Single‐Layer Carbon Nitride as an Efficient Metal‐Free Organic Electron‐Transport Material with a Tunable Work Function DOI Creative Commons
Abdus Saboor, Oleksandr Stroyuk, Oleksandra Raievska

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(29)

Published: March 7, 2024

Abstract Single‐layer carbon nitride (SLCN) is introduced as a metal‐free organic electron transport material (ETL) for solar cells, delivering performance comparable to that of the benchmark nanocrystalline ZnO. SLCN produced in form stable aqueous inks and can serve an efficient layer three different types active layers, showing high stability photodegradation. A lower conductivity films compared ZnO counter‐balanced by their higher transparency light scattering losses. The ETL provides unique opportunity tune work function from ca. −4.1 −4.6 eV varying annealing temperature due partial thermal oxidation film. PL band position follows oxidation‐induced changes allowing properties be used predict PV efficiency. 2D structure coupled with structural compositional variability, tunability show promise emerging devices.

Language: Английский

The Second Laser Revolution in Chemistry: Emerging Laser Technologies for Precise Fabrication of Multifunctional Nanomaterials and Nanostructures DOI Creative Commons
Alina Manshina, Ilya I. Tumkin, Evgeniia M. Khairullina

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(40)

Published: July 26, 2024

Abstract The use of photons to directly or indirectly drive chemical reactions has revolutionized the field nanomaterial synthesis resulting in appearance new sustainable laser chemistry methods for manufacturing micro‐ and nanostructures. incident radiation triggers a complex interplay between physical processes at interface solid surface liquid gas environment. In such multi‐parameter system, precise control over nanostructures is not possible without deep understanding both environment‐affected processes. present review intends provide detailed systematization these surveying well‐established emerging technologies production advanced nanomaterials. Both gases liquids are considered as potential reacting environments affecting fabrication process, while subtractive additive analyzed. Finally, prospects applications discussed.

Language: Английский

Citations

32
An ultraflexible energy harvesting-storage system for wearable applications DOI Creative Commons

Sakeena Saifi,

Xiao Xiao, Simin Cheng

et al.

Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)

Published: Aug. 2, 2024

The swift progress in wearable technology has accentuated the need for flexible power systems. Such systems are anticipated to exhibit high efficiency, robust durability, consistent output, and potential effortless integration. Integrating ultraflexible energy harvesters storage devices form an autonomous, efficient, mechanically compliant system remains a significant challenge. In this work, we report 90 µm-thick harvesting (FEHSS) consisting of high-performance organic photovoltaics zinc-ion batteries within configuration. With conversion efficiency surpassing 16%, output exceeding 10 mW cm–2, density beyond 5.82 mWh FEHSS can be tailored meet demands sensors gadgets. Without cumbersome rigid components, shows immense as versatile source advance electronics contribute toward sustainable future. integration Here, authors solar cells batteries, exhibiting

Language: Английский

Citations

22
Promises and challenges of indoor photovoltaics DOI Creative Commons
G. Krishnamurthy Grandhi, George Koutsourakis, James C. Blakesley

et al.

Published: Jan. 29, 2025

Language: Английский

Citations

4
The Role of Solution Aggregation Property toward High‐Efficiency Non‐Fullerene Organic Photovoltaic Cells DOI
Lei Xu, Sunsun Li, Wenchao Zhao

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(28)

Published: April 26, 2024

In organic photovoltaic cells, the solution-aggregation effect (SAE) is long considered a critical factor in achieving high power-conversion efficiencies for polymer donor (PD)/non-fullerene acceptor (NFA) blend systems. However, underlying mechanism has yet to be fully understood. Herein, based on an extensive study of blends consisting representative 2D-benzodithiophene-based PDs and acceptor-donor-acceptor-type NFAs, it demonstrated that SAE shows strong correlation with aggregation kinetics during solidification, competition between PD NFA determines phase separation film thus performance. SAEs enable earlier evolutions than resulting well-known polymer-templated fibrillar network structures superior PCEs. With weakening PDs' effects, showing stronger tendencies aggregate, tend form oversized domains, leading significantly reduced external quantum fill factors. These trends reveal importance matching NFA. The abilities various materials are further evaluated ability/photovoltaic parameter diagrams 64 PD/NFA combinations provided. This work proposes guiding criteria facile approach match efficient

Language: Английский

Citations

10
Progress in Flexible Perovskite Solar Cells: Paving the Way for Scalable Manufacturing DOI Creative Commons
Dimitar I. Kutsarov, Ehsan Rezaee, J. D.B. Lambert

et al.

