A NHC-Silyliumylidene Cation for Catalytic N-Formylation of Amines Using Carbon Dioxide DOI
Bi‐Xiang Leong,

Yeow-Chuan Teo,

Cloé Condamines

et al.

ACS Catalysis, Journal Year: 2020, Volume and Issue: 10(24), P. 14824 - 14833

Published: Dec. 3, 2020

This study describes the use of a silicon(II) complex, namely, NHC-silyliumylidene cation complex [(IMe)2SiH]I (1, IMe = :C{N(Me)C(Me)}2), to catalyze chemoselective N-formylation primary and secondary amines using CO2 PhSiH3 under mild conditions afford corresponding formamides as sole product (average reaction time: 4.5 h; amines, average yield: 95%, TOF: 8 h–1; 98%, 17 h–1). The activity 1 yields outperform currently available non-transition-metal catalysts used for this catalysis. Mechanistic studies show that center in catalyzes C–N bond formation via different pathway comparison with catalysts. It sequentially activates CO2, PhSiH3, which proceeds dihydrogen elimination mechanism, form formamides, siloxanes, gas.

Language: Английский

Solvent-free incorporation of CO2 into 2-oxazolidinones: a review DOI Creative Commons
Sattar Arshadi, Alireza Banaei, Saeideh Ebrahimiasl

et al.

RSC Advances, Journal Year: 2019, Volume and Issue: 9(34), P. 19465 - 19482

Published: Jan. 1, 2019

This review is an overview on the recent advances in synthesis of 2-oxazolidinones through CO2 fixation reactions under solvent-free conditions.

Language: Английский

Citations

60
Calcium carbide as a dehydrating agent for the synthesis of carbamates, glycerol carbonate, and cyclic carbonates from carbon dioxide DOI
Qiao Zhang,

Hao‐Yu Yuan,

Xiao-Tao Lin

et al.

Green Chemistry, Journal Year: 2020, Volume and Issue: 22(13), P. 4231 - 4239

Published: Jan. 1, 2020

Calcium carbide was used as a sustainable dehydrating agent for the synthesis of carbamates, glycerol carbonate, and cyclic carbonates directly from CO2.

Language: Английский

Citations

59
C3-symmetric zinc complexes as sustainable catalysts for transforming carbon dioxide into mono- and multi-cyclic carbonates DOI
Kanagaraj Naveen, Hoon Ji,

Tea Soon Kim

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2020, Volume and Issue: 280, P. 119395 - 119395

Published: Aug. 15, 2020

Language: Английский

Citations

59
Synthesis of well-defined yttrium-based Lewis acids by capturing a reaction intermediate and catalytic application for cycloaddition of CO2 to epoxides under atmospheric pressure DOI

Ounjit Sodpiban,

Silvano Del Gobbo, Samir Barman

et al.

Catalysis Science & Technology, Journal Year: 2019, Volume and Issue: 9(21), P. 6152 - 6165

Published: Jan. 1, 2019

Single-site yttrium complexes were prepared by immobilization of an intermediate cycloaddition CO2 to epoxides and applied in catalysis.

Language: Английский

Citations

58
A NHC-Silyliumylidene Cation for Catalytic N-Formylation of Amines Using Carbon Dioxide DOI
Bi‐Xiang Leong,

Yeow-Chuan Teo,

Cloé Condamines

et al.

ACS Catalysis, Journal Year: 2020, Volume and Issue: 10(24), P. 14824 - 14833

Published: Dec. 3, 2020

This study describes the use of a silicon(II) complex, namely, NHC-silyliumylidene cation complex [(IMe)2SiH]I (1, IMe = :C{N(Me)C(Me)}2), to catalyze chemoselective N-formylation primary and secondary amines using CO2 PhSiH3 under mild conditions afford corresponding formamides as sole product (average reaction time: 4.5 h; amines, average yield: 95%, TOF: 8 h–1; 98%, 17 h–1). The activity 1 yields outperform currently available non-transition-metal catalysts used for this catalysis. Mechanistic studies show that center in catalyzes C–N bond formation via different pathway comparison with catalysts. It sequentially activates CO2, PhSiH3, which proceeds dihydrogen elimination mechanism, form formamides, siloxanes, gas.

Language: Английский

Citations

56