Journal of Material Science and Technology, Journal Year: 2025, Volume and Issue: unknown
Published: June 1, 2025
Language: Английский
Journal of Material Science and Technology, Journal Year: 2025, Volume and Issue: unknown
Published: June 1, 2025
Language: Английский
Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown
Published: May 2, 2025
Abstract Inspired by the mechanical interlocking principles of traditional Chinese mortise‐and‐tenon structures, a 3D gradient supramolecular network is developed through oriented self‐assembly subphthalocyanine (SubPc‐0) arrays on La‐doped Ag 3 PO 4 (La 0.01 2.99 ). This bioinspired design synergistically combines π‐orbital topological extension with dynamic B–La coordination bonds to construct an S‐scheme heterojunction dual‐phase charge modulation capability. Mechanistic studies reveal that La 3+ doping induces anisotropic electron delocalization for directional bulk transfer, while interfacial coupling establishes ultrafast (<10 ps) atomic‐scale transport channels orbital hybridization. The optimized SubPc‐0/La system demonstrates 2.2‐ and 2.1‐fold improvements in tetracycline oxytetracycline degradation efficiencies, respectively, 94% activity retention after five cycles. Advanced characterization techniques including femtosecond transient absorption spectroscopy (fs‐TAS) Kelvin probe force microscopy (KPFM), combined theoretical calculations, elucidated intricate photocatalytic mechanism transfer pathways. work delivers effective strategy mechanistic insights stacking engineering materials.
Language: Английский
Citations
0Environmental Research, Journal Year: 2025, Volume and Issue: unknown, P. 121670 - 121670
Published: May 1, 2025
Bismuth stannate (Bi2Sn2O7) has emerged as a promising compound for heterostructure applications due to its outstanding photocatalytic, structural, and optical properties. As pyrochlore-type semiconducting material, Bi2Sn2O7 demonstrates suitable bandgap, strong visible-light absorption, high chemical stability, making it attractive environmental remediation. Heterostructures based on have gained significant attention because of their enhanced charge carrier separation efficiency, improved charged mobility, synergistic effects that boost photocatalytic performance. Different strategies been utilized construct Bi2Sn2O7-based heterostructures, including doping, vacancies generation, coupling with other semiconductors form Z-scheme S-scheme heterojunctions. These engineered interfaces effectively reduce recombination, thereby enhancing efficiency pollutant degradation. Furthermore, various synthesis techniques reviewed viz. hydrothermal, solvothermal solid-state reaction method, in-situ, co-precipitation, etc photocatalyst in which the hydrothermal method was most preferable yield crystallinity, morphology, cost-effectiveness, eco-friendly, energy conserving. This review highlights properties, synthesis, modification strategies, application heterostructures technologies. The challenges well future prospects these materials are also analysed, emphasizing potential next-generation photocatalysts. Further research is required optimize material enhance transport, develop scalable methods commercial applications.
Language: Английский
Citations
0Journal of Colloid and Interface Science, Journal Year: 2025, Volume and Issue: 696, P. 137890 - 137890
Published: May 15, 2025
Language: Английский
Citations
0Journal of Material Science and Technology, Journal Year: 2025, Volume and Issue: unknown
Published: May 1, 2025
Language: Английский
Citations
0Published: Jan. 1, 2025
Language: Английский
Citations
0Journal of Material Science and Technology, Journal Year: 2025, Volume and Issue: unknown
Published: May 1, 2025
Language: Английский
Citations
0Acta Physico-Chimica Sinica, Journal Year: 2025, Volume and Issue: unknown, P. 100107 - 100107
Published: May 1, 2025
Language: Английский
Citations
0Chinese Journal of Structural Chemistry, Journal Year: 2025, Volume and Issue: unknown, P. 100630 - 100630
Published: May 1, 2025
Language: Английский
Citations
0Journal of Material Science and Technology, Journal Year: 2025, Volume and Issue: unknown
Published: May 1, 2025
Language: Английский
Citations
0EnergyChem, Journal Year: 2025, Volume and Issue: unknown, P. 100159 - 100159
Published: June 1, 2025
Language: Английский
Citations
0