Abstract
Methane
(CH
4
)
emission
reduction
to
limit
warming
1.5
°C
can
be
tracked
by
analyzing
CH
concentration
and
its
isotopic
composition
(
δ
13
C,
D)
simultaneously.
Based
on
reconstructions
of
the
temporal
trends,
latitudinal,
vertical
gradient
C
from
1985
2020
using
an
atmospheric
chemistry
transport
model,
we
show
(1)
reductions
oil
gas
exploitation
(ONG)
since
1990s
stabilized
growth
rate
in
late
early
2000s,
(2)
emissions
farmed
animals,
waste
management,
coal
mining
contributed
increase
2006.
Our
findings
support
neither
increasing
ONG
reported
EDGARv6
inventory
during
1990–2020
nor
large
unconventional
GAINSv4
Total
fossil
fuel
remained
stable
2000
2020,
most
likely
because
decrease
some
regions
offset
China.
Earth system science data,
Journal Year:
2023,
Volume and Issue:
15(6), P. 2295 - 2327
Published: June 6, 2023
Abstract.
Intergovernmental
Panel
on
Climate
Change
(IPCC)
assessments
are
the
trusted
source
of
scientific
evidence
for
climate
negotiations
taking
place
under
United
Nations
Framework
Convention
(UNFCCC),
including
first
global
stocktake
Paris
Agreement
that
will
conclude
at
COP28
in
December
2023.
Evidence-based
decision-making
needs
to
be
informed
by
up-to-date
and
timely
information
key
indicators
state
system
human
influence
system.
However,
successive
IPCC
reports
published
intervals
5–10
years,
creating
potential
an
gap
between
report
cycles.
We
follow
methods
as
close
possible
those
used
Sixth
Assessment
Report
(AR6)
Working
Group
One
(WGI)
report.
compile
monitoring
datasets
produce
estimates
related
forcing
system:
emissions
greenhouse
gases
short-lived
forcers,
gas
concentrations,
radiative
forcing,
surface
temperature
changes,
Earth's
energy
imbalance,
warming
attributed
activities,
remaining
carbon
budget,
extremes.
The
purpose
this
effort,
grounded
open
data,
science
approach,
is
make
annually
updated
reliable
available
public
domain
(https://doi.org/10.5281/zenodo.8000192,
Smith
et
al.,
2023a).
As
they
traceable
methods,
can
all
parties
involved
UNFCCC
help
convey
wider
understanding
latest
knowledge
its
direction
travel.
show
human-induced
reached
1.14
[0.9
1.4]
∘C
averaged
over
2013–2022
decade
1.26
[1.0
1.6]
2022.
Over
period,
has
been
increasing
unprecedented
rate
0.2
per
decade.
This
high
caused
a
combination
being
all-time
54
±
5.3
GtCO2e
last
decade,
well
reductions
strength
aerosol
cooling.
Despite
this,
there
increases
have
slowed,
depending
societal
choices,
continued
series
these
annual
updates
critical
2020s
could
track
change
climate.
Nature Climate Change,
Journal Year:
2023,
Volume and Issue:
13(5), P. 430 - 433
Published: March 20, 2023
Abstract
The
positive
response
of
wetland
methane
(CH
4
)
emissions
to
climate
change
is
an
important
yet
uncertain
Earth-system
feedback
that
amplifies
atmospheric
CH
concentrations.
Here,
using
a
model,
we
report
intensified
during
2000–2021,
corresponding
with
2020
and
2021
being
exceptional
years
growth.
Our
results
highlight
the
need
for
sustained
monitoring
observations
global
fluxes
document
emerging
trends,
variability
underlying
drivers.
Earth system science data,
Journal Year:
2024,
Volume and Issue:
16(6), P. 2625 - 2658
Published: June 4, 2024
Abstract.
Intergovernmental
Panel
on
Climate
Change
(IPCC)
assessments
are
the
trusted
source
of
scientific
evidence
for
climate
negotiations
taking
place
under
United
Nations
Framework
Convention
(UNFCCC).
Evidence-based
decision-making
needs
to
be
informed
by
up-to-date
and
timely
information
key
indicators
state
system
human
influence
global
system.
However,
successive
IPCC
reports
published
at
intervals
5–10
years,
creating
potential
an
gap
between
report
cycles.
We
follow
methods
as
close
possible
those
used
in
Sixth
Assessment
Report
(AR6)
Working
Group
One
(WGI)
report.
compile
monitoring
datasets
produce
estimates
related
forcing
system:
emissions
greenhouse
gases
short-lived
forcers,
gas
concentrations,
radiative
forcing,
Earth's
energy
imbalance,
surface
temperature
changes,
warming
attributed
activities,
remaining
carbon
budget,
extremes.
