Inorganic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 24, 2024
Superatomic alloy Ag14Pd clusters exhibit strong near-infrared luminescence in both solid and solution states, for the first time, superatomic have been used as inks 3D printing various macroscopic models.
Language: Английский
Chemical Society Reviews, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 13, 2024
Ligand-protected metal nanoclusters are an emerging class of nanomaterials at the interface atomic and plasmonic regimes with unique photophysical electrochemical properties, leading to diverse applications.
Language: Английский
Citations
7
International Journal of Quantum Chemistry, Journal Year: 2025, Volume and Issue: 125(5)
Published: Feb. 21, 2025
ABSTRACT The structures and properties of PtAg n ( = 1–16) clusters have been studied by density functional theory (DFT). Tpssh/def2‐TZVP method is chosen in this work. Calculations reveal that the are planar when 1–3, while they present three‐dimensional 4–16. coordination number Pt atom range 1–11. atoms prefer to locate centers structures. electronic compared with available experimental theoretical data. stability analysis manifests odd‐even properties. study catalytic on perform similar interactions one CO molecule. favors interacting carbon terminal According thermodynamic property study, adsorption reactions all spontaneous. projected states (PDOS) reveals orbital hybridization phenomenon between C 6 cluster.
Language: Английский
Citations
1
The Journal of Physical Chemistry Letters, Journal Year: 2025, Volume and Issue: unknown, P. 2942 - 2949
Published: March 13, 2025
Atomically precise metal nanoclusters bridge the gap between atoms and nanoparticles, providing an ideal platform for correlating macroscopic properties of nanoparticles to their microstructures. In comparison rapid development coin nanoclusters, knowledge on group 10 is relatively limited because active nature, resulting in synthetic challenge. this work, we successfully synthesize three that is, Ni3(SNS)3, Ni3(SNOS)3, Pd3(SNS)3, by using SNS pincer ligands, which well-stabilize nickel palladium kernels. Intrinsic chirality originated from asymmetric arrangement surface ligands discovered. Oxidation-induced irreversible transformation boat-like Ni3(SNS)3 chair-like Ni3(SNOS)3 observed, boat/chair structure-dependent reactivity revealed. The structural features intriguing Ni3 Pd3 stabilized ligand will inspire further research nanoclusters.
Language: Английский
Citations
0
Chemical Science, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
The novel Pt 1 Ag 11 nanocluster with a defect-containing icosahedral kernel displayed excellent catalytic performance in the photocatalytic hydrogen evolution reaction.
Language: Английский
Citations
0
Chemical Society Reviews, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 1, 2025
By integrating four energy modalities—NIR light, radiation, magnetic field, and ultrasound—with bioengineered nanomaterials, dynamic in vivo diagnostics can be achieved, advancing the path toward personalized precision medicine.
Language: Английский
Citations
0
Nanoscale, Journal Year: 2024, Volume and Issue: unknown
Published: Jan. 1, 2024
This review focuses on the structure–property correlation and bioimaging application of luminescent metal nanoclusters, which feature atomically precise structures, diverse optical properties excellent biocompatibility.
Language: Английский
Citations
0
Inorganic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: unknown
Published: Dec. 24, 2024
Superatomic alloy Ag14Pd clusters exhibit strong near-infrared luminescence in both solid and solution states, for the first time, superatomic have been used as inks 3D printing various macroscopic models.
Language: Английский
Citations
0