The Promise and Challenges of Inverted Perovskite Solar Cells DOI
Peng Chen,

Yun Xiao,

Shunde Li

et al.

Chemical Reviews, Journal Year: 2024, Volume and Issue: 124(19), P. 10623 - 10700

Published: Aug. 29, 2024

Recently, there has been an extensive focus on inverted perovskite solar cells (PSCs) with a p-i-n architecture due to their attractive advantages, such as exceptional stability, high efficiency, low cost, low-temperature processing, and compatibility tandem architectures, leading surge in development. Single-junction perovskite-silicon (TSCs) have achieved certified PCEs of 26.15% 33.9% respectively, showing great promise for commercial applications. To expedite real-world applications, it is crucial investigate the key challenges further performance enhancement. We first introduce representative methods, composition engineering, additive solvent processing innovation charge transporting layers, interface fabricating high-efficiency stable PSCs. then delve into reasons behind excellent stability Subsequently, we review recent advances TSCs PSCs, including perovskite-Si TSCs, all-perovskite perovskite-organic TSCs. achieve final deployment, present efforts related scaling up, harvesting indoor light, economic assessment, reducing environmental impacts. Lastly, discuss potential PSCs future.

Language: Английский

Surface engineering with oxidized Ti3C2Tx MXene enables efficient and stable p-i-n-structured CsPbI3 perovskite solar cells DOI Creative Commons
Jin Hyuck Heo, Fei Zhang, Jin Kyoung Park

et al.

Joule, Journal Year: 2022, Volume and Issue: 6(7), P. 1672 - 1688

Published: June 14, 2022

Language: Английский

Citations

84
Tailored Cysteine‐Derived Molecular Structures toward Efficient and Stable Inorganic Perovskite Solar Cells DOI
Hao Zhang, Qingwen Tian, Wanchun Xiang

et al.

Advanced Materials, Journal Year: 2023, Volume and Issue: 35(31)

Published: March 27, 2023

Abstract Surface–defect‐triggered non‐radiative charge recombination and poor stability have become the main roadblock to continued improvement in inorganic perovskite solar cells (PSCs). Herein, culprits are identified on surface by first‐principles calculations, purposefully design a brand‐new passivator, Boc‐S‐4‐methoxy‐benzyl‐l‐cysteine (BMBC), whose multiple Lewis‐based functional groups (NH, S CO) suppress halide vacancies coordinate with undercoordinated Pb 2+ through typical Lewis baseacid reactions. The tailored electron‐donating methoxyl group (CH 3 O–) can cause an increased electron density benzene ring, which strengthens interaction via electrostatic interactions. This BMBC passivation reduce trap density, enlarge grains, prolong lifetime, more suitable energy‐level alignment. In addition, hydrophobic tert‐butyl butoxycarbonyl (Boc‐) ensures that is uniformly covered prevents harmful aggregation steric repulsion at perovskite/hole–transporting layer (HTL) interface, thus providing umbrella resist moisture invasion. Consequently, combination of above increases efficiency CsPbI 3−x Br x PSC from 18.6% 21.8%, highest for this type metal PSCs so far, as far it known. Moreover, device exhibits higher environmental thermal stability.

Language: Английский

Citations

84
Chiral Hybrid Copper(I) Halides for High Efficiency Second Harmonic Generation with a Broadband Transparency Window DOI
Fei Ge, Bohan Li,

Puxin Cheng

et al.

Angewandte Chemie International Edition, Journal Year: 2022, Volume and Issue: 61(10)

Published: Jan. 10, 2022

Chiral hybrid organic-inorganic metal halides (HOMHs) with intrinsic noncentrosymmetry have shown great promise for applications in second-order nonlinear optics (NLO). However, established chiral HOMHs often suffer from their relatively small band gaps, which lead to negative impacts on transparent window and laser-induced damage thresholds (LDT). Here, we synthesized two based CuI halides, namely (R-/S-MBA)CuBr2 , feature well-balanced NLO performances a highly efficient SHG response, outstanding optical transparency, high LDT. The effective coefficient of (R-MBA)CuBr2 has been determined be ≈24.7 pm V-1 is orders magnitude higher than that CuII counterparts. This work shows the promising potential -based photonic wide wavelength regions.

