Effects of crosslink density and plasticizer on thermorheological properties of dissociative guanidine-based covalent adaptable networks DOI

Adelle L. Koenig,

Kelsey M. Allis,

John S. Lehr

et al.

Polymer Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

This work describes the effect of varying crosslink density and plasticizer loading on covalent adaptable networks that have equal amounts reactive functionalities.

Language: Английский

Mechanism model of dynamic polyurethanes with two scales of nodes to regulate mechanical property DOI Creative Commons
Yue Liu, Jinpeng Li, Lin Jia

et al.

Materials & Design, Journal Year: 2025, Volume and Issue: 250, P. 113611 - 113611

Published: Jan. 15, 2025

Language: Английский

Citations

0
Light-Induced Transformation from Covalent to Supramolecular Polymer Networks DOI
Chuan Yue,

Jingxi Deng,

Bo Pang

et al.

ACS Macro Letters, Journal Year: 2025, Volume and Issue: unknown, P. 169 - 175

Published: Jan. 26, 2025

Stimuli-responsive polymers have demonstrated significant potential in the development of smart materials due to their capacity undergo targeted property changes response external physical or chemical stimuli. However, scales most existing stimuli-responsive polymer systems are mainly focused on three levels: functional units, chain conformations, topologies. Herein, we developed a covalent network (CPN) capable converting into supramolecular (SPN) within bulk directly at scale types. This transformation is enabled by specifically designed moieties that upon UV exposure reveal quadruple hydrogen bonding sites, allowing formation network. network-type transition from CPN SPN induces pronounced intrinsic material properties, including substantially increased breaking elongation, lower Young's modulus, reduced fracture strength, and decreased creep resistance, marking shift stable, rigid structure dynamic, adaptable one. These findings provide new insights design advanced through transformations, opening avenues for applications multifunctional materials.

Language: Английский

Citations

0
Mechanics of CO2-Induced Dynamic Covalent Polymer Networks: Constitutive Modeling and Crack Healing DOI

Haoxiang Deng,

Haixu Du,

Yanchu Zhang

et al.

Journal of the Mechanics and Physics of Solids, Journal Year: 2025, Volume and Issue: unknown, P. 106098 - 106098

Published: Feb. 1, 2025

Language: Английский

Citations

0
Effect of ACR/PMDA dynamic ion cross-linking network on dimensional stability and lightweight of PVC foam materials DOI

Jingze Guo,

Shikai Song,

Jianqiao Liu

et al.

Polymer Degradation and Stability, Journal Year: 2025, Volume and Issue: unknown, P. 111386 - 111386

Published: April 1, 2025

Language: Английский

Citations

0
Effects of crosslink density and plasticizer on thermorheological properties of dissociative guanidine-based covalent adaptable networks DOI

Adelle L. Koenig,

Kelsey M. Allis,

John S. Lehr

et al.

Polymer Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

This work describes the effect of varying crosslink density and plasticizer loading on covalent adaptable networks that have equal amounts reactive functionalities.

Language: Английский

Citations

0