Multifunctional Trifluoroborate Additive for Simultaneous Carrier Dynamics Governance and Defects Passivation to Boost Efficiency and Stability of Inverted Perovskite Solar Cells DOI
Jun Li,

Lisha Xie,

Guanhao Liu

et al.

Angewandte Chemie International Edition, Journal Year: 2024, Volume and Issue: 63(14)

Published: Feb. 10, 2024

Abstract The main obstacles to promoting the commercialization of perovskite solar cells (PSCs) include their record power conversion efficiency (PCE), which still remains below Shockley–Queisser limit, and poor long‐term stability, attributable crystallographic defects in films open‐circuit voltage ( V oc ) loss devices. In this study, potassium (4‐tert‐butoxycarbonylpiperazin‐1‐yl) methyl trifluoroborate (PTFBK) was employed as a multifunctional additive target modulate bulk carrier dynamics PSCs. Apart from simultaneously passivating anionic cationic defects, PTFBK could also optimize energy‐level alignment devices weaken interaction between carriers longitudinal optical phonons, resulting lifetime greater than 3 μs. Furthermore, it inhibited non‐radiative recombination improved crystallization capacity film. Hence, rigid flexible p‐i‐n PSCs yielded champion PCEs 24.99 % 23.48 %, respectively. More importantly, due hydrogen bonding formamidinium fluorine, exhibited remarkable thermal, humidity, operational tracking at maximum point stabilities. reduced Young's modulus residual stress layer provided excellent bending stability for

Language: Английский

Stabilized hole-selective layer for high-performance inverted p-i-n perovskite solar cells DOI
Zhen Li, Xianglang Sun, Xiaopeng Zheng

et al.

Science, Journal Year: 2023, Volume and Issue: 382(6668), P. 284 - 289

Published: Oct. 19, 2023

P-i-n geometry perovskite solar cells (PSCs) offer simplified fabrication, greater amenability to charge extraction layers, and low-temperature processing over n-i-p counterparts. Self-assembled monolayers (SAMs) can enhance the performance of p-i-n PSCs but ultrathin SAMs be thermally unstable. We report a robust hole-selective layer comprised nickel oxide (NiOx) nanoparticle film with surface-anchored (4-(3,11-dimethoxy-7H-dibenzo[c,g]carbazol-7-yl)butyl)phosphonic acid (MeO-4PADBC) SAM that improve stabilize NiOx/perovskite interface. The energetic alignment favorable contact binding between NiOx/MeO-4PADBC reduced voltage deficit various compositions led strong interface toughening effects under thermal stress. resulting 1.53-electron-volt devices achieved 25.6% certified power conversion efficiency maintained >90% their initial after continuously operating at 65 degrees Celsius for 1200 hours 1-sun illumination.

Language: Английский

Citations

356
Bimolecularly passivated interface enables efficient and stable inverted perovskite solar cells DOI
Cheng Liu, Yi Yang, Hao Chen

et al.

Science, Journal Year: 2023, Volume and Issue: 382(6672), P. 810 - 815

Published: Nov. 16, 2023

Compared with the n-i-p structure, inverted (p-i-n) perovskite solar cells (PSCs) promise increased operating stability, but these photovoltaic often exhibit lower power conversion efficiencies (PCEs) because of nonradiative recombination losses, particularly at perovskite/C60 interface. We passivated surface defects and enabled reflection minority carriers from interface into bulk using two types functional molecules. used sulfur-modified methylthio molecules to passivate suppress through strong coordination hydrogen bonding, along diammonium repel reduce contact-induced achieved field-effect passivation. This approach led a fivefold longer carrier lifetime one-third photoluminescence quantum yield loss certified quasi-steady-state PCE 25.1% for PSCs stable operation 65°C >2000 hours in ambient air. also fabricated monolithic all-perovskite tandem 28.1% PCE.

Language: Английский

Citations

345
Homogenized NiO x nanoparticles for improved hole transport in inverted perovskite solar cells DOI
Shiqi Yu, Zhuang Xiong, Haitao Zhou

et al.

Science, Journal Year: 2023, Volume and Issue: 382(6677), P. 1399 - 1404

Published: Nov. 23, 2023

The power conversion efficiency (PCE) of inverted perovskite solar cells (PSCs) is still lagging behind that conventional PSCs, in part because inefficient carrier transport and poor morphology hole layers (HTLs). We optimized self-assembly [4-(3,6-dimethyl-9H-carbazol-9-yl)butyl]phosphonic acid (Me-4PACz) onto nickel oxide (NiOx) nanoparticles as an HTL through treatment with hydrogen peroxide, which created a more uniform dispersion high conductivity attributed to the formation Ni3+ well surface hydroxyl groups for bonding. A 25.2% certified PCE mask size 0.074 square centimeters was obtained. This device maintained 85.4% initial after 1000 hours stabilized output operation under 1 sun light irradiation at about 50°C 85.1% 500 accelerated aging 85°C. obtained 21.0% minimodule aperture area 14.65 centimeters.

