Chemical Reviews,
Journal Year:
2024,
Volume and Issue:
124(19), P. 10623 - 10700
Published: Aug. 29, 2024
Recently,
there
has
been
an
extensive
focus
on
inverted
perovskite
solar
cells
(PSCs)
with
a
p-i-n
architecture
due
to
their
attractive
advantages,
such
as
exceptional
stability,
high
efficiency,
low
cost,
low-temperature
processing,
and
compatibility
tandem
architectures,
leading
surge
in
development.
Single-junction
perovskite-silicon
(TSCs)
have
achieved
certified
PCEs
of
26.15%
33.9%
respectively,
showing
great
promise
for
commercial
applications.
To
expedite
real-world
applications,
it
is
crucial
investigate
the
key
challenges
further
performance
enhancement.
We
first
introduce
representative
methods,
composition
engineering,
additive
solvent
processing
innovation
charge
transporting
layers,
interface
fabricating
high-efficiency
stable
PSCs.
then
delve
into
reasons
behind
excellent
stability
Subsequently,
we
review
recent
advances
TSCs
PSCs,
including
perovskite-Si
TSCs,
all-perovskite
perovskite-organic
TSCs.
achieve
final
deployment,
present
efforts
related
scaling
up,
harvesting
indoor
light,
economic
assessment,
reducing
environmental
impacts.
Lastly,
discuss
potential
PSCs
future.
Science,
Journal Year:
2022,
Volume and Issue:
377(6603), P. 302 - 306
Published: June 23, 2022
The
performance
of
perovskite
solar
cells
with
inverted
polarity
(p-i-n)
is
still
limited
by
recombination
at
their
electron
extraction
interface,
which
also
lowers
the
power
conversion
efficiency
(PCE)
p-i-n
perovskite-silicon
tandem
cells.
A
MgF
x
interlayer
thickness
~1
nanometer
perovskite/C
60
interface
favorably
adjusts
surface
energy
layer
through
thermal
evaporation,
facilitates
efficient
and
displaces
C
from
to
mitigate
nonradiative
recombination.
These
effects
enable
a
champion
open-circuit
voltage
1.92
volts,
an
improved
fill
factor
80.7%,
independently
certified
stabilized
PCE
29.3%
for
monolithic
cell
square
centimeter
in
area.
retained
~95%
its
initial
after
damp-heat
testing
(85°C
85%
relative
humidity)
>1000
hours.
Science,
Journal Year:
2022,
Volume and Issue:
378(6626), P. 1295 - 1300
Published: Dec. 22, 2022
The
development
of
highly
stable
and
efficient
wide-bandgap
(WBG)
perovskite
solar
cells
(PSCs)
based
on
bromine-iodine
(Br-I)
mixed-halide
(with
Br
greater
than
20%)
is
critical
to
create
tandem
cells.
However,
issues
with
Br-I
phase
segregation
under
cell
operational
conditions
(such
as
light
heat)
limit
the
device
voltage
stability.
This
challenge
often
exacerbated
by
ready
defect
formation
associated
rapid
crystallization
Br-rich
chemistry
antisolvent
processes.
We
combined
a
gentle
gas-quench
method
prepare
textured
columnar
1.75-electron
volt
mixed
WBG
films
reduced
density.
With
this
approach,
we
obtained
PSCs
20%
power
conversion
efficiency,
approximately
1.33-volt
open-circuit
(Voc),
excellent
stability
(less
5%
degradation
over
1100
hours
operation
1.2
sun
at
65°C).
When
further
integrated
1.25-electron
narrow-bandgap
PSC,
27.1%
efficient,
all-perovskite,
two-terminal
high
Voc
2.2
volts.
Advanced Materials,
Journal Year:
2021,
Volume and Issue:
34(10)
Published: Dec. 29, 2021
All-inorganic
cesium
lead
triiodide
(CsPbI3
)
perovskite
is
well
known
for
its
unparalleled
stability
at
high
temperatures
up
to
500
°C
and
under
oxidative
chemical
stresses.
However,
upscaling
solar
cells
via
ambient
printing
suffers
from
imperfect
crystal
quality
defects
caused
by
uncontrollable
crystallization.
Here,
the
incorporation
of
a
low
concentration
novel
ionic
liquid
reported
as
being
promising
managing
in
CsPbI3
films,
interfacial
energy
alignment,
device
fabricated
blade-coating.
Both
theoretical
simulations
experimental
measurements
reveal
that
successfully
regulates
thin-film
growth
decrease
grain
boundaries,
strongly
coordinates
with
undercoordinated
Pb2+
passivate
iodide
vacancy
defects,
aligns
interface
barrier
electron-transporting
layer,
relaxes
lattice
strain
promote
phase
stability.
Consequently,
printed
power
conversion
efficiency
20.01%
1
sun
illumination
(100
mW
cm-2
37.24%
indoor
light
(1000
lux,
365
µW
are
achieved;
both
highest
all-inorganic
corresponding
applications.
Furthermore,
bare
show
an
impressive
long-term
only
≈5%
PCE
degradation
after
1000
h
aging
conditions.
Coatings,
Journal Year:
2022,
Volume and Issue:
12(8), P. 1089 - 1089
Published: July 31, 2022
Perovskite
solar
cells
(PSC)
have
been
identified
as
a
game-changer
in
the
world
of
photovoltaics.
This
is
owing
to
their
rapid
development
performance
efficiency,
increasing
from
3.5%
25.8%
decade.
Further
advantages
PSCs
include
low
fabrication
costs
and
high
tunability
compared
conventional
silicon-based
cells.
paper
reviews
existing
literature
discuss
structural
fundamental
features
that
resulted
significant
gains.
Key
electronic
optical
properties
electron
mobility
(800
cm2/Vs),
long
diffusion
wavelength
(>1
μm),
absorption
coefficient
(105
cm−1).
Synthesis
methods
are
considered,
with
solution-based
manufacturing
being
most
cost-effective
common
industrial
method.
Furthermore,
this
review
identifies
issues
impeding
large-scale
commercialisation
actions
needed
resolve
them.
The
main
issue
stability
particularly
vulnerable
moisture,
caused
by
inherently
weak
bonds
perovskite
structure.
Scalability
also
big
spin-coating
technique
used
for
laboratory-scale
tests
not
appropriate
production.
highlights
need
transition
techniques
compatible
roll-to-roll
processing
achieve
throughput.
Finally,
discusses
future
innovations,
more
environmentally
friendly
lead-free
high-efficiency
multi-junction
Overall,
provides
critical
evaluation
advances,
opportunities
challenges
PSCs.
Nano-Micro Letters,
Journal Year:
2023,
Volume and Issue:
15(1)
Published: March 21, 2023
Perovskite-based
tandem
solar
cells
have
attracted
increasing
interest
because
of
its
great
potential
to
surpass
the
Shockley-Queisser
limit
set
for
single-junction
cells.
In
architectures,
wide-bandgap
(WBG)
perovskites
act
as
front
absorber
offer
higher
open-circuit
voltage
(V
