Scientia Sinica Chimica, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 1, 2024
Chemical Science, Journal Year: 2024, Volume and Issue: 15(11), P. 3920 - 3927
Published: Jan. 1, 2024
Stimuli-responsive aggregation-induced emission (AIE) materials are highly sensitive and rapidly responsive to external signals, making them ideal solid for anti-counterfeiting encryption. However, the limited conformational packing variations resulting from regio-isomerization with a single substituent restricts stimuli-responsive behavior of these materials. In this work, several AIE-active regio-structural isomers based on salicylaldehyde Schiff base scaffold have been straightforwardly obtained through multiple substitutions bromide triphenylamine moieties. Solvent-effect experiments demonstrate their different orders charge-transfer excited-state intramolecular proton transfer upon photoexcitation, indicating regulation processes via multi-site isomerization. These also mechanochromism acidichromism, allowing adjustable effects. As demonstration, p-Br-TPA both acidichromism can be synergistically utilized multi-level decryption. This study successfully regulates evolution excited states isomerization, offering general approach achieving tunable properties in bases toward
Language: Английский
Citations
22
Green Chemistry, Journal Year: 2024, Volume and Issue: 26(6), P. 3479 - 3487
Published: Jan. 1, 2024
A new strategy for multi-component synthesis of functionalized carbazole-based AIEgens from lignin phenolic β-O-4 model linkages was developed by a one-pot, two-step method with low-cost CuCl 2 as catalyst.
Language: Английский
Citations
8
Green Chemistry, Journal Year: 2024, Volume and Issue: 26(7), P. 4151 - 4160
Published: Jan. 1, 2024
The design of biphasic DES systems facilitates the targeted conversion lignin into valuable monomeric acetals or polyols, thereby enabling directional valorization lignin.
Language: Английский
Citations
6
Chemical Science, Journal Year: 2024, Volume and Issue: 15(28), P. 10969 - 10979
Published: Jan. 1, 2024
We have developed a series of novel single AIE fluorophores based on the N , -diaryl dihydrophenazine moiety, which possess anti-quenching properties and can be utilized for efficient in vivo bioimaging cancer phototherapy.
Language: Английский
Citations
6
Advanced Science, Journal Year: 2023, Volume and Issue: 11(9)
Published: Dec. 15, 2023
Abstract Artificial aggregation‐induced emission luminogens (AIEgens) have flourished in bio‐applications with the development of synthetic chemistry, which however are plagued by issues like singularity structures and non‐renewability. The unique renewability biomass moieties can compensate for these drawbacks, but their properties hard to design regulate due confined structures. Therefore, it appears be a reasonable approach derive AIEgens from abundant (BioAIEgens), integrating bilateral advantages both natural AIEgens. In this work, blue‐violet emissive coumarin its lactone structure serving as rare acceptor, is utilized construct donor‐π‐acceptor typed BioAIE isomers incorporating propeller‐like electron‐donating triphenylamine (TPA) unit. results show that Cm‐ p ‐TPA undergoes charge transfer keto form, emitting red light at 600 nm, applied monitor Cu 2+ concentration during mitophagy using fluorescence lifetime imaging microscopy because excellent biocompatibility, photostability, specific recognition . This work not only demonstrates feasibility utilizing positional isomerization modulate excited‐state evolutions resultant optical properties, also provides evidence rationality constructing biologically‐active BioAIEgens via biomass‐derivatization concept.
Language: Английский
Citations
15
Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: 505, P. 158869 - 158869
Published: Jan. 5, 2025
Language: Английский
Citations
0
International Journal of Biological Macromolecules, Journal Year: 2025, Volume and Issue: 295, P. 139476 - 139476
Published: Jan. 7, 2025
Language: Английский
Citations
0
Industrial Crops and Products, Journal Year: 2025, Volume and Issue: 226, P. 120627 - 120627
Published: Jan. 31, 2025
Language: Английский
Citations
0
Sustainable Chemistry and Pharmacy, Journal Year: 2025, Volume and Issue: 44, P. 101962 - 101962
Published: Feb. 20, 2025
Language: Английский
Citations
0
ACS Nano, Journal Year: 2025, Volume and Issue: unknown
Published: March 18, 2025
Biomass-based luminescent nanocomposites have garnered significant attention due to their renewable, biocompatible, and environmentally sustainable characteristics for ensuring information encryption security. Nanomaterials are central this development, as high surface area, tunable optical properties, nanoscale structural advantages enable enhanced efficiency, stability, adaptability in diverse conditions. This review delves into the principles of luminescence, focusing on inherent bioluminescent properties natural materials, utilization biomass precursors carbon dots (CDs) aggregation-induced emission (AIE)-enhanced substances, functional optimization materials. The role cellulose nanocrystals (CNC), lignin, chitosan key biomass-derived nanomaterials will be highlighted, alongside interfacial engineering strategies that further improve material performance. Recent advancements synthesis integration anticounterfeiting systems discussed detail. Furthermore, advanced artificial intelligence (AI) technologies is explored, emphasizing potential revolutionize anticounterfeiting. Current challenges, including scalability, waste minimization, performance optimization, critically examined. Finally, outlines future research directions, application AI-driven methodologies exploration unconventional accelerate development high-performance, eco-friendly solutions.
Language: Английский
Citations
0