Language: Английский

Citations

279
Reinforcing self-assembly of hole transport molecules for stable inverted perovskite solar cells DOI
Hongcai Tang, Zhichao Shen, Yangzi Shen

et al.

Science, Journal Year: 2024, Volume and Issue: 383(6688), P. 1236 - 1240

Published: March 14, 2024

Power conversion efficiencies (PCEs) of inverted perovskite solar cells (PSCs) have been improved by the use a self-assembled monolayer (SAM) hole transport layer. Long-term stability PSCs requires keeping SAM compact under layer during operation. We found that strong polar solvents in precursor desorb if it is anchored on substrates hydrogen-bonded, rather than covalently bonded, hydroxyl groups. used atomic-layer deposition to create an indium tin oxide substrate with fully covalent hydroxyl-covered surface for anchoring, as well trimethoxysilane group exhibited tridentate anchoring substrate. The resulting achieved PCEs 24.8 (certified 24.6) and 23.2% aperture areas 0.08 1.01 square centimeters, respectively. devices retained 98.9 98.2% initial PCE after 1000 hours damp-heat test operation maximum power point tracking at 85°C 1200 standard illumination,

Language: Английский

Citations

170
Double-side 2D/3D heterojunctions for inverted perovskite solar cells DOI
Randi Azmi,

Drajad Satrio Utomo,

Badri Vishal

et al.

Nature, Journal Year: 2024, Volume and Issue: 628(8006), P. 93 - 98

Published: Feb. 21, 2024

Language: Английский

Citations

168
Toward the Commercialization of Perovskite Solar Modules DOI

Pengchen Zhu,

Chuanlu Chen,

Jiaqi Dai

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(15)

Published: Jan. 12, 2024

Perovskite (PVSK) photovoltaic (PV) devices are undergoing rapid development and have reached a certified power conversion efficiency (PCE) of 26.1% at the cell level. Tremendous efforts in material device engineering also increased moisture, heat, light-related stability. Moreover, solution-process nature makes fabrication process perovskite feasible compatible with some mature high-volume manufacturing techniques. All these features render solar modules (PSMs) suitable for terawatt-scale energy production low levelized cost electricity (LCOE). In this review, current status cells (PSCs) their potential applications first introduced. Then critical challenges identified commercialization propose corresponding solutions, including developing strategies to realize high-quality films over large area further improve stability meet commercial demands. Finally, directions issues requiring attention future, mainly focusing on dealing toxicity recycling whole device, attainment highly efficient perovskite-based tandem modules, which can reduce environmental impact accelerate LCOE reduction put forwarded.

Language: Английский

Citations

117
Rapid advances enabling high-performance inverted perovskite solar cells DOI
Qi Jiang, Kai Zhu

Nature Reviews Materials, Journal Year: 2024, Volume and Issue: 9(6), P. 399 - 419

Published: May 17, 2024

Language: Английский

Citations

105
peri-Fused polyaromatic molecular contacts for perovskite solar cells DOI
Ke Zhao, Qingqing Liu,

Libing Yao

et al.

Nature, Journal Year: 2024, Volume and Issue: 632(8024), P. 301 - 306

Published: July 24, 2024

Language: Английский

Citations

87
Poly(carbazole phosphonic acid) as a versatile hole-transporting material for p-i-n perovskite solar cells and modules DOI Creative Commons
Zhijun Ren,

Zewei Cui,

Xiaoyu Shi

et al.

Joule, Journal Year: 2023, Volume and Issue: 7(12), P. 2894 - 2904

Published: Nov. 10, 2023

Language: Английский

Citations

83
Strong-bonding hole-transport layers reduce ultraviolet degradation of perovskite solar cells DOI
Chengbin Fei, Anastasia Kuvayskaya, Xiaoqiang Shi

et al.

Science, Journal Year: 2024, Volume and Issue: 384(6700), P. 1126 - 1134

Published: June 6, 2024

The light-emitting diodes (LEDs) used in indoor testing of perovskite solar cells do not expose them to the levels ultraviolet (UV) radiation that they would receive actual outdoor use. We report degradation mechanisms p-i-n-structured under unfiltered sunlight and with LEDs. Weak chemical bonding between perovskites polymer hole-transporting materials (HTMs) transparent conducting oxides (TCOs) dominate accelerated A-site cation migration, rather than direct HTMs. An aromatic phosphonic acid, [2-(9-ethyl-9H-carbazol-3-yl)ethyl]phosphonic acid (EtCz3EPA), enhanced at perovskite/HTM/TCO region a group bonded TCOs nitrogen interacting lead perovskites. A hybrid HTM EtCz3EPA strong hole-extraction polymers retained high efficiency improved UV stability devices, champion minimodule-independently measured by Perovskite PV Accelerator for Commercializing Technologies (PACT) center-retained operational >16% after 29 weeks testing.

Language: Английский

Citations

72