ChemCatChem,
Journal Year:
2025,
Volume and Issue:
unknown
Published: April 10, 2025
Abstract
In
the
photocatalytic
conversion
of
water,
carbon
dioxide,
and
small‐molecule
organics
into
clean
energy
sources
and/or
value‐added
products,
direct
or
indirect
utilization
metal‐organic
framework
(MOF)
has
gained
significant
attention
because
its
versatile
use.
The
reaction
flask
uses
either
MOF
directly
a
MOF‐derived
catalyst.
both
cases,
role
ligand
is
noteworthy.
When
used,
more
defined
functions
with
several
chemical
supramolecular
interactions,
conversely,
sacrificial
when
materials
are
developed.
Both
aspects
were
critically
assessed
covered
categorically
suitable
examples,
research
gap
was
identified.
current
review
offers
(i)
fundamental
idea
charge
transfer
phenomena
irrespective
nature
reactions,
(ii)
multi‐body
(iii)
synthetic
origin
structural
properties
that
only
associated
linkers
do
not
aim
to
discuss
catalytic
activity
metric,
metal
nodes,
hypothesis
MOF.
Nature Communications,
Journal Year:
2022,
Volume and Issue:
13(1)
Published: Aug. 6, 2022
High-performance
and
low-cost
photocatalysts
play
the
key
role
in
achieving
large-scale
solar
hydrogen
production.
In
this
work,
we
report
a
liquid-exfoliation
approach
to
prepare
NiPS
ACS Energy Letters,
Journal Year:
2023,
Volume and Issue:
8(6), P. 2652 - 2660
Published: May 18, 2023
Water
oxidation
is
a
critical
reaction
in
artificial
photosynthesis
which
limited
by
high
energy
barrier
and
often
requires
matching
cocatalysts.
Dual
cocatalysts
Co3O4
Pt
are
combined
with
perylene
diimide
(PDI)
polymer,
accomplishing
photocatalytic
O2
production
rate
of
24.4
mmol
g–1
h–1
under
visible
light
irradiation,
5.4-fold
enhancement
compared
PDI
alone.
Moreover,
the
apparent
quantum
yield
evolution
reaches
6.9%
at
420
nm
remains
1.2%
590
nm.
The
dual
cocatalysts-constructed
interfacial
electric
fields
provide
an
anisotropic
driving
force
for
photogenerated
holes
to
electrons
Pt,
synergistically
improving
spatial
charge
separation
efficiency
water
oxidation.
molecules
serve
as
active
sites
improve
utilization
on
surface.
This
work
provides
valuable
demonstration
interaction
process
mechanism
cocatalysts,
guiding
selection
high-efficiency
solar
conversion.
