Angstrom‐Scale 2D Channels Designed For Osmotic Energy Harvesting DOI
Zhengmao Ding, Tiancheng Gu, Minghao Zhang

et al.

Small, Journal Year: 2024, Volume and Issue: 20(44)

Published: Aug. 23, 2024

Confronting the impending exhaustion of traditional energy, it is urgent to devise and deploy sustainable clean energy alternatives. Osmotic contained in salinity gradient sea-river interface an innovative, abundant, clean, renewable osmotic that has garnered considerable attention recent years. Inspired by impressively intelligent ion channels nature, developed angstrom-scale 2D with simple fabrication process, outstanding design flexibility, substantial charge density exhibit excellent conversion performance, opening up a new era for harvesting. However, this attractive research field remains fraught numerous challenges, particularly due complexities associated regulation at angstrom scale. In review, latest advancements are primarily outlined harvesting energy. Drawing upon analytical framework power generation mechanisms insights gleaned from biomimetic devices, strategies highlighted high-performance terms structure, functionalization, application, particular emphasis on selectivity transport resistance. Finally, current challenges future prospects discussed anticipate emergence more anomalous properties disruptive technologies can promote large-scale generation.

Language: Английский

Nanoarchitectonics in Advanced Membranes for Enhanced Osmotic Energy Harvesting DOI
Peifang Wang,

Weixiang Tao,

Tianhong Zhou

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(35)

Published: June 22, 2024

Osmotic energy, often referred to as "blue energy", is the energy generated from mixing of solutions with different salt concentrations, offering a vast, renewable, and environmentally friendly resource. The efficacy osmotic power production considerably relies on performance transmembrane process, which depends ionic conductivity capability differentiate between positive negative ions. Recent advancements have led development membrane materials featuring precisely tailored ion transport nanochannels, enabling high-efficiency harvesting. In this review, diffusion in confined nanochannels rational design optimization architecture are explored. Furthermore, structural mitigate resistance concentration polarization effect for enhancing harvesting highlighted. Finally, an outlook challenges that lie ahead provided, potential applications conversion outlined. This review offers comprehensive viewpoint evolving prospects conversion.

Language: Английский

Citations

16

2D Conjugated Metal–Organic Framework‐Based Composite Membranes for Nanofluidic Ionic Photoelectric Conversion DOI Open Access

Xinyan Jiang,

Qixiang Zhang,

Naijia Zhao

et al.

Advanced Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 10, 2025

Abstract Nanofluidic photoelectric conversion system based on photo‐excitable 2D materials can directly transduce light stimuli into an ion‐transport‐mediated electric signal, showing potential for mimicking the retina's function with a more favorable human–robot interactions. However, current membranes suffer from low generation efficiency of charge carriers due to mixed microstructure and limited transport ability caused by large interlayer spacing monotonous pathway. Here, fully conjugated hexaimino‐substituted triphenylene‐based metal–organic framework (2D‐HATP‐cMOF) composite membrane high conductivity is presented. The extended π‐d conjugation within ab plane pathway through π–π stacking c‐MOF maximize transfer carrier greatly accelerate ion transport. As result, 2D‐HATP‐cMOF‐based possesses ultrafast response, superior other reported systems like graphene oxide (GO), transition metal carbides, carbonitrides nitrides (MXene), MoS 2 , which require at least 10 s. A successful pump phenomenon, that active concentration as important way information transmission in organisms, realized efficient capability. This work demonstrates great promise ionic conversion.

Language: Английский

Citations

2

Review on the effect of isomorphic replacement on the structure and application performance of typical clay minerals DOI Creative Commons

Ritong Huang,

Limei Wu, Xiaolong Wang

et al.

Progress in Natural Science Materials International, Journal Year: 2024, Volume and Issue: 34(2), P. 251 - 262

Published: March 27, 2024

Clay minerals represent a class of hydrated phyllosilicates making up the fine-grained portions rocks, sediments, and soils. Due to advantages abundant reserves, low prices, wide applications, development utilization clay have received increasing attention in recent years. Isomorphic replacement is common phenomenon minerals, which one main causes changes mineral chemical composition physical properties. This article briefly describes crystal structure several such as montmorillonite, vermiculite, palygorskite, kaolinite, halloysite. It summarized research status effect isomorphic on their application performance. The results can provide theoretical basis for structural efficient resource minerals.