Language: Английский

Citations

77
Progress and Perspective on Inorganic CsPbI2Br Perovskite Solar Cells DOI
Jing Song, Haibing Xie, Eng Liang Lim

et al.

Advanced Energy Materials, Journal Year: 2022, Volume and Issue: 12(40)

Published: Sept. 1, 2022

Abstract Over the past few years, all‐inorganic perovskite solar cells (PSCs), especially CsPbI 2 Br PSCs, have received much attention because of their excellent thermal stability and a suitable trade‐off between light absorption higher phase among family inorganic perovskites. In this progress report, realization highly efficient stable PSCs is summarized through preparation process, additive engineering, interface modification, transport material selection. Furthermore, application in tandem its large‐area development are highlighted. Finally, challenges outlook discussed for further performance improvement future practical deployment.

Language: Английский

Citations

74
The Path to Perovskite Commercialization: A Perspective from the United States Solar Energy Technologies Office DOI
Timothy D. Siegler, Andrew H. Dawson, Peter Lobaccaro

et al.

ACS Energy Letters, Journal Year: 2022, Volume and Issue: 7(5), P. 1728 - 1734

Published: April 20, 2022

ADVERTISEMENT RETURN TO ISSUEPREVEnergy FocusNEXTADDITION / CORRECTIONThis article has been corrected. View the notice.The Path to Perovskite Commercialization: A Perspective from United States Solar Energy Technologies OfficeTimothy D. Siegler*Timothy SieglerOak Ridge Institute of Science and Engineering, Oak Ridge, Tennessee 37830, States*[email protected]More by Timothy Sieglerhttps://orcid.org/0000-0001-6033-2232, Andrew DawsonAndrew DawsonSolar Office, Office Efficiency Renewable Energy, U.S. Department Washington, D.C. 20585, StatesMore Dawson, Peter LobaccaroPeter LobaccaroAllegheny Technology, under contract Bridgeport, West Virginia 26330, Lobaccarohttps://orcid.org/0000-0003-4675-1400, David UngDavid UngOak Ung, Markus E. BeckMarkus BeckSolar Beck, Garrett NilsenGarrett NilsenSolar Nilsen, Leonard L. Tinker*Leonard TinkerSolar TinkerCite this: ACS Lett. 2022, 7, 5, 1728–1734Publication Date (Web):April 20, 2022Publication History Received24 March 2022Accepted6 April 2022Published online20 inissue 13 May 2022https://pubs.acs.org/doi/10.1021/acsenergylett.2c00698https://doi.org/10.1021/acsenergylett.2c00698newsACS PublicationsCopyright © Published 2022 American Chemical Society. This publication is available these Terms Use. Request reuse permissions free access through this site. Learn MoreArticle Views14130Altmetric-Citations16LEARN ABOUT THESE METRICSArticle Views are COUNTER-compliant sum full text downloads since November 2008 (both PDF HTML) across all institutions individuals. These metrics regularly updated reflect usage leading up last few days.Citations number other articles citing article, calculated Crossref daily. Find more information about citation counts.The Altmetric Attention Score a quantitative measure attention that research received online. Clicking on donut icon will load page at altmetric.com with additional details score social media presence for given article. how calculated. Share Add toView InAdd Full Text ReferenceAdd Description ExportRISCitationCitation abstractCitation referencesMore Options onFacebookTwitterWechatLinked InRedditEmail (1 MB) Get e-AlertscloseSUBJECTS:Degradation,Durability,Industrial manufacturing,Perovskites,Photovoltaics e-Alerts

Language: Английский

Citations

71
Investigation of heavy thallium perovskites TlGeX (X = Cl, Br and I) for optoelectronic and thermoelectric applications: A DFT study DOI
Soukaina Bouhmaidi, Md Borhan Uddin, Redi Kristian Pingak

et al.

