A novel design of a mesoporous Li2MnO3/YVO4 step-scheme heterostructure photocatalyst to promote visible-light-mediated reduction of venomous Hg2+ ions from aquatic solution
Materials Science in Semiconductor Processing,
Journal Year:
2024,
Volume and Issue:
182, P. 108723 - 108723
Published: July 24, 2024
Language: Английский
Kinetics of Periodate-Mediated Oxidation of Cellulose
Nazmun Sultana,
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Ulrica Edlund,
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Chandan Guria
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et al.
Polymers,
Journal Year:
2024,
Volume and Issue:
16(3), P. 381 - 381
Published: Jan. 30, 2024
The
oxidation
of
cellulose
to
dialdehyde
(DAC)
is
a
process
that
has
received
increased
interest
during
recent
years.
Herein,
kinetic
modeling
the
reaction
with
sodium
periodate
as
an
oxidizing
agent
was
performed
quantify
rate-limiting
steps
and
overall
kinetics
reaction.
Considering
pseudo-first-order
reaction,
general
rate
expression
derived
elucidate
impact
pH,
concentration,
temperature
on
concurrent
formation
degradation
products.
Experimental
concentration
profiles
were
utilized
determine
constants
for
DAC
(k1),
constant
(k2),
(k3),
confirming
follows
Notably,
increase
in
more
pronounced
effect
k1
compared
influence
IO4−
concentration.
In
contrast,
k2
k3
display
minimal
changes
response
but
significantly
increasing
temperature.
model
developed
may
help
understanding
providing
valuable
information
optimizing
toward
faster
higher
yield
target
product.
Language: Английский
Tailoring of spherical nanocellulose via esterification with methionine followed by protonation to generate two different adsorbents for mercuric ions and Congo red
International Journal of Biological Macromolecules,
Journal Year:
2024,
Volume and Issue:
279, P. 135313 - 135313
Published: Sept. 4, 2024
Language: Английский
Long-lasting, UV shielding, and cellulose-based avermectin nano/micro spheres with dual smart stimuli-microenvironment responsiveness for Plutella xylostella control
Haonan Zhang,
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Bin Yu,
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Yun Fang
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et al.
Carbohydrate Polymers,
Journal Year:
2024,
Volume and Issue:
345, P. 122553 - 122553
Published: Aug. 2, 2024
Language: Английский
Sequestration of Cr(VI) onto polyethyleneimine-derivatized cellulose and its effect on the enzymatic degradation and microbiome viability
M P Hibakhadeeja,
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Anindita Thakur,
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Alexander J. Mathews
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et al.
International Journal of Biological Macromolecules,
Journal Year:
2025,
Volume and Issue:
297, P. 139915 - 139915
Published: Jan. 15, 2025
Language: Английский
Design, spectroscopic analysis, DFT calculations, adsorption evaluation, molecular docking, comprehensive in silico and in vitro bioactivity studies of thiocarbohydrazide grafted dialdehyde cellulose nanobiosorbent
Magda A. Akl,
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Aya G. Mostafa,
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Abdelrahman S. El-Zeny
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et al.
Scientific Reports,
Journal Year:
2025,
Volume and Issue:
15(1)
Published: April 17, 2025
Abstract
Heavy
metals
have
attracted
considerable
attention
lately
because
of
their
widespread
occurrence
in
aquatic
environments
and
potential
biological
toxicity
to
animals
human.
The
current
investigation
focused
on
synthesizing
the
DAC@TCH
nanobiosorbent
by
coupling
dialdehyde
cellulose
with
thiocarbohydrazide
ligand.
Subsequent
characterization
was
carried
out
utilizing
various
analytical
methods
such
as
elemental
analysis,
scanning
electron
microscopy
(SEM),
transmission
(TEM),
Fourier
transform
infrared
(FT-IR),
thermogravimetric
analysis
(TGA
DTA).