The
purpose
this
effort,
grounded
open-data,
open-science
approach,
is
make
annually
updated
reliable
available
public
domain
(https://doi.org/10.5281/zenodo.11388387,
Smith
et
al.,
2024a).
As
they
traceable
methods,
can
all
parties
involved
UNFCCC
help
convey
wider
understanding
latest
knowledge
its
direction
travel.
show
that,
2014–2023
decade
average,
observed
was
1.19
[1.06
1.30]
°C,
which
[1.0
1.4]
°C
human-induced.
For
single-year
human-induced
reached
1.31
[1.1
1.7]
2023
relative
1850–1900.
best
estimate
below
2023-observed
record
1.43
[1.32
1.53]
indicating
a
substantial
contribution
internal
variability
record.
Human-induced
has
been
increasing
rate
that
unprecedented
instrumental
record,
reaching
0.26
[0.2–0.4]
per
over
2014–2023.
This
high
caused
combination
net
being
persistent
53±5.4
Gt
CO2e
yr−1
last
decade,
well
reductions
strength
aerosol
cooling.
Despite
this,
there
increase
CO2
slowed
compared
2000s,
depending
societal
choices,
continued
series
these
annual
updates
critical
2020s
could
track
change
some
presented
here.
Global Biogeochemical Cycles,
Journal Year:
2023,
Volume and Issue:
37(8)
Published: July 15, 2023
Abstract
Atmospheric
methane's
rapid
growth
from
late
2006
is
unprecedented
in
the
observational
record.
Assessment
of
atmospheric
methane
data
attributes
a
large
fraction
this
to
increased
natural
emissions
over
tropics,
which
appear
be
responding
changes
anthropogenic
climate
forcing.
Isotopically
lighter
measurements
are
consistent
with
recent
being
mainly
driven
by
an
increase
microbial
sources,
particularly
wetlands.
The
global
budget
currently
disequilibrium
and
new
inputs
as
yet
poorly
quantified.
Although
agriculture
waste
sources
have
between
2022
perhaps
35
Tg/yr,
wide
uncertainty,
approximately
another
35–45
Tg/yr
net
may
been
biogenic
processes,
especially
wetland
feedbacks
change.
A
model
comparison
shows
that
comparable
or
greater
scale
speed
than
isotopic
shift
during
past
glacial/interglacial
termination
events.
It
remains
possible
current
within
range
Holocene
variability,
but
it
also
indicate
large‐scale
reorganization
biosphere
under
way.
Atmospheric chemistry and physics,
Journal Year:
2023,
Volume and Issue:
23(8), P. 4863 - 4880
Published: April 25, 2023
Abstract.
The
global
atmospheric
methane
growth
rates
reported
by
NOAA
for
2020
and
2021
are
the
largest
since
systematic
measurements
began
in
1983.
To
explore
underlying
reasons
these
anomalous
rates,
we
use
newly
available
data
from
Japanese
Greenhouse
gases
Observing
SATellite
(GOSAT)
to
estimate
surface
emissions.
Relative
baseline
values
2019,
find
that
a
significant
increase
emissions
of
27.0
±
11.3
20.8
11.4
Tg
is
needed
reproduce
observed
2021,
respectively,
assuming
fixed
climatological
OH.
We
see
annual
increases
during
over
Eastern
Africa
(14
3
Tg),
tropical
Asia
(3
4
South
America
(5
temperate
Eurasia
reductions
China
(−6
Tg)
India
(−2
Tg).
comparable
emission
changes
relative
except
where
increased
9
Tg,
North
5
2
Tg.
elevated
contributions
saw
western
half
(−5
substantially
reduced
compared
our
2019
baseline.
statistically
positive
correlations
between
anomalies
groundwater,
consistent
with
recent
studies
have
highlighted
growing
role
microbial
sources
tropics.
Emission
expected
due
Covid-19
lockdown
but
continued
which
do
not
currently
understand.
investigate
OH
concentrations
on
2020–2021,
extended
inversion
state
vector
include
monthly
scaling
factors
six
latitude
bands.
During
2020,
tropospheric
1.4
1.7
%
corresponding
value.
revised
posteriori
decreased
34
17.9
13.2
value
inferred
using
values,
sensitivity
tests
climatology
counter
statement
66
was
emissions,
particularly
regions.
Regional
flux
differences
joint
methane–OH
typically
much
smaller
than
10
%.
amount
representing
about
year.
Therefore,
conclude
most
contribution
levels
Abstract
The
atmospheric
methane
trend
is
not
fully
understood.
