Journal of the Chinese Chemical Society,
Journal Year:
2019,
Volume and Issue:
67(2), P. 192 - 196
Published: Sept. 9, 2019
Abstract
A
new
protocol
for
SO
bond
formation
was
developed
by
electrochemical
oxidative
cross‐coupling
between
alcohols
and
thiophenols.
With
this
strategy,
a
series
of
valuable
sulfinic
ester
derivatives
were
synthesized
up
to
96%
yield
from
basic
starting
materials.
preliminary
mechanistic
investigation
reveals
that
reaction
involves
oxygen
reduction
(ORR).
Green Chemistry,
Journal Year:
2024,
Volume and Issue:
26(5), P. 2592 - 2598
Published: Jan. 1, 2024
A
novel
copper-based
biomass-carbon
aerogel
catalyst
was
prepared
as
a
highly
efficient
and
selective
for
maleimides
reduction
the
first
time
with
excellent
catalytic
activity,
chemo-selectivity,
recyclability.
Croatica Chemica Acta,
Journal Year:
2018,
Volume and Issue:
91(3)
Published: Jan. 1, 2018
A
mild
and
efficient
one-pot
visible
light-induced
method
has
been
developed
for
the
synthesis
of
sulfinic
esters.Sulfinic
esters
are
important
structural
elements
that
frequently
found
in
pharmaceutical
agents
biologically
active
natural
products.The
routine
procedure
drug
discovery
development
process
to
prepare
fully
characterize
make
them
a
candidate
biological
evaluation.
Chemical Communications,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
Recent
sulfinate
esters
chemistry
is
summarized
in
this
feature
article.
Efficient
methods
to
synthesize
diverse
from
readily
available
starting
materials
and
various
modern
transformations
of
are
introduced.
Chemical Communications,
Journal Year:
2018,
Volume and Issue:
54(65), P. 9087 - 9090
Published: Jan. 1, 2018
By
ruthenium/acid
dual
catalysis,
a
novel
transfer
hydrogenative
para-selective
aminoalkylation
of
aniline
derivatives
with
N-heteroarenes
has
been
demonstrated.
Organic Letters,
Journal Year:
2019,
Volume and Issue:
21(19), P. 7722 - 7725
Published: Sept. 12, 2019
A
novel
dual
catalytic
system
of
iodine
and
manganese
is
used
for
the
first
time
oxidative
dehydrogenation
coupling
amines
with
thiols
during
aerobic
oxidation.
Sulfenamides
are
synthesized
via
this
approach
moderate
to
high
efficiencies.
The
mechanistic
studies
indicate
that
activated
MnO2
an
electron
transfer
bridge
assisting
in
completing
cycle.
ACS Omega,
Journal Year:
2020,
Volume and Issue:
5(29), P. 18515 - 18526
Published: July 13, 2020
A
tetrabutylammonium
iodide-mediated
direct
sulfenylation
of
arenes
with
ethyl
arylsulfinates
in
water
was
developed.
Various
electron-rich
and
were
investigated
the
reaction,
a
series
aryl
sulfides
obtained
excellent
yields.
The
advantages
this
green
protocol
simple
reaction
conditions
(metal-free,
as
solvent,
under
air),
odorless
easily
available
sulfur
reagent,
broad
substrate
scope,
gram-scale
synthesis.
Moreover,
potential
application
exemplified
by
further
transformations.
Organic & Biomolecular Chemistry,
Journal Year:
2021,
Volume and Issue:
19(40), P. 8656 - 8686
Published: Jan. 1, 2021
This
review
describes
the
oxidative
cross-couplings
of
thiols
forming
various
organosulfur
compounds,
focusing
on
critical
intermediates
such
as
sulfenyl
halides,
thiyl
radicals,
sulfenium
cations,
disulfides,
and
organo-transition
metal
intermediates.
Organic Letters,
Journal Year:
2022,
Volume and Issue:
24(33), P. 6159 - 6164
Published: Aug. 16, 2022
Herein,
with
air-stable
chalcogenated
stibines
(Sb-ER)
as
organometallic
chalcogenating
reagents,
we
developed
base-promoted
(Z)-hydrochalcogenation
of
alkynes
DMSO/DMSO-d6
hydrogen/deuterium
sources,
giving
(Z)-olefins
in
good
yields
and
excellent
regioselectivity.
These
easily
synthesized
from
halostibines
situ
generated
[Zn(ER)2]
at
room
temperature
within
a
few
minutes,
could
be
also
used
the
C(sp3)-S(Se)
cross-coupling
C(sp3)-X
copper-catalyzed
C(sp2)-S(Se)
C(sp2)-X
(X
=
F,
CI,
Br,
I)
under
mild
conditions.
This
protocol
simply
extended
to
organobismuth
complexes
(Bi-ER)
functional
tolerance.
Organic Letters,
Journal Year:
2018,
Volume and Issue:
20(20), P. 6554 - 6558
Published: Oct. 4, 2018
By
employing
reusable
nanocobalt
oxides
as
the
catalysts,
a
site-specific
oxidative
C-H
chalcogenation
of
(hetero)aryl-fused
cyclic
amines
with
various
thiols
and
diselenides
is
presented
for
first
time.
The
reaction
proceeds
selectively
at
sites
(hetero)aryl
rings
para
to
N
atom,
enables
access
wide
array
chalcogenyl
N-heteroarenes.
merits
transformation
involve
high
step-
atom-efficiency,
excellent
substrate
functional
compatibility,
operational
simplicity,
use
naturally
abundant
Co/O2
system.
present
work
has
offered
fundamental
basis
selective
synthesis
N-heteroarenes
from
readily
available
feedstocks.
