Environmental Science & Technology,
Journal Year:
2022,
Volume and Issue:
56(15), P. 10818 - 10828
Published: July 19, 2022
Nanoplastics
are
emerging
pollutants
that
pose
potential
threats
to
the
environment
and
organisms.
However,
in-depth
research
on
nanoplastics
has
been
hindered
by
absence
of
feasible
reliable
analytical
methods,
particularly
for
trace
nanoplastics.
Herein,
we
propose
a
hyphenated
method
involving
membrane
filtration
surface-enhanced
Raman
spectroscopy
(SERS)
analyze
in
water.
In
this
method,
bifunctional
Ag
nanowire
was
employed
enrich
enhance
their
spectra
situ,
which
omitted
sample
transfer
avoided
losing
smaller
Good
retention
rates
(86.7%
50
nm
approximately
95.0%
100–1000
nm)
high
sensitivity
(down
10–7
g/L
50–1000
up
105
SERS
enhancement
factor)
standard
polystyrene
(PS)
were
achieved
using
proposed
method.
PS
with
concentrations
from
10–1
sizes
ranging
1000
successfully
detected
mapping.
Moreover,
micro-
environmental
water
samples
collected
seafood
market
also
at
μg/L
level.
Consequently,
provides
more
possibilities
analyzing
low-concentration
aquatic
environments
enrichment
efficiency,
minimal
loss,
sensitivity.
Progress in Polymer Science,
Journal Year:
2021,
Volume and Issue:
117, P. 101395 - 101395
Published: April 21, 2021
Biodegradable
polymers
have
emerged
as
a
subject
of
enormous
scientific
and
industrial
interest
due
to
their
environmentally
friendly
compostability.
For
the
benefit
market
economy
reoccurring
environmental
hazards,
biodegradable
materials
should
play
more
critical
role
in
packaging
materials,
which
currently
accounts
for
60%
plastic
products.
However,
various
challenges
remain
towards
practical
applications.
Particularly
pertaining
poor
gas/moisture
barrier
issues
greatly
limit
food
application
current
polymers.
The
chain
architecture
tailoring,
crystallinity,
melt
blending/multi-layer
co-extrusion,
nanotechnology
surface
coating
been
considered
effective
strategies
overcoming
facing
polymers,
extensively
researched
decades.
In
this
review,
we
provide
an
in-depth
study
on
oxygen/water
vapor
representative
mainstream
research
with
emphasis
theoretical
models
experimental
modifications
improve
properties.
influence
improvement,
pros/cons
each
method
are
summarized.
limitations
methods
discussed,
potential
overcome
these
presented.
Finally,
conclude
review
by
listing
associated
properties,
processing
scalability
market,
future
perspectives
sustainable
composites
field.
Environmental Science & Technology,
Journal Year:
2022,
Volume and Issue:
56(4), P. 2476 - 2486
Published: Jan. 24, 2022
Microplastic
pollution
is
an
emerging
environmental
problem,
and
little
research
has
focused
on
its
impact
the
human
body.
Based
retrospective
case
series,
study
required
participants
to
fill
out
a
questionnaire
provide
sputum
samples
in
order
investigate
presence
of
microplastics
determine
whether
humans
involuntarily
inhale
them.
A
total
22
patients
suffering
from
different
respiratory
diseases
were
recruited.
We
used
Agilent
8700
laser
infrared
imaging
spectrometer
Fourier-transform
microscope
analyze
evaluate
tract.
Remarkably,
size
range
method
for
detecting
our
20–500
μm.
The
results
showed
that
21
types
identified,
polyurethane
was
dominant,
followed
by
polyester,
chlorinated
polyethylene,
alkyd
varnish,
accounting
78.36%
microplastics.
Most
aspirated
detected
are
smaller
than
500
μm
(median:
75.43
μm;
interquartile
range:
44.67–210.64
μm).
Microplastics
ubiquitous
all
sputum,
indicating
inhalation
potential
way
plastics
enter
Additionally,
quantities
microplastic
tract
related
smoking,
invasive
examination,
etc.
(P
<
0.05).
This
sheds
new
light
exposure,
which
provides
basic
data
risk
assessment
health.
Science,
Journal Year:
2021,
Volume and Issue:
373(6550), P. 107 - 111
Published: July 1, 2021
Plastic
floating
at
the
ocean
surface,
estimated
tens
to
hundreds
of
thousands
metric
tons,
represents
only
a
small
fraction
several
million
tons
annually
discharged
by
rivers.
Such
an
imbalance
promoted
search
for
missing
plastic
sink
that
could
explain
rapid
removal
river-sourced
plastics
from
surface.
On
basis
in-depth
statistical
reanalysis
updated
data
on
microplastics-a
size
which
both
and
river
sampling
rely
equal
techniques-we
demonstrate
current
flux
assessments
are
overestimated
two
three
orders
magnitude.
