Dual‐Interface Modification for Inverted Methylammonium‐Free Perovskite Solar Cells of 25.35% Efficiency with Balanced Crystallization DOI
Yiting Zheng, Congcong Tian,

Xueyun Wu

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: 14(20)

Published: March 8, 2024

Abstract In a methylammonium‐free (MA‐free) composition, the uncontrollable crystallization process between Cs and formamidine (FA) currently hinders its efficiency enhancement, especially in inverted perovskite solar cells (PSCs). Here, dual‐interface modification of films is proposed by simultaneously introducing additives surface passivators. particular, (aminomethyl)phosphonic acid (AMP) introduced into precursor solution to balance inducing preferential FA through specific formation strong hydrogen bonds with FA. addition, AMP spontaneously sinks anchors buried interface fill voids self‐assembled monolayer (SAM) via covalent formed ─PO 3 H 2 FTO. Subsequently, sequential 2‐(3‐fluorophenyl)ethylamine iodide (mF‐PEAI) piperazine diiodide (PDI), uniform potential achieved recombination losses at are minimized. Notably, dual‐interface‐modified MA‐free PSCs achieve state‐of‐the‐art power conversion (PCE) 25.35% (certified: 24.87%) satisfactory V oc 1.17 based on bandgap 1.52 eV. Importantly, unencapsulated devices maintain 92.8% 91.7% initial after 1000 h maximum output (MPP) tracking >800 heating 85 °C, respectively, confirming excellent operational thermal stability.

Language: Английский

Stabilized hole-selective layer for high-performance inverted p-i-n perovskite solar cells DOI
Zhen Li, Xianglang Sun, Xiaopeng Zheng

et al.

Science, Journal Year: 2023, Volume and Issue: 382(6668), P. 284 - 289

Published: Oct. 19, 2023

P-i-n geometry perovskite solar cells (PSCs) offer simplified fabrication, greater amenability to charge extraction layers, and low-temperature processing over n-i-p counterparts. Self-assembled monolayers (SAMs) can enhance the performance of p-i-n PSCs but ultrathin SAMs be thermally unstable. We report a robust hole-selective layer comprised nickel oxide (NiOx) nanoparticle film with surface-anchored (4-(3,11-dimethoxy-7H-dibenzo[c,g]carbazol-7-yl)butyl)phosphonic acid (MeO-4PADBC) SAM that improve stabilize NiOx/perovskite interface. The energetic alignment favorable contact binding between NiOx/MeO-4PADBC reduced voltage deficit various compositions led strong interface toughening effects under thermal stress. resulting 1.53-electron-volt devices achieved 25.6% certified power conversion efficiency maintained >90% their initial after continuously operating at 65 degrees Celsius for 1200 hours 1-sun illumination.

Language: Английский

Citations

337
Low-loss contacts on textured substrates for inverted perovskite solar cells DOI

So Min Park,

Mingyang Wei, Nikolaos Lempesis

et al.

Nature, Journal Year: 2023, Volume and Issue: 624(7991), P. 289 - 294

Published: Oct. 23, 2023

Language: Английский

Citations

224
Enhanced optoelectronic coupling for perovskite/silicon tandem solar cells DOI
Erkan Aydın, Esma Ugur, Bumın K. Yildırım

et al.

Nature, Journal Year: 2023, Volume and Issue: 623(7988), P. 732 - 738

Published: Sept. 28, 2023

Language: Английский

Citations

210
Self-Assembled Monolayers for Interfacial Engineering in Solution-Processed Thin-Film Electronic Devices: Design, Fabrication, and Applications DOI
Mingliang Li, Ming Liu, Qi Feng

et al.

Chemical Reviews, Journal Year: 2024, Volume and Issue: 124(5), P. 2138 - 2204

Published: Feb. 29, 2024

Interfacial engineering has long been a vital means of improving thin-film device performance, especially for organic electronics, perovskites, and hybrid devices. It greatly facilitates the fabrication performance solution-processed devices, including field effect transistors (OFETs), solar cells (OSCs), perovskite (PVSCs), light-emitting diodes (OLEDs). However, due to limitation traditional interfacial materials, further progress these devices is hampered particularly in terms stability, flexibility, sensitivity. The deadlock gradually broken through development self-assembled monolayers (SAMs), which possess distinct benefits transparency, diversity, sensitivity, selectivity, surface passivation ability. In this review, we first showed evolution SAMs, elucidating their working mechanisms structure–property relationships by assessing wide range SAM materials reported date. A comprehensive comparison various growth, fabrication, characterization methods was presented help readers interested applying works. Moreover, recent design applications mainstream electronic OFETs, OSCs, PVSCs OLEDs, summarized. Finally, an outlook prospects section summarizes major challenges SAMs used

Language: Английский

Citations

153
Reinforcing self-assembly of hole transport molecules for stable inverted perovskite solar cells DOI
Hongcai Tang, Zhichao Shen, Yangzi Shen

et al.