DFT
calculations
were
utilized
verify
molecular
structure,
frontier
orbitals
(FMOs),
electrostatic
(MEP)
reactivity
descriptor
for
all
phases.
In
vitro
experiments
conducted
evaluate
properties
nanobiosorbent.
These
findings
revealed
that
synthesized
has
been
observed
show
effective
antibacterial
IZD
value
against
E.
Coli
(28
mm)
which
is
superior
efficacy
standard
drug
amoxicillin
used
(5
mm).
Furthermore,
silico
activities
(molecular
docking)
indicated
this
exhibit
excellent
docking
score
(
−
7.4237
kcal/mol)
(−7.1325
S.
aureus
and,
coli,
respectively.
Meanwhile
binding
energies
(best
scores)
kcal/mol
Amoxicillin
are
(−5.8090)
(−6.7442)
Drug-likeness
rules
like
Lipinski’s,
Veber’s
Egan’s
considered
a
more
comprehensive
evaluation.
prepared
investigated
its
adsorb
metal
ions
(Ag
+
,
Hg
2+
Cu
)
from
diverse
water
samples.
Optimal
conditions
including
pH,
temperature,
dosage,
oscillation
time,
initial
ion
concentration,
interference
other
explored.
adsorption
Ag
followed
pseudo-second-order
kinetics
Langmuir
isothermal
model,
achieving
maximum
capacities
196
mg/g
190
73
.
process
determined
be
exothermic
spontaneous
across
varying
temperatures.
Additionally,
over
95%
adsorbed
effectively
desorbed
using
thiourea
(5%)
0.3
M
HNO
3
elution
mixture.
demonstrated
reusability,
retaining
capacity
through
five
cycles
without
degradation.
study
highlights
efficient
recovery
heavy
different
sources,
considering
application
versatility,
minimal
interference.
plausible
mechanism
onto
bionanosorbent
elucidated.
Language: Английский
Novel sulfonic groups grafted sugarcane bagasse biosorbent for efficient removal of cationic dyes from wastewater
Scientific Reports,
Journal Year:
2024,
Volume and Issue:
14(1)
Published: Aug. 19, 2024
In
this
research,
we
reported
the
synthesis
of
effective
sulphonated
sugarcane
bagasse
(SCB@SA)
biosorbent
based
on
agriculture
waste
materials
via
a
simple
diazotization
strategy
for
removal
methylene
blue
(MB)
and
Bismarck
Brown
R(BB)
dyes
from
water
samples.
First,
(SCB)
was
collected,
grinded,
sieved
to
obtain
desired
size.
Secondly,
SCB
powder
is
modified
with
sulfanilinic
acid
(SA)
formation
its
diazonium
salt
introduce
sulfonic
groups
surface.
Different
advanced
techniques
were
applied
characterize
prepared
before
after
adsorption
process
viz.
Scanning
electron
microscopy
(SEM),
transmission
(TEM),
Fourier
transform
infrared
spectroscopy
(FTIR),
X-ray
diffraction
(XRD),
Energy-dispersive
(EDS)
Thermogravimetric
analysis
(TGA).
parameters
affecting
both
MB
BB
studied.
Because
higher
correlation
coefficient
(R
Language: Английский
Chitosan impregnated sugarcane bagasse biochar for removal of anionic dyes from wastewater
Magda A. Akl,
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Asmaa A. Serage
No information about this author
Scientific Reports,
Journal Year:
2024,
Volume and Issue:
14(1)
Published: Nov. 7, 2024
Wastewater
treatment
is
of
utmost
importance
in
providing
all
equitable
and
safe
drinking
water.
In
the
present
study,
a
chitosan
impregnated
sugarcane
bagasse
biochar
SCNC
biocomposite
has
been
synthesized
for
removal
Congo
red
(CR)
dye
from
an
aqueous
solution.
The
was
thoroughly
characterized
through
Brunauer,
Emmett
Teller
(BET)
N
Language: Английский