Top-down approach for easy processing, cost-effective, biodegradable chiral photonic materials with spontaneous circularly polarized room-temperature phosphorescence activity DOI
Hao Wang, Yi Qian,

Qiongya Li

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160357 - 160357

Published: Feb. 1, 2025

Language: Английский

Room-Temperature Phosphorescence from Bamboo Fibers and Designed Materials DOI Creative Commons
Yingxiang Zhai, Jingyi Zhou,

Ben Dang

et al.

ACS Materials Letters, Journal Year: 2025, Volume and Issue: unknown, P. 1119 - 1126

Published: Feb. 20, 2025

Language: Английский

Citations

1

Producing a Room Temperature Phosphorescent Film from Natural Wood Using a Top‐Down Approach DOI Creative Commons
Ruixia Liu,

Hongda Guo,

Mengnan Cao

et al.

Advanced Functional Materials, Journal Year: 2023, Volume and Issue: 34(12)

Published: Dec. 8, 2023

Abstract Producing mechanic robust and sustainable room temperature phosphorescent (RTP) films in a convenient manner is fundamental requirement but remains challenging. Here, an efficient “top‐down” method for processing natural wood into RTP developed. Specifically, partially delignified to increase its processability the first step. After that, treated converted W‐film with tensile strength of 273.6 MPa via mechanical pressing. The lignin units are well confined by cellulose W‐film, triggering emission lifetime ≈241.9 ms. Additionally, exhibits good energy transfer properties Rhodamine B (RhB). Therefore, series multifunctional afterglow 2D 3D materials constructed using as building block. This research expected result preparation films.

Language: Английский

Citations

17

Producing sustainable room temperature phosphorescent materials using natural wood and sucrose DOI Creative Commons
Wei-Ming Yin,

Ben Dang,

Yuanyuan Miao

et al.

Cell Reports Physical Science, Journal Year: 2024, Volume and Issue: 5(2), P. 101792 - 101792

Published: Jan. 31, 2024

Producing room temperature phosphorescent materials from natural sources is essential for sustainability. However, either toxic chemical reagents or complicated processing still required to produce such derived resources. Here, we sustainable phosphorescence (RTP) wood and sugar. Specifically, sugar introduced into a matrix, which confines the lignin in matrix situ. As result, treated (sucrose [S-wood]) exhibited RTP emissions with lifetime of ∼284.4 ms. Life cycle carbon analysis indicates that ∼8.1–11.2 kg CO2 produced during preparation S-wood, lower than other similar materials. Moreover, S-wood could be naturally degraded soil over 40 days. demonstration practical potential, used visual decorations anti-counterfeiting applications.

Language: Английский

Citations

7

Circularly polarized room-temperature phosphorescence based on chiral co-assembled helical nanofiber from chiral co-assembled liquid crystal co-polymer DOI
Chao Liu, Hang Li, Yihan Chen

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 486, P. 150442 - 150442

Published: March 16, 2024

Language: Английский

Citations

7

Room Temperature Phosphorescent Nanofiber Membranes by Bio‐Fermentation DOI Creative Commons
Xiaolin Nie, Junyi Gong,

Zeyang Ding

et al.

Advanced Science, Journal Year: 2024, Volume and Issue: 11(33)

Published: July 1, 2024

Abstract Stimuli‐responsive materials exhibiting exceptional room temperature phosphorescence (RTP) hold promise for emerging technologies. However, constructing such systems in a sustainable, scalable, and processable manner remains challenging. This work reports bio‐inspired strategy to develop RTP nanofiber using bacterial cellulose (BC) via bio‐fermentation. The green fabrication process, high biocompatibility, non‐toxicity, abundant hydroxyl groups make BC an ideal biopolymer durable stimuli‐responsive materials. Remarkable performance is observed with long lifetimes of up 1636.79 ms at temperature. Moreover, moisture can repeatedly quench activate dynamic tunable fashion by disrupting rigidity permeability. With capabilities repeatable moisture‐sensitive phosphorescence, these are highly suitable applications as anti‐counterfeiting information encryption. pioneering bio‐derived approach provides reliable sustainable blueprint dynamic, beyond synthetic polymers.

Language: Английский

Citations

7

Ultralong Blue Organic Room‐Temperature Phosphorescence Promoted by Green Assembly DOI
Zhongyuan Chen, Zhaojun Chen, Yuqi Zhu

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(46)

Published: July 9, 2024

Abstract In recent years, there is a growing interest in developing ultralong organic room‐temperature phosphorescence (ORTP) with lifetimes the range of seconds. As one important three primary colors, blue ORTP an indispensable core component RTP regulation and application, however, large Stokes shift characteristics pose certain challenges ORTP. Here, new family phosphors are synthesized realized through crystal assembly water phase. Remarkably, compared to materials obtained phases, enabled long‐lived up 2.3 s quantum yield reached as high 29.27%. addition efficient green form, such dark possessed thermal stability flexible tunability. Moreover, superiority selected components demonstrated by comparing them polymer proposed show great potential programmable information encryption/anti‐counterfeiting.

Language: Английский

Citations

7

Self-confining isolated chiral chromophore for circularly polarized organic afterglow from amorphous polymer systems DOI
Chen‐Yu Zhang,

Xin Yan,

Zhisheng Gao

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 485, P. 149886 - 149886

Published: Feb. 22, 2024

Language: Английский

Citations

6

Harnessing triplet excitons: Advances in luminescence metal coordination compounds DOI

Lin Geng,

Rui Sun, Da‐Shuai Zhang

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 518, P. 216066 - 216066

Published: July 15, 2024

Language: Английский

Citations

6

Photoactivated room temperature phosphorescence from lignin DOI Creative Commons
Jingyi Zhou, Bing Tian, Yingxiang Zhai

et al.

Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)

Published: Aug. 22, 2024

Sustainable photoactivated room temperature phosphorescent materials exhibit great potential but are difficult to obtain. Here, we develop by covalently attaching lignin polylactic acid, where and acid the chromophore matrix, respectively. Initially phosphorescence of is quenched residual O2. However, switched on when oxygen consumed triplet excitons under continuous UV light irradiation. As such, lifetime increases from 3.0 ms 221.1 after 20 s activation. Interestingly, again being kept an atmosphere air for 2 h in absence irradiation due diffusion into materials. Using these properties, as-developed material successfully used as a smart anti-counterfeiting logo medicine bottle information recording. Convenient sustainable (RTP) wide ranging applications Here authors RTP acid.

Language: Английский

Citations

6

Sunlight‐Activated Room‐Temperature Phosphorescent Carbon Dots DOI

Zengsheng Guo,

Chenchen Wang,

Fangzheng Qi

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 20, 2024

Abstract The efficient utilization of clean and safe sunlight as an excitation source for room‐temperature phosphorescent (RTP) materials is crucial practical applications in solar energy. Herein, sunlight‐activated RTP nitrogen‐doped carbon dots @ alumina (N‐CDs@Al 2 O 3 ) composites with long lifetime exceptional stability are designed fabricated using situ preparation strategy. N‐CDs@Al display bright yellow (more than 18 s to the naked eye) when activated by sunlight. results indicate that introduction nitrogen into CDs not only promotes effective filling triplet excitons but also facilitates red‐shift absorption spectrum CDs. high rigidity structure Al stable strong covalent bonds effectively protect excitons. Additionally, numerous oxygen vacancy defects formed under appropriate calcination conditions store release Finally, application multi‐color 3D artworks, defense markings, emergency signs demonstrated. This work provides design principles feasible strategies development new materials.

Language: Английский

Citations

6