Anomalous Catalytic Performance on Non‐Active‐Site Carbon Substrate DOI

Wenxing Sun,

Yao Hu, Jinlong Gong

et al.

ChemSusChem, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 14, 2024

Carbon-based nanomaterials are gaining attention in electrocatalysis. This study investigates the inherent nitrate reduction activity (NO

Language: Английский

Comprehensive Chlorine Suppression: Advances in Materials and System Technologies for Direct Seawater Electrolysis DOI Creative Commons

Cenkai Zhao,

Zheyuan Ding,

Kunye Zhang

et al.

Nano-Micro Letters, Journal Year: 2025, Volume and Issue: 17(1)

Published: Jan. 22, 2025

Abstract Seawater electrolysis offers a promising pathway to generate green hydrogen, which is crucial for the net-zero emission targets. Indirect seawater severely limited by high energy demands and system complexity, while direct bypasses pre-treatment, offering simpler more cost-effective solution. However, chlorine evolution reaction impurities in lead severe corrosion hinder electrolysis’s efficiency. Herein, we review recent advances rational design of chlorine-suppressive catalysts integrated systems architectures chloride-induced corrosion, with simultaneous enhancement Faradaic efficiency reduction cost. Furthermore, directions are proposed durable efficient systems. This provides perspectives toward sustainable conversion environmental protection.

Language: Английский

Citations

3

Enhanced Syngas Production through Dry Reforming of Methane with Ni/CeZrO2 Catalyst: Kinetic Parameter Investigation and CO2-Rich Feed Simulation DOI Creative Commons
Intan Clarissa Sophiana,

Soen Steven,

Rawiyah Khairunida’ Shalihah

et al.

Chemical Engineering Journal Advances, Journal Year: 2024, Volume and Issue: 20, P. 100655 - 100655

Published: Oct. 9, 2024

Language: Английский

Citations

6

Upcycling PET wastes into high value-added 1,4-cyclohexanedimethanol (CHDM) via tandem reactions DOI

Songlei Mo,

jiancun kou, Jianrong Zeng

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 157249 - 157249

Published: Oct. 1, 2024

Language: Английский

Citations

5

Carbon Reduction Strategy for the Growth of Ni Nanoparticles on Binary TiO2–Al2O3 for CO2 Methanation DOI
Li Qiu,

Yuxin Kang,

Yubin Li

et al.

Industrial & Engineering Chemistry Research, Journal Year: 2025, Volume and Issue: unknown

Published: March 31, 2025

Language: Английский

Citations

0

CO-Tolerant Pt1-MoOx/Mo2N Catalyst for Efficient Activation of C–H and O–H Bonds toward Alcohol Dehydrogenation DOI
Ming Zhang, Xin‐Pu Fu, Shanqing Li

et al.

Journal of the American Chemical Society, Journal Year: 2025, Volume and Issue: unknown

Published: April 7, 2025

Excessively strong adsorption of CO onto a Pt-based catalyst results in the poisoning effect during numerous CO-containing catalysis reactions, including dehydrogenation process alcohols. Traditional strategies via modifying electronic state Pt atoms are beneficial for weakening adsorption; however, they normally detrimental to C-H cracking, thereby degrading catalytic efficiency toward alcohol reaction. In this work, we present synergistic function Pt1 single and heterostructured MoOx/Mo2N efficiently dehydrogenating alcohols, allowing high resistance along with excellent capacity O-H activation. This conjunction renders electron transfer Pt-MoOx/Mo2N interaction thus induces low 5d occupancy sites, enabling facile desorption, which boosts entire reaction cycles. Based on situ structural characterizations isotopic labeling analysis, found that spontaneously formed thin MoOx-Ov layer enables barrierless breakage bonds even at as room temperature, further energetically facilitates cracking interfacial sites. Therefore, strategy can be applied fabricate CO-tolerant catalysts reactions without compromising reactivity by coupling advantages single-atom defective support materials.

Language: Английский

Citations

0

Pressure-dependent catalytic combustion of low-concentration methane: mechanisms and kinetic behavior on Mn-Ce-Cu catalysts DOI
Ziqi Wang, Zhongqing Yang, Jiaqi Qiu

et al.

Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 133130 - 133130

Published: April 1, 2025

Language: Английский

Citations

0

Pilot scale study of elevated pressure autothermal dry reforming of methane over Ni-UGSO pellets DOI Creative Commons
Muhammad Irfan Malik, Nicolas Abatzoglou,

Jasmin Blanchard

et al.

Journal of CO2 Utilization, Journal Year: 2025, Volume and Issue: 97, P. 103121 - 103121

Published: May 23, 2025

Language: Английский

Citations

0

Promotional Role of Pd Over Ni Catalyst Dispersed Over Sc‐ZrO₂ for Methane Partial Oxidation: Crystallinity and Reducibility Effects DOI Creative Commons
Norah Alwadai, Kenit Acharya, Ahmed A. Ibrahim

et al.

Energy Science & Engineering, Journal Year: 2025, Volume and Issue: unknown

Published: May 25, 2025

ABSTRACT Natural emissions of the highly potent greenhouse gas methane cannot be completely prevented, but in presence O 2 , can catalytically converted to hydrogen‐rich syngas. This reaction is specified as partial oxidation (POM). Herein, Ni dispersed over “scandia‐stabilized‐zirconia” (5Ni/DSZ) and promotional effect Pd (0.01 0.1 wt%) are investigated for POM characterized with surface area porosity measurements, X‐ray diffraction, Raman spectroscopy, temperature‐programmed studies, thermogravimetry. During POM, initial population active sites decreases non‐promoted catalysts due under oxygen, upon loading 0.02 wt.% 5Ni/DSZ, site preserved against oxygen during improved metal support interaction between long‐range order crystallites (like cubic ZrO orthorhombic Sc Zr 5 13 ). 5Ni0.02 Pd/DSZ catalyst acquired more than 80% catalytic activity (CH 4 conversion H yield) 2.5 /CO ratio at 600°C 240 min on stream. The also maintained 70% yield ~2 30 h time thermostable may recommended syngas production high ‐yield through POM.

Language: Английский

Citations

0

Recent developments and discourse on catalyst systems for partial oxidation of methane to syngas production DOI
Nida Naeem, Asif Hussain Khoja, Mehboob Alam

et al.

International Journal of Hydrogen Energy, Journal Year: 2025, Volume and Issue: 139, P. 646 - 717

Published: May 27, 2025

Language: Английский

Citations

0

Ni-Co bimetal catalysts anchored on MWCNTS-COOH for enhancing CH4 electrooxidation to C2H5OH DOI

Junyi Peng,

Wensheng Liao,

Xiaohong Fu

et al.

Molecular Catalysis, Journal Year: 2024, Volume and Issue: 569, P. 114589 - 114589

Published: Oct. 2, 2024

Language: Английский

Citations

2