Here
we
investigate
the
role
of
main
sink,
natural
source,
and
anthropogenic
emissions
on
growth
rate
over
last
three
decades
using
numerical
models
emission
inventories.
We
find
that
long-term
driven
by
increased
emissions,
while
wetland
show
large
variability
can
modify
trend.
influence
hydroxyl
radical,
through
nitrogen
oxides
carbon
monoxide
has
modified
contributed
to
stabilization
from
2000
2007.
radical
increase
prior
this
period
might
have
decline
in
isotopic
ratio
after
2007
due
time
dependent
response
radical.
Emission
reductions
COVID-19
restrictions
via
possibly
approximately
two
thirds
2019
2020.
Nature Climate Change,
Journal Year:
2024,
Volume and Issue:
14(3), P. 282 - 288
Published: Feb. 14, 2024
Abstract
Wetland
methane
(CH
4
)
emissions
over
the
Boreal–Arctic
region
are
vulnerable
to
climate
change
and
linked
feedbacks,
yet
understanding
of
their
long-term
dynamics
remains
uncertain.
Here,
we
upscaled
analysed
two
decades
(2002–2021)
wetland
CH
emissions,
representing
an
unprecedented
compilation
eddy
covariance
chamber
observations.
We
found
a
robust
increasing
trend
(+8.9%)
with
strong
inter-annual
variability.
The
majority
emission
increases
occurred
in
early
summer
(June
July)
were
mainly
driven
by
warming
(52.3%)
ecosystem
productivity
(40.7%).
Moreover,
2
°C
temperature
anomaly
2016
led
highest
recorded
annual
(22.3
Tg
yr
−1
this
region,
primarily
high
Western
Siberian
lowlands.
However,
current-generation
models
from
Global
Carbon
Project
failed
capture
magnitude
trend,
may
bias
estimates
future
amplified
greening.
Journal of Geophysical Research Biogeosciences,
Journal Year:
2024,
Volume and Issue:
129(3)
Published: Feb. 26, 2024
Abstract
Significant
progress
in
permafrost
carbon
science
made
over
the
past
decades
include
identification
of
vast
stocks,
development
new
pan‐Arctic
maps,
an
increase
terrestrial
measurement
sites
for
CO
2
and
methane
fluxes,
important
factors
affecting
cycling,
including
vegetation
changes,
periods
soil
freezing
thawing,
wildfire,
other
disturbance
events.
Process‐based
modeling
studies
now
key
elements
cycling
advances
statistical
inverse
enhance
understanding
region
C
budgets.
By
combining
existing
data
syntheses
model
outputs,
is
likely
a
wetland
source
small
ecosystem
sink
with
lower
net
uptake
toward
higher
latitudes,
excluding
wildfire
emissions.
For
2002–2014,
strongest
was
located
western
Canada
(median:
−52
g
m
−2
y
−1
)
smallest
sinks
Alaska,
Canadian
tundra,
Siberian
tundra
(medians:
−5
to
−9
).
Eurasian
regions
had
largest
median
fluxes
(16–18
CH
4
Quantifying
regional
scale
balance
remains
challenging
because
high
spatial
temporal
variability
relatively
low
density
observations.
More
accurate
require:
(a)
better
maps
characterizing
wetlands
dynamics
disturbances,
abrupt
thaw;
(b)
establishment
year‐round
flux
underrepresented
areas;
(c)
improved
models
that
represent
cycle
dynamics,
non‐growing
season
emissions
effects.
Nature Communications,
Journal Year:
2024,
Volume and Issue:
15(1)
Published: Feb. 22, 2024
Abstract
Hydroxyl
radicals
(OH)
determine
the
tropospheric
self-cleansing
capacity,
thus
regulating
air
quality
and
climate.
However,
state-of-the-art
mechanisms
still
underestimate
OH
at
low
nitrogen
oxide
high
volatile
organic
compound
regimes
even
considering
latest
isoprene
chemistry.
Here
we
propose
that
reactive
aldehyde
chemistry,
especially
autoxidation
of
carbonyl
peroxy
(R(CO)O
2
)
derived
from
higher
aldehydes,
is
a
noteworthy
regeneration
mechanism
overwhelms
contribution
autoxidation,
latter
has
been
proved
to
largely
contribute
missing
source
under
condition.
As
diagnosed
by
quantum
chemical
calculations,
R(CO)O
undergo
fast
H-migration
produce
unsaturated
hydroperoxyl-carbonyls
generate
through
rapid
photolysis.
This
chemistry
could
explain
almost
all
unknown
sources
in
areas
rich
both
natural
anthropogenic
emissions
warm
seasons,
may
increasingly
impact
global
capacity
future
society
carbon
neutrality
scenarios.