Cited by Rapid Thermal Shutdown of Deep‐Eutectic‐Polymer Electrolyte Enabling Overheating Self‐Protection of Lithium Metal Batteries

Anode‐Free Alkali Metal Batteries: From Laboratory to Practicability DOI

Peng Xu, Fei Huang, Yanyan Sun

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(44)

Published: May 19, 2024

Abstract Anode‐free alkali metal batteries (AFAMBs) are regarded as the most promising candidates for next‐generation high‐energy systems owing to their high safety, energy density, and low cost. However, restricted supply at cathode, severe dendrite growth, unstable electrode‐electrolyte interface result in Coulombic efficiency severely short cycle life. The optimization strategies mainly based on laboratory‐level coin cells, but effectiveness practical‐level is rarely discussed. This review presents a comprehensive overview of recent developments challenges AFAMBs from laboratory toward practicability. First, advances, major challenges, systematically summarized. More significantly, given vast differences battery structures operating conditions, gap between particularly emphasized this review. In addition, failure mechanisms have been outlined key parameters affecting performance identified. Finally, insightful perspectives practical presented, aiming provide helpful guidance subsequent basic research promote large‐scale commercial applications AFAMBs.

Language: Английский

Citations

Characterizing Electrode Materials and Interfaces in Solid-State Batteries DOI

Elif Pınar Alsaç, Douglas Lars Nelson, Sun Geun Yoon

et al.

Chemical Reviews, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 4, 2025

Solid-state batteries (SSBs) could offer improved energy density and safety, but the evolution degradation of electrode materials interfaces within SSBs are distinct from conventional with liquid electrolytes represent a barrier to performance improvement. Over past decade, variety imaging, scattering, spectroscopic characterization methods has been developed or used for characterizing unique aspects in SSBs. These efforts have yielded new understanding behavior lithium metal anodes, alloy composite cathodes, these various solid-state (SSEs). This review provides comprehensive overview strategies applied SSBs, it presents mechanistic SSB that derived methods. knowledge critical advancing technology will continue guide engineering toward practical performance.

Language: Английский

Citations

Decoupled Ion Transport via Triadic Molecular Synergy in Flame‐Retardant Quasi‐Solid Electrolytes for Safe Lithium Metal Batteries DOI

Kun Li, Anjun Hu,

Ruizhe Xu

et al.

Advanced Energy Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 16, 2025

Abstract Ionic liquids (IL)‐based quasi‐solid polymer electrolytes (QSPEs) hold promise for safe lithium metal batteries owing to their tunable electrochemical properties and processability. However, traditional design strategy has ignored the interdependencies among “component‐function‐interface”, leading compromised practical applications hindered by sluggish lithium‐ion transport kinetics safety concerns. Herein, a triadic molecular synergy paradigm is proposed decouple conduction mechanisms in flame‐retardant QSPEs. Pentaerythritol tetraacrylate‐lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) provides structural framework, while IL (1‐butyl‐3‐methylimidazole bis (trifluoromethylsulfonyl) imide, BmimTFSI) as plasticizer softens chains weakening intermolecular forces provide an additional ion‐transport pathway imparting properties. Additionally, highly electronegative fluorine atoms of additive (2‐(perfluorohexyl)ethyl methacrylate, PFMA) promote LiTFSI dissociation through electron cloud migration, simultaneously immobilizing TFSI⁻ anions suppressing cationic competition strong PFMA−Bmim + coordination. As proof‐of‐concept, this synergistic achieves high transference number (0.72), forms stable fluoride‐dominated interphases, enhances battery via condensed‐phase mechanism. Experimental validation demonstrates that designed electrolyte significantly cycling stability Li symmetric cells, Li||LiFePO 4 Li||LiNi 0.8 Co 0.1 Mn O 2 cells. The engineering establishes developing high‐performance QSPEs batteries.

Language: Английский

Citations

Host–Guest Inversion Engineering Induced Superionic Composite Solid Electrolytes for High-Rate Solid-State Alkali Metal Batteries DOI

Xiong Xiong Liu, Long Pan, Haotian Zhang

et al.

Nano-Micro Letters, Journal Year: 2025, Volume and Issue: 17(1)

Published: March 17, 2025

Abstract Composite solid electrolytes (CSEs) are promising for solid-state Li metal batteries but suffer from inferior room-temperature ionic conductivity due to sluggish ion transport and high cost expensive active ceramic fillers. Here, a host–guest inversion engineering strategy is proposed develop superionic CSEs using cost-effective SiO 2 nanoparticles as passive hosts poly(vinylidene fluoride-hexafluoropropylene) (PVH) microspheres polymer guests, forming an unprecedented “polymer guest-in-ceramic host” (i.e., PVH-in-SiO ) architecture differing the traditional “ceramic guest-in-polymer host”. The exhibits excellent Li-salt dissociation, achieving high-concentration free + . Owing low diffusion energy barriers coefficient, thermodynamically kinetically favorable migrate at /PVH interfaces. Consequently, delivers exceptional of 1.32 × 10 −3 S cm −1 25 °C (vs typically −5 –10 −4 high-cost ceramics), achieved under ultralow residual solvent content 2.9 wt% 8–15 in other CSEs). Additionally, electrochemically stable with anode various cathodes. Therefore, demonstrates high-rate cyclability LiFePO 4 |Li full cells (92.9% capacity-retention 3C after 300 cycles °C) outstanding stability high-mass-loading (9.2 mg high-voltage NCM622 (147.1 mAh g ). Furthermore, we verify versatility by fabricating Na-ion K-ion-based similarly promotions conductivity. Our offers simple, low-cost approach large-scale application beyond.