Advanced Materials Technologies, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 20, 2025

Abstract The urgency for a sustainable mitigation of the environmental impacts caused by climate change highlights importance renewable energy technologies to fight this challenge. Perovskite solar cells (PSCs) emerge as promising alternative traditional photovoltaic (PV) due their unprecedented increase in efficiency (currently peaking at 26.95%) and long‐term stability proven successful completion industry relevant International Electrotechnical Commission (IEC) testing standards. Flexible PSCs (f‐PSCs) offer significant advantages such lightweight high power‐per‐weight ratio, mechanical flexibility, throughput roll‐to‐roll (R2R) manufacturing. These make f‐PSCs ideal implementation various applications areas, wearable electronics, portable devices, space PV, building‐ or automotive‐integrated PVs, more. Notably, efficiencies over 23% now mark milestone f‐PSCs, demonstrating competitiveness with rigid panels. This review explores breakthroughs focusing on flexible substrates, electrode materials, perovskite inks, encapsulation strategies. It also covers recent advancements studies fabricated scalable deposition methods emphasizes interfacial engineering enhancing durability. concludes summary key findings, remaining challenges, perspectives market uptake f‐PSCs.

Language: Английский

Citations

1
Advancements in photovoltaic technology: A comprehensive review of recent advances and future prospects DOI Creative Commons

Abdelrahman O. Ali,

Abdelrahman T. Elgohr,

Mostafa H. El-Mahdy

et al.

Energy Conversion and Management X, Journal Year: 2025, Volume and Issue: 26, P. 100952 - 100952

Published: March 4, 2025

Language: Английский

Citations

1
Exploring the Versatile Uses of Triplet States: Working Principles, Limitations, and Recent Progress in Phosphorescence, TADF, and TTA DOI Creative Commons
Larissa Gomes Franca, David G. Bossanyi, Jenny Clark

et al.

ACS Applied Optical Materials, Journal Year: 2024, Volume and Issue: 2(12), P. 2476 - 2500

Published: April 19, 2024

Triplet excited states in organic semiconductors are usually optically dark and long-lived as they have a spin-forbidden transition to the singlet ground state therefore hinder processes light-harvesting applications. Also, triplets often cause damage system can sensitize formation of reactive oxygen. Despite these unfavorable characteristics, there exist mechanisms through which we utilize triplet states, that constitutes scope this review. Commencing with an introductory short exploration problem, proceed elucidate principal underpinning utilization materials: 1. Phosphorescence (PH), 2. Thermally Activated Delayed Fluorescence (TADF), 3. Triplet-Triplet Annihilation (TTA). In each section unveil their working principles, highlight vast range applications, discuss limitations perspectives. We dedicate special attention use light-emitting diodes (OLEDs), given OLEDs represent most thriving commercial application semiconductors. This review aims provide readers insights opportunities engage contribute study photophysical properties device physics semiconductors, especially regarding harnessing potential states.

Language: Английский

Citations

7
Over 19% Efficient Inverted Organic Photovoltaics Featuring a Molecularly Doped Metal Oxide Electron‐Transporting Layer DOI
Mohamad Insan Nugraha, Zhaoheng Ling, Filip Aniés

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(35)

Published: June 22, 2024

Molecular doping is commonly utilized to tune the charge transport properties of organic semiconductors. However, applying this technique electrically dope inorganic materials like metal oxide semiconductors challenging due limited availability molecules with suitable energy levels and processing characteristics. Herein, n-type zinc (ZnO) films demonstrated using 1,3-dimethylimidazolium-2-carboxylate (CO

Language: Английский

Citations

7
Unified model for probing solar cell dynamics via cyclic voltammetry and impedance spectroscopy DOI
Victor López-Richard, Luiz A. Meneghetti, Gabriel Leonardo Nogueira

et al.

Physical review. B./Physical review. B, Journal Year: 2024, Volume and Issue: 110(11)

Published: Sept. 12, 2024

Citations

5
12.84% Efficiency Flexible Kesterite Solar Cells by Heterojunction Interface Regulation DOI Open Access
Xiao Xu, Jiazheng Zhou, Kang Yin

et al.

Advanced Energy Materials, Journal Year: 2023, Volume and Issue: 13(38)

Published: Aug. 18, 2023

Abstract Due to their environmental friendliness, low cost, and versatility in applications, flexible Cu 2 ZnSn(S, Se) 4 (CZTSSe) solar cells have garnered significant attention recent years. However, the lack of alkali metal elements substrate has posed a challenge advancement CZTSSe cells. In this study, post‐treatment strategy is proposed involving Rb ions simultaneously regulate surface properties film reactions during CdS chemical bath deposition (CBD) process. Material characterization results confirm that effectively passivate detrimental Se 0 defect, leading more active for epitaxial growth. Additionally, coordination between thiourea CBD solution improves ion‐by‐ion layer. These beneficial effects significantly improve heterojunction interface consequently enable cell achieve record total‐area efficiency 12.84% excellent bending performance. Overall, regulation employed work, along with obtained remarkable results, offer promising prospects development

Language: Английский

Citations

12