Accordingly,
average
residence
time
microplastics
surface
rises
few
days
years,
strongly
reducing
theoretical
need
sink.
Environmental Science Processes & Impacts,
Journal Year:
2021,
Volume and Issue:
23(2), P. 198 - 212
Published: Jan. 1, 2021
The
fate
of
plastic
in
the
ocean
is
influenced
by
physical,
chemical
and
biological
stressors.
These
cause
fragemntation
formation
micro
nanoplastics
but
also
degradation
plastics.
Global Change Biology,
Journal Year:
2021,
Volume and Issue:
27(10), P. 2188 - 2199
Published: Feb. 9, 2021
Abstract
Plastic
pollution
has
pervaded
almost
every
facet
of
the
biosphere,
yet
we
lack
an
understanding
consumption
risk
by
marine
species
at
global
scale.
To
address
this,
compile
data
from
research
documenting
plastic
debris
ingestion
fish,
totaling
171,774
individuals
555
species.
Overall,
386
fish
have
ingested
including
210
commercial
importance.
However,
148
studied
had
no
records
consumption,
suggesting
that
while
this
evolutionary
trap
is
widespread,
it
not
universal.
Across
all
studies
accounted
for
microplastics,
incidence
rate
was
26%.
Over
last
decade
doubled,
increasing
2.4
±
0.4%
per
year.
This
driven
both
detection
smaller
sized
particles
as
a
result
improved
methodologies,
well
increase
in
consuming
plastic.
Further,
investigated
role
geographic,
ecological,
and
behavioral
factors
across
These
analyses
revealed
abundance
surface
waters
positively
correlated
to
ingestion.
Demersal
are
more
likely
ingest
shallow
waters;
contrast,
pelagic
were
most
consume
below
mixed
layer.
Mobile
predatory
highest
likelihood
plastic;
similarly,
found
positive
relationship
between
trophic
level
We
also
find
evidence
ingestion‐deep
sea
egestion
microplastics
mesopelagic
myctophids
key
mechanism
export
ocean
seafloor,
sink
debris.
results
elucidate
ecology
biogeography
underlying
point
toward
regions
urgent
need
study.
Annals of Global Health,
Journal Year:
2023,
Volume and Issue:
89(1)
Published: Jan. 1, 2023
Plastics
have
conveyed
great
benefits
to
humanity
and
made
possible
some
of
the
most
significant
advances
modern
civilization
in
fields
as
diverse
medicine,
electronics,
aerospace,
construction,
food
packaging,
sports.
It
is
now
clear,
however,
that
plastics
are
also
responsible
for
harms
human
health,
economy,
earth's
environment.
These
occur
at
every
stage
plastic
life
cycle,
from
extraction
coal,
oil,
gas
its
main
feedstocks
through
ultimate
disposal
into
The
extent
these
not
been
systematically
assessed,
their
magnitude
fully
quantified,
economic
costs
comprehensively
counted.The
goals
this
Minderoo-Monaco
Commission
on
Human
Health
examine
plastics'
impacts
across
cycle
on:
(1)
health
well-being;
(2)
global
environment,
especially
ocean;
(3)
economy;
(4)
vulnerable
populations-the
poor,
minorities,
world's
children.
On
basis
examination,
offers
science-based
recommendations
designed
support
development
a
Global
Treaty,
protect
save
lives.This
report
contains
seven
Sections.
Following
an
Introduction,
Section
2
presents
narrative
review
processes
involved
production,
use,
notes
hazards
environment
associated
with
each
stages.
3
describes
ocean
potential
enter
marine
web
result
exposure.
4
details
health.
5
first-order
estimate
health-related
costs.
6
examines
intersection
between
plastic,
social
inequity,
environmental
injustice.
7
Commission's
findings
recommendations.Plastics
complex,
highly
heterogeneous,
synthetic
chemical
materials.
Over
98%
produced
fossil
carbon-
oil
gas.
comprised
carbon-based
polymer
backbone
thousands
additional
chemicals
incorporated
polymers
convey
specific
properties
such
color,
flexibility,
stability,
water
repellence,
flame
retardation,
ultraviolet
resistance.
Many
added
toxic.
They
include
carcinogens,
neurotoxicants
endocrine
disruptors
phthalates,
bisphenols,
per-
poly-fluoroalkyl
substances
(PFAS),
brominated
retardants,
organophosphate
retardants.
integral
components
many
environment.Global
production
has
increased
almost
exponentially
since
World
War
II,
time
more
than
8,300
megatons
(Mt)
manufactured.
Annual
volume
grown
under
Mt
1950
460
2019,
230-fold
increase,
track
triple
by
2060.
More
half
all
ever
2002.
