Advanced Energy Materials,
Journal Year:
2021,
Volume and Issue:
12(4)
Published: March 19, 2021
Abstract
Metal‐organic
frameworks
(MOFs)
and
covalent‐organic
(COFs)
are
two
emerging
families
of
functional
materials
used
in
many
fields.
Advantages
both
include
compositional
designability,
structural
diversity,
high
porosity,
which
offer
immense
possibilities
the
search
for
high‐performance
electrode
metal‐ion
batteries.
A
large
number
MOF/COF‐based
cathode
have
been
reported.
Despite
these
advantageous
features
research
advances,
MOFs/COFs
their
derivatives
face
various
challenges
as
materials.
In
this
review,
an
overview
progress
cathodes
advanced
batteries
is
presented,
including
lithium‐ion
other
nascent
technologies,
such
sodium‐ion
batteries,
zinc‐ion
aluminum‐ion
magnesium‐ion
Research
advances
on
summarized
terms
active
sites,
design,
protective
coatings.
Perspectives
directions
future
development
outlined
meeting
requirements
practical
applications.
Chemical Reviews,
Journal Year:
2021,
Volume and Issue:
121(20), P. 12278 - 12326
Published: July 19, 2021
Metal-organic
frameworks
(MOFs)
have
been
widely
recognized
as
one
of
the
most
fascinating
classes
materials
from
science
and
engineering
perspectives,
benefiting
their
high
porosity
well-defined
tailored
structures
components
at
atomic
level.
Although
intrinsic
micropores
endow
size-selective
capability
surface
area,
etc.,
narrow
pores
limit
applications
toward
diffusion-control
large-size
species
involved
processes.
In
recent
years,
construction
hierarchically
porous
MOFs
(HP-MOFs),
MOF-based
composites,
derivatives
has
captured
widespread
interest
to
extend
conventional
materials.
this
Review,
advances
in
design,
synthesis,
functional
are
summarized.
Their
structural
characters
various
applications,
including
catalysis,
gas
storage
separation,
air
filtration,
sewage
treatment,
sensing
energy
storage,
demonstrated
with
typical
reports.
The
comparison
HP-MOFs
traditional
(e.g.,
zeolite,
silica,
carbons,
metal
oxides,
polymers),
subsisting
challenges,
well
future
directions
research
field,
also
indicated.
Chemical Society Reviews,
Journal Year:
2020,
Volume and Issue:
49(17), P. 6364 - 6401
Published: Jan. 1, 2020
Developing
efficient
sensor
materials
with
superior
performance
for
selective,
fast
and
sensitive
detection
of
gases
volatile
organic
compounds
(VOCs)
is
essential
human
health
environmental
protection,
through
monitoring
indoor
outdoor
air
pollutions,
managing
industrial
processes,
controlling
food
quality
assisting
early
diagnosis
diseases.
Metal-organic
frameworks
(MOFs)
are
a
unique
type
crystalline
porous
solid
material
constructed
from
metal
nodes
(metal
ions
or
clusters)
functional
ligands.
They
have
been
investigated
extensively
possible
use
as
high
sensors
the
many
different
VOCs
in
recent
years,
due
to
their
large
surface
area,
tunable
pore
size,
functionalizable
sites
intriguing
properties,
such
electrical
conductivity,
magnetism,
ferroelectricity,
luminescence
chromism.
The
porosity
MOFs
allows
them
interact
strongly
various
analytes,
including
VOCs,
thus
resulting
easily
measurable
responses
physicochemical
parameters.
Although
much
work
on
MOF-based
luminescent
summarized
several
excellent
reviews
(up
2018),
comprehensive
overview
these
sensing
based
chemiresistive,
magnetic,
ferroelectric,
colorimertic
mechanisms
missing.
In
this
review,
we
highlight
most
progress
developing
MOF
switching
an
emphasis
electricity,
ferroelectricity
We
provide
analysis
MOF-analyte
interactions
which
play
key
role
switches.
discuss
detail
applications
detecting
oxygen,
water
vapor,
toxic
(such
hydrogen
sulfide,
ammonia,
sulfur
dioxide,
nitrous
oxide,
carbon
oxides
disulfide)
aromatic
aliphatic
hydrocarbons,
ketones,
alcohols,
aldehydes,
chlorinated
hydrocarbons
N,N'-dimethylformamide).
Overall,
review
serves
timely
source
information
provides
insight
future
development
advanced
next-generation
gas
VOC
sensors.
Chemical Reviews,
Journal Year:
2021,
Volume and Issue:
121(7), P. 3751 - 3891
Published: Feb. 25, 2021
Among
the
recent
developments
in
metal-organic
frameworks
(MOFs),
porous
layered
coordination
polymers
(CPs)
have
garnered
attention
due
to
their
modular
nature
and
tunable
structures.
These
factors
enable
a
number
of
properties
applications,
including
gas
guest
sorption,
storage
separation
gases
small
molecules,
catalysis,
luminescence,
sensing,
magnetism,
energy
conversion.
MOFs,
two-dimensional
(2D)
compounds
are
also
known
as
2D
CPs
or
MOFs.
Since
discovery
graphene
2004,
materials
been
widely
studied.
Several
MOFs
suitable
for
exfoliation
ultrathin
nanosheets
similar
other
materials,
making
these
structures
useful
unique
various
technological
applications.
Furthermore,
fascinating
topological
networks
entanglements.
