-dimensional (quasi-2D) perovskites have emerged as promising semiconductors for light-emitting diodes (LEDs), the broad-width distribution of quantum wells hinders their efficient energy transfer and electroluminescence performance in blue emission. In particular, underlying mechanism is closely related to crystallization kinetics has yet be understood. Here first time, influence bifunctional zwitterions with different coordination affinity on quasi-2D systematically investigated. The can coordinate Pb2+ also act co-spacer organic species perovskites, which collectively inhibit aggregation colloidal precursors shorten distance wells. Consequently, restricted nucleation high-n phases promoted growth low-n are achieved moderately coordinated zwitterions, leading final film a more concentrated n improved efficiency. It thus enables high-efficiency LEDs recorded external efficiency 15.6% at 490 nm, operation stability been prolonged 55.3 min. These results provide useful directions tuning expected lead high-performance perovskite LEDs.

Language: Английский

Citations

104
Suppressing thermal quenching via defect passivation for efficient quasi-2D perovskite light-emitting diodes DOI Creative Commons
Dezhong Zhang,

Yunxing Fu,

Hongmei Zhan

et al.

Light Science & Applications, Journal Year: 2022, Volume and Issue: 11(1)

Published: March 23, 2022

Emission thermal quenching is commonly observed in quasi-2D perovskite emitters, which causes the severe drop luminescence efficiency for light-emitting diodes (PeLEDs) during practical operations. However, this issue often neglected and rarely studied, root cause of has not been completely revealed now. Here, we develop a passivation strategy via 2,7-dibromo-9,9-bis (3'-diethoxylphosphorylpropyl)-fluorene to investigate suppress quenching. The agent can effectively passivate coordination-unsaturated Pb2+ defects both surface bulk film without affecting crystallization, helps more truly demonstrate important role And our results reveal that will be strengthened by defect-promoted exciton-phonon coupling. Ultimately, PeLEDs with defect achieve an improved external quantum (EQE) over 22% doubled operation lifetime at room temperature, maintain about 85% initial EQE 85 °C, much higher than 17% control device. These findings provide basis fabricating lighting displays.

Language: Английский

Citations

101
Recent Progress in Mixed A‐Site Cation Halide Perovskite Thin‐Films and Nanocrystals for Solar Cells and Light‐Emitting Diodes DOI
Mahdi Malekshahi Byranvand, Clara Otero‐Martínez, Junzhi Ye

et al.

Advanced Optical Materials, Journal Year: 2022, Volume and Issue: 10(14)

Published: June 22, 2022

Abstract Over the past few years, lead‐halide perovskites (LHPs), both in form of bulk thin films and colloidal nanocrystals (NCs), have revolutionized field optoelectronics, emerging at forefront next‐generation optoelectronics. The power conversion efficiency (PCE) halide perovskite solar cells has increased from 3.8% to over 25.7% a short period time is very close theoretical limit (33.7%). At same time, external quantum (EQE) LEDs surpassed 23% 20% for green red emitters, respectively. Despite great progress device efficiencies, photoactive phase instability one major concerns long‐term stability devices limiting their transition commercialization. In this regard, researchers found that LHPs reproducibility performance can be improved by A‐site cation alloying with two or more species, these are named mixed (double, triple, quadruple) perovskites. This review provides state‐of‐the‐art overview different types NCs reported literature, along discussion synthesis, properties, LEDs.

Language: Английский

Citations

96