Language: Английский

Citations

Tailoring Stable PEO‐Based Electrolyte/Electrodes Interfaces via Molecular Coordination Regulating Enables 4.5 V Solid‐State Lithium Metal Batteries DOI

Chaowei He,

Hangjun Ying,

Lucheng Cai

et al.

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 13, 2024

Abstract Solid‐state lithium metal batteries (SSLMBs) with poly (ethylene oxide) (PEO)‐based electrolytes have increasingly become one of the most promising battery technologies due to high energy density and safety. However, adverse electrode/electrolyte interface compatibility issues hinder further application. Herein, a PEO‐based composite solid electrolyte excellent anode cathode interfacial is designed via coordination modulation strategy induced by difluorobis(oxalato)phosphate (DFBOP). By utilizing this electrolyte, robust inorganic‐rich interphase involving LiF, Li x PO y F z , P─O components in situ generated on (Li) LiNi 0.8 Co 0.1 Mn O 2 (NCM811) surfaces forceful among PEO, bis(trifluoromethanesulphonyl)imide, DFBOP subsequent adjustment front orbital levels. It contributes homogeneous deposition an effective impediment PEO oxidation decomposition at voltage, promoting superior stability. Consequently, Li‐symmetric cells modified can achieve stable cycle over 7000 h 0.2 mA cm −2 . Specially, unique organic–inorganic interpenetration network structure enables 4.5 V Li/NCM811 steadily 100 cycles, discharge capacity 215.4 mAh g −1 initial coulombic efficiency 91.23%. This research has shed light design from perspective regulation construct high‐performance SSLMBs.

Language: Английский

Citations

Recent progress of thin solid-state electrolytes and applications for solid-state lithium pouch cells DOI

Zhihao Guo,

Huan Zhao,

Yiyang Xiao

et al.

Materials Today Energy, Journal Year: 2025, Volume and Issue: 48, P. 101801 - 101801

Published: Jan. 9, 2025

Language: Английский

Citations

Fatigue of Li metal anode in solid-state batteries DOI

Tengrui Wang, Bo Chen, Yijie Liu

et al.

Science, Journal Year: 2025, Volume and Issue: 388(6744), P. 311 - 316

Published: April 17, 2025

Solid-state lithium metal batteries (SSBs) are promising for electric vehicles because of their potential to provide high energy density and enhanced safety. However, these face short-circuit challenges caused by uncontrolled dendrite growth during cycling. Using operando scanning electron microscopy phase-field simulations, we determined that failure SSBs is closely linked the fatigue anode, which markedly contributes interface degradation in SSBs. This follows Coffin-Manson equation mechanics, indicating it an innate characteristic. Clarifying essential role provides a physical basis understanding failures paves way extending lifespan.

Language: Английский

Citations

Developing Cathode Films for Practical All‐Solid‐State Lithium‐Sulfur Batteries DOI

Chao Ye, Shijie Xu, Huan Li

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: unknown

Published: July 29, 2024

Abstract The development of all‐solid‐state lithium‐sulfur batteries (ASSLSBs) toward large‐scale electrochemical energy storage is driven by the higher specific energies and lower cost in comparison with state‐of‐the‐art Li‐ion batteries. Yet, insufficient mechanistic understanding quantitative parameters key components sulfur‐based cathode hinders advancement ASSLSB technologies. This review offers a comprehensive analysis electrode parameters, including capacity, voltage, S mass loading content establishing (Wh kg −1 ) density L ASSLSBs. Additionally, this work critically evaluates progress enhancing lithium ion electron percolation mitigating electrochemical‐mechanical degradation cathodes. Last, critical outlook on potential future research directions provided to guide rational design high‐performance cathodes practical

Language: Английский

Citations

Versatile polymer-supported argyrodite-type sulfide solid electrolyte membranes for energy-dense lithium batteries DOI

Yijie Yan,

Shuxian Zhang, Qingyu Li

et al.

Materials Science and Engineering R Reports, Journal Year: 2025, Volume and Issue: 163, P. 100941 - 100941

Published: Feb. 1, 2025

Citations

Ductile Inorganic Solid Electrolytes for All-Solid-State Lithium Batteries DOI

Tao Yu,

Yuankai Liu,

Haoyu Li

et al.

Chemical Reviews, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 11, 2025

Solid electrolytes, as the core of all-solid-state batteries (ASSBs), play a crucial role in determining kinetics ion transport and interface compatibility with cathodes anodes, which can be subdivided into catholytes, bulk anolytes based on their functional characteristics. Among various inorganic solid ductile distinguished from rigid oxide exhibit excellent properties even under cold pressing, thus holding greater promise for industrialization. However, challenge lies finding electrolyte that simultaneously serve catholyte, electrolyte, anolyte. Fortunately, due to immobility combining multiple types electrolytes allows leveraging respective advantages. In this review, we discuss five sulfides, halides, nitrides, antiperovskite-type, complex hydrides, challenges superiorities these are also addressed. The impact pressure ASSBs has been systematically discussed. Furthermore, suitability anolyte is discussed characteristics physicochemical properties. This discussion aims deepen our understanding enabling us harness advantages develop practical, high-performance ASSBs.

Language: Английский

Citations