Small,
Journal Year:
2024,
Volume and Issue:
unknown
Published: April 30, 2024
Abstract
Photocatalytic
CO
2
reduction
technology,
capable
of
converting
low‐density
solar
energy
into
high‐density
chemical
energy,
stands
as
a
promising
approach
to
alleviate
the
crisis
and
achieve
carbon
neutrality.
Semiconductor
metal
oxides,
characterized
by
their
abundant
reserves,
good
stability,
easily
tunable
structures,
have
found
extensive
applications
in
field
photocatalysis.
However,
wide
bandgap
inherent
oxides
contributes
poor
efficiency
photocatalytic
reduction.
Defect
engineering
presents
an
effective
strategy
address
these
challenges.
This
paper
reviews
research
progress
defect
enhance
performance
summarizing
classifications,
preparation
methods,
characterization
techniques.
The
focus
is
on
engineering,
represented
vacancies
doping,
for
improving
oxide
photocatalysts.
includes
advancements
expanding
photoresponse
range,
enhancing
photogenerated
charge
separation,
promoting
molecule
activation.
Finally,
provides
summary
current
issues
challenges
faced
along
with
prospective
outlook
future
development
technology.
Journal of Advances in Modeling Earth Systems,
Journal Year:
2022,
Volume and Issue:
14(10)
Published: Sept. 15, 2022
Abstract
Many
different
emission
pathways
exist
that
are
compatible
with
the
Paris
climate
agreement,
and
many
more
possible
miss
target.
While
some
of
most
complex
Earth
System
Models
have
simulated
a
small
selection
Shared
Socioeconomic
Pathways,
it
is
impractical
to
use
these
expensive
models
fully
explore
space
possibilities.
Such
explorations
therefore
mostly
rely
on
one‐dimensional
impulse
response
models,
or
simple
pattern
scaling
approaches
approximate
physical
given
scenario.
Here
we
present
ClimateBench—the
first
benchmarking
framework
based
suite
Coupled
Model
Intercomparison
Project,
AerChemMIP
Detection‐Attribution
Project
simulations
performed
by
full
complexity
Model,
set
baseline
machine
learning
emulate
its
variety
forcers.
These
emulators
can
predict
annual
mean
global
distributions
temperature,
diurnal
temperature
range
precipitation
(including
extreme
precipitation)
wide
emissions
concentrations
carbon
dioxide,
methane
aerosols,
allowing
them
efficiently
probe
previously
unexplored
scenarios.
We
discuss
accuracy
interpretability
consider
their
robustness
constraints
such
as
total
energy
conservation.
Future
opportunities
incorporating
directly
in
using
for
detection
attribution
studies
also
discussed.
This
opens
improve
prediction,
mathematical
tractability.
hope
laying
out
principles
model
emulation
clear
examples
metrics
encourage
engagement
from
statisticians
specialists
keen
tackle
this
important
demanding
challenge.
Scientific Reports,
Journal Year:
2023,
Volume and Issue:
13(1)
Published: Nov. 14, 2023
The
excessive
release
of
greenhouse
gases,
especially
carbon
dioxide
(CO2)
pollution,
has
resulted
in
significant
environmental
problems
all
over
the
world.
CO2
capture
technologies
offer
a
very
effective
means
combating
global
warming,
climate
change,
and
promoting
sustainable
economic
growth.
In
this
work,
UiO-66-NH2
was
synthesized
by
novel
sonochemical
method
only
one
hour.
This
material
characterized
through
PXRD,
FT-IR,
FE-SEM,
EDX,
BET,
TGA
methods.
potential
presented
investigated
analysis
gas
isotherms
under
varying
pressure
conditions,
encompassing
both
low
high-pressure
regions.
Remarkably,
adsorbent
manifested
notable
augmentation
adsorption
capacity
(3.2
mmol/g),
achieving
an
approximate
enhancement
0.9
mmol/g,
when
compared
to
conventional
solvothermal
techniques
(2.3
mmol/g)
at
25
°C
1
bar.
To
accurately
represent
experimental
findings,
three
isotherm,
kinetic
models
were
used
fit
data
which
Langmuir
model
Elovich
exhibited
best
with
R2
values
0.999
0.981,
respectively.
Isosteric
heat
evaluation
showed
higher
than
80
kJ/mol
indicates
chemisorption
between
surface
adsorbate.
Furthermore,
selectivity
examined
using
Ideal
Adsorbed
Solution
Theory
(IAST),
high
value
202
towards
simulated
flue
conditions.
evaluate
durability
performance
consecutive
adsorption-desorption
processes,
cyclic
tests
conducted.
Interestingly,
these
demonstrated
0.6
mmol/g
decrease
for
throughout
8
cycles.
npj Climate and Atmospheric Science,
Journal Year:
2023,
Volume and Issue:
6(1)
Published: May 26, 2023
Abstract
As
the
world
warms,
extremely
hot
days
are
becoming
more
frequent
and
intense,
reaching
unprecedented
temperatures
associated
with
excess
mortality.
Here,
we
assess
how
anthropogenic
forcings
affect
likelihood
of
maximum
daily
above
50
°C
at
12
selected
locations
around
Mediterranean
Middle
East.
We
adopt
a
risk-based
attribution
methodology
that
utilises
climate
model
simulations
without
human
influence
to
estimate
probability
extremes.
find
all
locations,
would
have
been
rare
or
impossible
in
pre-industrial
world,
but
under
human-induced
change
their
is
rapidly
increasing.
At
hottest
has
increased
by
factor
10–10
3
,
whereas
end
century
such
extremes
could
occur
every
year.
All
may
see
1–2
additional
months
thermal
deaths
2100,
which
stresses
need
for
effective
adaptation
planning.
Small,
Journal Year:
2024,
Volume and Issue:
unknown
Published: April 30, 2024
Abstract
Photocatalytic
CO
2
reduction
technology,
capable
of
converting
low‐density
solar
energy
into
high‐density
chemical
energy,
stands
as
a
promising
approach
to
alleviate
the
crisis
and
achieve
carbon
neutrality.
Semiconductor
metal
oxides,
characterized
by
their
abundant
reserves,
good
stability,
easily
tunable
structures,
have
found
extensive
applications
in
field
photocatalysis.
However,
wide
bandgap
inherent
oxides
contributes
poor
efficiency
photocatalytic
reduction.
Defect
engineering
presents
an
effective
strategy
address
these
challenges.
This
paper
reviews
research
progress
defect
enhance
performance
summarizing
classifications,
preparation
methods,
characterization
techniques.
The
focus
is
on
engineering,
represented
vacancies
doping,
for
improving
oxide
photocatalysts.
includes
advancements
expanding
photoresponse
range,
enhancing
photogenerated
charge
separation,
promoting
molecule
activation.
Finally,
provides
summary
current
issues
challenges
faced
along
with
prospective
outlook
future
development
technology.