Language: Английский

Citations

8

Sustainable Chitin‐Derived 2D Nanosheets with Hierarchical Ion Transport for Osmotic Energy Harvesting DOI
Zhongrun Xiang, Yu Chen,

Zhijiang Xie

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown

Published: June 21, 2024

Abstract Generating electricity from salinity‐gradient waters with nanofluidic structures is a promising approach for achieving zero‐emission energy goals and addressing escalating crises. However, the ingenious design development of biomass membranes that satisfy requirements sustainability, low‐cost, long‐term stability, high output power density crucial challenge. This work reports two‐dimensional (2D) hierarchical‐structured chitin nanosheets (2D H‐CNS) abundant micro‐/nano‐pore through chemical modification, acid vapor treatment, ultrasound‐assisted exfoliation. The results showed surface charge modification not only promotes loosening controllable exfoliation dense structure into ultra‐thin 2D H‐CNS (1.34 nm) but also increases porosity enhances ion transport flux selectivity nanosheets. Furthermore, experimental simulation confirm hierarchical in nanosheet‐assembled (2D‐HM) substantially performance, an 18.5 times improvement conductance over (2D‐DM). 2D‐HM embedded harvesting system achieved 2.59 W m −2 , 2.51 2D‐DM. study all‐biomass materials high‐performance osmotic harvesting.

Language: Английский

Citations

8

“Brick-and-Mortar” Structured Nanofluidics with High Cation Flux Employed for Efficient Osmotic Energy Harvesting DOI

Suan Huang,

Tao Liu, Weiwen Xin

et al.

Journal of Membrane Science, Journal Year: 2025, Volume and Issue: unknown, P. 123678 - 123678

Published: Jan. 1, 2025

Language: Английский

Citations

1

Lithium complexing strategy based on host-guest recognition for efficient Mg2+/Li+ separation DOI
Xiangmin Xu,

Xiaowei Zhu,

Jinchao Chen

et al.

Water Research, Journal Year: 2025, Volume and Issue: 274, P. 123100 - 123100

Published: Jan. 5, 2025

Language: Английский

Citations

1

Integrating Aerogel into van der Waals Crystals for a High-Strength Thermal Insulator DOI
Soo Jung Park, Sunghwan Hong, Taehoon Kim

et al.

Nano Letters, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 9, 2025

Achieving low thermal conductivity and high mechanical strength presents a material design challenge due to intrinsic trade-offs, such as the aerogel's porosity, impeding applications in construction, industry, aerospace. This study composite that incorporates silica aerogel within thermally expanded 2D layered vermiculite matrix. overcomes limitations imposed by van der Waals bonding lengths, typically less than 10 Å, which hinder integration with crystals. Our method employs spark reaction expand interlayer space, allowing incorporation. maintains of 29.6 mW m–1 K–1, while enhancing its Young's modulus 66.0 MPa─a more 103-fold increase over pure aerogel. The innovative embedding aerogels crystals marks significant advancement high-strength insulation technology, paving way for development demanding environments require management without compromising structural integrity.

Language: Английский

Citations

1

High-performance osmotic energy harvesting enabled by the synergism of space and surface charge in two-dimensional nanofluidic membranes DOI
Tianliang Xiao,

Xuejiang Li,

Wenwei Lei

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 673, P. 365 - 372

Published: June 12, 2024

Language: Английский

Citations

7

Enhanced osmotic power generation through anodic electrodeposited MOFs@MXene heterostructured nanochannels DOI
Bing Yao, Zhou Fang, Yue Hu

et al.

Journal of Membrane Science, Journal Year: 2024, Volume and Issue: 709, P. 123116 - 123116

Published: July 22, 2024

Language: Английский

Citations

4

Ion-selective Vermiculite Nanochannel Membrane with Water Anchoring Effect for Efficient Energy Recovery from Water Evaporation DOI

Xueru Li,

Haochen Lu,

Lei Lei

et al.

Journal of Membrane Science, Journal Year: 2025, Volume and Issue: 718, P. 123698 - 123698

Published: Jan. 7, 2025

Language: Английский

Citations

0