Single-use
account
35-40%
current
represent
rapidly
growing
segment
manufacture.Explosive
recent
growth
reflects
deliberate
pivot
integrated
multinational
fossil-carbon
corporations
produce
manufacture
plastics.
reducing
fuels
increasing
manufacture.
two
principal
factors
decreasing
demand
due
increases
'green'
energy,
massive
expansion
fracking.Plastic
energy-intensive
contributes
significantly
climate
change.
At
present,
estimated
3.7%
greenhouse
emissions,
contribution
Brazil.
This
fraction
projected
increase
4.5%
2060
if
trends
continue
unchecked.The
three
phases:
disposal.
In
carbon
feedstocks-coal,
gas,
oil-are
transformed
energy-intensive,
catalytic
vast
array
products.
Plastic
use
occurs
aspect
results
widespread
exposure
contained
plastic.
constitute
largest
portion
followed
fibers
construction.Plastic
inefficient,
recovery
recycling
rates
below
10%
globally.
22
waste
enters
year,
much
it
single-use
gigatons
accumulated
1950.
Strategies
controlled
uncontrolled
landfilling,
open
burning,
thermal
conversion,
export.
Vast
quantities
exported
year
high-income
low-income
countries,
where
accumulates
landfills,
pollutes
air
water,
degrades
vital
ecosystems,
befouls
beaches
estuaries,
health-environmental
injustice
scale.
Plastic-laden
e-waste
particularly
problematic.Plastics
plastic-associated
pollution.
contaminate
aquatic
(marine
freshwater),
terrestrial,
atmospheric
environments
destination
found
throughout
ocean,
including
coastal
regions,
sea
surface,
deep
sea,
polar
ice.
appear
resist
breakdown
could
persist
decades.
Macro-
micro-plastic
particles
identified
hundreds
species
major
taxa,
consumed
humans.
Trophic
transfer
microplastic
within
them
demonstrated.
Although
themselves
(>10
µm)
undergo
biomagnification,
hydrophobic
bioaccumulate
animals
biomagnify
webs.
amounts
fates
smaller
nanoplastic
(MNPs
<10
poorly
understood,
but
harm
worrying
given
mobility
biological
systems.
Adverse
pollution
multiple
levels
molecular
biochemical
population
ecosystem.
MNP
contamination
seafood
direct,
though
well
chemicals.
Marine
endangers
ecosystems
upon
which
depends
food,
oxygen,
livelihood,
well-being.Coal
miners,
workers
field
who
extract
suffer
mortality
traumatic
injury,
coal
workers'
pneumoconiosis,
silicosis,
cardiovascular
disease,
chronic
obstructive
pulmonary
lung
cancer.
risk
leukemia,
lymphoma,
hepatic
angiosarcoma,
brain
cancer,
breast
mesothelioma,
neurotoxic
decreased
fertility.
Workers
producing
textiles
die
bladder
interstitial
disease
rates.
toxic
metal
poisoning,
neuropathy,
Residents
"fenceline"
communities
adjacent
sites
experience
risks
premature
birth,
low
birth
weight,
asthma,
childhood
cancer.During
disposal,
release
additives
residual
monomers
people.
National
biomonitoring
surveys
USA
document
population-wide
exposures
disrupt
function
births,
neurodevelopmental
disorders,
male
reproductive
defects,
infertility,
obesity,
renal
cancers.
Chemical-laden
MNPs
formed
degradation
can
living
organisms,
Emerging,
albeit
still
incomplete
evidence
indicates
may
cause
toxicity
physical
toxicological
effects
acting
vectors
transport
bacterial
pathogens
tissues
cells.Infants
womb
young
children
populations
high
plastic-related
effects.
Because
exquisite
sensitivity
early
hazardous
children's
unique
patterns
exposure,
linked
prematurity,
stillbirth,
defects
organs,
impairment,
impaired
growth,
Early-life
non-communicable
diseases
later
life.Plastic's
We
2015
exceeded
$250
billion
(2015
Int$)
globally,
alone
disability
caused
PBDE,
BPA
DEHP
$920
Int$).
(GHG)
emissions
equivalent
1.96
dioxide
(CO2e)
annually.
Using
US
Environmental
Protection
Agency's
(EPA)
cost
metric,
we
annual
GHG
be
$341
Int$).These
costs,
large
they
are,
certainly
underestimate
full
losses
resulting
negative
All
costs-and
costs-are
externalized
petrochemical
manufacturing
industry
borne
citizens,
taxpayers,
governments
countries
around
world
without
compensation.The
adverse
economy
evenly
distributed.
disproportionately
affect
disempowered,
marginalized
workers,
racial
ethnic
communities,
Indigenous
groups,
women,
children,
whom
had
little
do
creating
crisis
lack
political
influence
or
resources
address
it.