This
review
provides
an
overview
different
aspects
MOF
architectures
such
topology,
interpenetration,
structural
transformations,
properties,
Energy & Environmental Science,
Journal Year:
2021,
Volume and Issue:
14(4), P. 2186 - 2243
Published: Jan. 1, 2021
The
limited
resources
and
uneven
distribution
of
lithium
stimulate
strong
motivation
to
develop
new
rechargeable
potassium-ion
batteries
that
use
alternative
charge
carriers.
Angewandte Chemie International Edition,
Journal Year:
2022,
Volume and Issue:
61(11)
Published: Jan. 10, 2022
In
this
study,
we
propose
a
versatile
method
for
synthesizing
uniform
three-dimensional
(3D)
metal
carbides,
nitrides,
and
carbonitrides
(MXenes)/metal-organic
frameworks
(MOFs)
composites
(Ti3
C2
TX
/Cu-BTC,
Ti3
/Fe,Co-PBA,
/ZIF-8,
/ZIF-67)
that
combine
the
advantages
of
MOFs
MXenes
to
enhance
stability
improve
conductivity.
Subsequently,
3D
hollow
/ZIF-67/CoV2
O6
with
excellent
electron-
ion-transport
properties
derived
from
/ZIF-67
were
synthesized.
The
specific
capacitance
electrode
was
285.5
F
g-1
,
which
is
much
higher
than
ZIF-67
electrode.
This
study
opens
new
avenue
design
synthesis
MXene/MOF
complex
structures
tailorable
compositions
various
applications.
Chemical Society Reviews,
Journal Year:
2021,
Volume and Issue:
50(4), P. 2663 - 2695
Published: Jan. 1, 2021
This
review
summarizes
the
recent
progress
on
MOFs
and
their
derivatives
used
for
OER
electrocatalysis
in
terms
of
morphology,
composition
structure–performance
relationship.
Chemical Reviews,
Journal Year:
2020,
Volume and Issue:
120(23), P. 13087 - 13133
Published: Oct. 13, 2020
Metal-organic
frameworks
(MOFs),
constructed
from
organic
linkers
and
inorganic
building
blocks,
are
well-known
for
their
high
crystallinity,
surface
areas,
component
tunability.
The
stability
of
MOFs
is
a
key
prerequisite
potential
practical
applications
in
areas
including
storage,
separation,
catalysis,
biomedicine
since
it
essential
to
guarantee
the
framework
integrity
during
utilization.
However,
prone
destruction
under
external
stimuli,
considerably
hampering
commercialization.
In
this
Review,
we
provide
an
overview
situations
where
undergo
due
stimuli
such
as
chemical,
thermal,
photolytic,
radiolytic,
electronic,
mechanical
factors
offer
guidelines
avoid
unwanted
degradation
happened
framework.
Furthermore,
discuss
possible
mechanisms
varying
derived
products.
particular,
highlight
cases
that
utilize
MOF
instability
fabricate
materials
hierarchically
porous
MOFs,
monolayer
nanosheets,
amorphous
liquids
glasses,
polymers,
metal
nanoparticles,
carbide
carbon
materials.
Finally,
perspective
on
utilization
develop
advanced
with
superior
hierarchy
various
applications.
Advanced Materials,
Journal Year:
2021,
Volume and Issue:
33(45)
Published: Sept. 23, 2021
Abstract
Metal–organic
frameworks
(MOFs),
which
consist
of
central
metal
nodes
and
organic
linkers,
constitute
a
fast
growing
class
crystalline
porous
materials
with
excellent
application
potential.
Herein,
series
Mn‐based
multimetallic
MOF
(bimetallic
trimetallic
MIL‐100)
nano‐octahedra
are
prepared
by
facile
one‐pot
synthetic
strategy.
The
types
proportions
the
incorporated
elements
can
be
tuned
while
retaining
original
topological
structure.
introduction
other
ions
is
verified
at
atomic
level
combining
X‐ray
absorption
fine
structure
experiments
theoretical
calculations.
Furthermore,
these
MIL‐100
utilized
as
sulfur
hosts
to
prepare
cathodes
for
Li–S
batteries.
MnNi‐MIL‐100@S
cathode
exhibits
best
battery
performance
among
all
reported
MIL‐100@S
composite
materials,
reversible
capacity
≈708.8
mAh
g
−1
after
200
cycles.
strategy
described
herein
incorporate
into
architecture,
parent
monometallic
cannot
directly,
thus
rationally
generating
novel
MOFs.
Importantly,
also
allows
general
synthesis
study
various
micro‐/nanoscale
MOFs
in
energy
storage
field.
Advanced Functional Materials,
Journal Year:
2021,
Volume and Issue:
31(37)
Published: June 26, 2021
Abstract
Photocatalysis
is
considered
to
be
a
green
and
environment‐friendly
technology
since
it
can
convert
solar
energy
into
other
types
of
chemical
energies.
Over
the
past
several
years,
metal‐organic
frameworks
(MOFs)‐based
photocatalysts
have
received
remarkable
research
interest
due
their
unique
morphology,
high
photocatalytic
performance,
good
stability,
easy
synthesis,
low
cost.
In
this
review,
synthetic
strategies
developing
MOFs‐based
are
first
introduced.
Second,
recent
progress
in
fabrication
various
MOFs
composites
summarized.
Third,
different
applications
including
hydrogen
evolution
reaction,
oxygen
overall
water
splitting,
nitrogen
reduction
carbon
dioxide
reaction
as
well
photodegradation
organic
pollutants
summed
up.
Finally,
challenges
some
suggestions
for
future
development
MOFs‐
composites‐based
also
highlighted.
It
expected
that
report
will
help
researchers
systematically
devise
develop
highly
efficient
based
on
composites.