Science, Journal Year: 2024, Volume and Issue: 383(6688), P. 1236 - 1240

Published: March 14, 2024

Power conversion efficiencies (PCEs) of inverted perovskite solar cells (PSCs) have been improved by the use a self-assembled monolayer (SAM) hole transport layer. Long-term stability PSCs requires keeping SAM compact under layer during operation. We found that strong polar solvents in precursor desorb if it is anchored on substrates hydrogen-bonded, rather than covalently bonded, hydroxyl groups. used atomic-layer deposition to create an indium tin oxide substrate with fully covalent hydroxyl-covered surface for anchoring, as well trimethoxysilane group exhibited tridentate anchoring substrate. The resulting achieved PCEs 24.8 (certified 24.6) and 23.2% aperture areas 0.08 1.01 square centimeters, respectively. devices retained 98.9 98.2% initial PCE after 1000 hours damp-heat test operation maximum power point tracking at 85°C 1200 standard illumination,

Language: Английский

Citations

151
Compact Hole‐Selective Self‐Assembled Monolayers Enabled by Disassembling Micelles in Solution for Efficient Perovskite Solar Cells DOI
Ming Liu, Le‐Yu Bi, Wenlin Jiang

et al.

Advanced Materials, Journal Year: 2023, Volume and Issue: 35(46)

Published: July 24, 2023

Self-assembled monolayers (SAMs) are widely employed as effective hole-selective layers (HSLs) in inverted perovskite solar cells (PSCs). However, most SAM molecules amphiphilic nature and tend to form micelles the commonly used alcoholic processing solvents. This introduces an extra energetic barrier disassemble during binding of on substrate surface, limiting formation a compact SAM. To alleviate this problem for achieving optimal growth, co-solvent strategy carbazole-based solution is developed. effectively increases critical micelle concentration be above enhances reactivity phosphonic acid anchoring group allow densely packed SAMs formed indium tin oxide. Consequently, PSCs derived from using MeO-2PACz, 2PACz, CbzNaph HSLs show universally improved performance, with SAM-derived device champion efficiency 24.98% stability.

Language: Английский

Citations

122
Recent Advances in Wide-Bandgap Organic–Inorganic Halide Perovskite Solar Cells and Tandem Application DOI Creative Commons

Ting Nie,

Zhimin Fang, Xiaodong Ren

et al.

Nano-Micro Letters, Journal Year: 2023, Volume and Issue: 15(1)

Published: March 21, 2023

Perovskite-based tandem solar cells have attracted increasing interest because of its great potential to surpass the Shockley-Queisser limit set for single-junction cells. In architectures, wide-bandgap (WBG) perovskites act as front absorber offer higher open-circuit voltage (V

Language: Английский

Citations

112
Advantages and challenges of self-assembled monolayer as a hole-selective contact for perovskite solar cells DOI Creative Commons

Songran Wang,

Huanxin Guo, Yongzhen Wu

et al.

Materials Futures, Journal Year: 2023, Volume and Issue: 2(1), P. 012105 - 012105

Published: Feb. 13, 2023

Abstract Charge-transporting layers (CTLs) are important in determining the performance and stability of perovskite solar cells (PSCs). Recently, there has been considerable use self-assembled monolayers (SAMs) as charge-selective contacts, especially for hole-selective SAMs inverted PSCs well involving tandem cells. The SAM-based contact shows many advantages over traditional thin-film organic/inorganic CTLs, including reduced cost, low optical electric loss, conformal coating on a rough substrate, simple deposition large-area substrate easy modulation energy levels, molecular dipoles surface properties. incorporation various resulted high-efficiency single junction This topical review summarizes both challenges discusses potential direction future studies.

Language: Английский

Citations

77
High Open‐Circuit Voltage (1.197 V) in Large‐Area (1 cm2) Inverted Perovskite Solar Cell via Interface Planarization and Highly Polar Self‐Assembled Monolayer DOI

Anxin Sun,

Congcong Tian,

Rongshan Zhuang

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: 14(8)

Published: Jan. 2, 2024

Abstract The efficiency loss caused by area scaling is one of the key factors hindering industrial development perovskite solar cells. energy and contact issues in buried interface are main reasons. Here, a new self‐assembled monolayer (SAM), Ph‐4PACz, with large dipole moment (2.32 D) obtained . It found that Ph‐4PACz high polarity can improve band alignment minimize , resulting an open‐circuit voltage ( V oc ) as 1.2 for 1.55 eV perovskite. However, when applied to large‐area devices, fill factor (FF) still suffered from significant attenuation. Therefore, alumina nanoparticles (Al 2 O 3 ‐NPs) introduced between rough FTO substrate further flatness conformal film almost no voids interface, thus promoting low exciton binding energy, fast hot‐carrier extraction non‐radiative recombination. final devices achieved small‐area power conversion (PCE) 25.60% (1 cm PCE 24.61% (certified at 24.48%), which represents highest single device ≥ 1 area. Additionally, mini‐modules stability testing also carried out demonstrate feasibility commercialization.

Language: Английский

Citations

77
Molecular engineering of hole-selective layer for high band gap perovskites for highly efficient and stable perovskite-silicon tandem solar cells DOI Creative Commons
Guoliang Wang, Jianghui Zheng, Weiyuan Duan

et al.

Joule, Journal Year: 2023, Volume and Issue: 7(11), P. 2583 - 2594

Published: Oct. 6, 2023

Language: Английский

Citations

64