Plastics'
harmful
keenly
felt
South,
small
island
states,
disenfranchised
areas
North.
Social
justice
(SEJ)
principles
require
reversal
inequitable
burdens
ensure
no
group
bears
disproportionate
share
those
benefit
economically
bear
fair
currently
costs.It
clear
sustainable
societal
injustices.The
driver
worsening
exponential
accelerating
production.
further
magnified
long
persistence
environment.The
plastics-monomers,
additives,
processing
agents,
non-intentionally
substances-include
amongst
number
known
disruptors,
neurotoxicants,
persistent
organic
pollutants.
planetary
leach
out
plastics,
pollution,
disease.
efforts
reduce
must
chemicals.To
at-risk
populations,
put
end
2040,
supports
urgent
adoption
nations
strong
comprehensive
Treaty
accord
mandate
set
forth
March
2022
resolution
United
Nations
Environment
Assembly
(UNEA).International
measures
needed
curb
because
transcend
national
boundaries,
scale,
well-being
people
poorest
nations.
Effective
implementation
will
international
action
coordinated
complemented
interventions
national,
regional,
local
levels.This
urges
cap
targets,
timetables,
contributions
central
provision
Treaty.
recommend
inclusion
following
provisions:The
needs
extend
beyond
microplastics
litter
plastics.The
banning
severely
restricting
unnecessary,
avoidable,
problematic
items,
items
manufactured
microbeads.The
requirements
extended
producer
responsibility
(EPR)
make
producers,
manufacturers
products
legally
financially
safety
end-of-life
management
materials
sell.The
reductions
complexity
products;
health-protective
standards
additives;
requirement
non-toxic
materials;
disclosure
components;
traceability
components.
International
cooperation
essential
implementing
enforcing
standards.The
SEJ
remedies
fill
gaps
community
knowledge
advance
both
distributional
procedural
equity.This
encourages
calling
exploration
listing
least
pollutants
(POPs)
Stockholm
Convention.This
interface
Basel
London
Conventions
enhance
slow
exports
least-developed
countries.This
recommends
creation
Permanent
Science
Policy
Advisory
Body
guide
Treaty's
implementation.
priorities
would
Member
States
other
stakeholders
evaluating
solutions
effective
consumption,
enhancing
recycling,
curbing
generation
waste.
assess
trade-offs
among
evaluate
safer
alternatives
monitor
transnational
export
coordinate
robust
oceanic-,
land-,
air-based
monitoring
programs.This
investment
research
crisis.
need
determine
cost-effective
context
particular
proposed
solutions.
Oceanographic
better
measure
concentrations
µm
understand
distribution
fate
Biomedical
elucidate
MNPs.This
finds
boon
stealth
threat
enormous
benefits,
linear
pay
attention
design
safe
near
absence
recovery,
reuse,
grave
damage,
injustices.
worsening.While
there
remain
about
uncertainties
magnitude,
available
today
demonstrates
unequivocally
severity
intervention
Manufacture
continue.
However,
reckless
ever-increasing
unnecessary
products,
curbed.Global
against
failure
act
immense.
The Science of The Total Environment,
Journal Year:
2022,
Volume and Issue:
851, P. 158022 - 158022
Published: Aug. 12, 2022
Understanding
the
fate
of
plastics
in
environment
is
critical
importance
for
quantitative
assessment
biological
impacts
plastic
waste.
Specially,
there
a
need
to
analyze
more
detail
reputed
longevity
context
degradation
through
oxidation
and
fragmentation
reactions.
Photo-oxidation
debris
by
solar
UV
radiation
(UVR)
makes
material
prone
subsequent
fragmentation.
The
fragments
generated
following
exposure
mechanical
stresses
include
secondary
micro-
or
nanoparticles,
an
emerging
class
pollutants.
paper
discusses
UV-driven
photo-oxidation
process,
identifying
relevant
knowledge
gaps
uncertainties.
Serious
exist
concerning
wavelength
sensitivity
dose-response
photo-fragmentation
process.
Given
heterogeneity
natural
irradiance
varying
from
no
sediments
full
floating,
beach
litter
air-borne
plastics,
it
argued
that
rates
degradation/fragmentation
will
also
vary
dramatically
between
different
locations
environmental
niches.
Biological
phenomena
such
as
biofouling
further
modulate
radiation,
while
potentially
contributing
and/or
independent
UVR.
Reductions
UVR
many
regions,
consequent
implementation
Montreal
Protocol
its
Amendments
protecting
stratospheric
ozone,
have
consequences
global
heterogeneous
manner
across
geographic
zones.
interacting
effects
warming,
ozone
are
projected
increase
at
surface
localized
areas,
mainly
because
decreased
cloud
cover.
complexity
uncertainty
future
conditions,
this
currently
precludes
reliable
predictions
persistence
on
scale.