Materials Today Communications, Journal Year: 2023, Volume and Issue: 37, P. 107025 - 107025

Published: Sept. 4, 2023

Language: Английский

Citations

70
Surface n-type band bending for stable inverted CsPbI3perovskite solar cells with over 20% efficiency DOI
Shuo Wang, Minghua Li, Yanyan Zhang

et al.

Energy & Environmental Science, Journal Year: 2023, Volume and Issue: 16(6), P. 2572 - 2578

Published: Jan. 1, 2023

Inverted CsPbI 3 perovskite solar cells offer merits for tandem and indoor photovoltaics.

Language: Английский

Citations

67
Highly efficient bifacial single-junction perovskite solar cells DOI Creative Commons
Qi Jiang, Zhaoning Song, Rosemary C. Bramante

et al.

Joule, Journal Year: 2023, Volume and Issue: 7(7), P. 1543 - 1555

Published: June 29, 2023

Language: Английский

Citations

56
Mixed tin-lead perovskites with balanced crystallization and oxidation barrier for all-perovskite tandem solar cells DOI Creative Commons
Jin Zhou,

Shiqiang Fu,

Shun Zhou

et al.

Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)

Published: March 14, 2024

Abstract Mixed tin-lead perovskite solar cells have driven a lot of passion for research because their vital role in all-perovskite tandem cells, which hold the potential achieving higher efficiencies compared to single-junction counterparts. However, pronounced disparity crystallization processes between tin-based perovskites and lead-based perovskites, coupled with easy Sn 2+ oxidation, has long been dominant factor contributing high defect densities. In this study, we propose multidimensional strategy achieve efficient by employing functional N-(carboxypheny)guanidine hydrochloride molecule. The tailored molecule plays pivotal manipulating grain growth while also serving as preservative effectively inhibit owing strong binding tin (II) iodide elevated energy barriers oxidation. Consequently, exhibit stabilized power conversion efficiency 23.11% can maintain 97.45% initial value even after 3500 h shelf storage an inert atmosphere without encapsulation. We further integrate into two-terminal monolithic delivering certified 27.35%.

Language: Английский

Citations

54
Managing Multiple Halide‐Related Defects for Efficient and Stable Inorganic Perovskite Solar Cells DOI
Zhiteng Wang, Qingwen Tian,

Hao Zhang

et al.

Angewandte Chemie International Edition, Journal Year: 2023, Volume and Issue: 62(30)

Published: May 25, 2023

Abstract Halide‐related surface defects on inorganic halide perovskite not only induce charge recombination but also severely limit the long‐term stability of solar cells. Herein, adopting density functional theory calculation, we verify that iodine interstitials (I i ) has a low formation energy similar to vacancy (V I and is readily formed all‐inorganic perovskite, it regarded function as an electron trap. We screen specific 2,6‐diaminopyridine (2,6‐DAPy) passivator, which, with aid combined effects from halogen‐N pyridine coordination bonds, successfully eliminates dissociative 2 passivates abundant V . Furthermore, two symmetric neighboring ‐NH groups interact adjacent halides octahedral cluster by forming hydrogen which further promotes adsorption 2,6‐DAPy molecules onto surface. Such synergetic can significantly passivate harmful iodine‐related undercoordinated Pb 2+ , prolong carrier lifetimes facilitate interfacial hole transfer. Consequently, these merits enhance power‐conversion efficiency (PCE) 19.6 % 21.8 %, highest value for this type cells, just importantly, 2,6‐DAPy‐treated CsPbI 3− x Br films show better environmental stability.

Language: Английский

Citations

51