Benzyl thioether formation merging copper catalysis DOI Creative Commons
Bing Xu, Ying‐Chih Lin, Yang Ye

et al.

RSC Advances, Journal Year: 2021, Volume and Issue: 12(2), P. 692 - 697

Published: Dec. 23, 2021

A novel copper-catalyzed thioetherification reaction has been developed to afford benzyl thioethers in moderate excellent yields. Under the mild and easy-to-operate conditions, a variety of are efficiently prepared from readily available alcohols (primary, secondary, tertiary) thiols presence Cu(OTf)2 as Lewis acid catalysis. This C-S bond formation protocol furnishes exceptional chemoselectivity, preliminary mechanism studies show that should proceed through Lewis-acid-mediated SN1-type nucleophilic attack carbocations formed situ.

Language: Английский

A new pathway to pyrrolo[1,2-a]quinoxalines via solvent-free one-pot strategy utilizing FeMoSe nanosheets as efficient recyclable synergistic catalyst DOI
Tuong Anh To,

Chuc T. Nguyen,

My Ha Tran

et al.

Journal of Catalysis, Journal Year: 2019, Volume and Issue: 377, P. 163 - 173

Published: July 31, 2019

Language: Английский

Citations

16
Copper-catalyzed oxidative sulfenylation and alkylation of indolin-2-ones for direct construction of sulfur-substituted quaternary carbons DOI

Yun‐Hao Zhang,

Yinuo Wang, Ziyu Liu

et al.

Organic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(11), P. 3131 - 3136

Published: Jan. 1, 2024

A rapid and green one-pot access to S -substituted quaternary carbon centers from commercially available feedstock chemicals has been established, providing complex molecules with high chemoselectivity by the use of air as terminal oxidant.

Language: Английский

Citations

1
Regulation of the Properties of Hydrogen Dissociation and Transfer in the Presence of S Atoms for Efficient Hydrogenations DOI Creative Commons

Xiaoyan Liu,

Mingyuan Zhang, Xin Liu

et al.

ACS Catalysis, Journal Year: 2024, Volume and Issue: 14(21), P. 16214 - 16223

Published: Oct. 18, 2024

The dissociation and spillover process of hydrogen is one the key processes in hydrogenation reactions, but this very challenging or even impossible presence a S atom, as atoms can severely poison surface supported metal catalysts. Herein, we report that efficient transfer be achieved poisoning over synergetic units together with H2 5-nitrobenzothiazole catalyzed by Pt/MoO3. Pt/MoO3 showcases 99% conversion ∼99% selectivity under mild reaction conditions most active catalysts reported so far for sulfur atom-containing compounds. Mechanism studies, situ characterization, density functional theory calculations collectively demonstrate MoO3 support, H1.68MoO3 an intermediate, acts bridge transferring H species between Pt sites nitrobenzothiazole. unique proton storage release properties formed not only accelerate breaking N–O bond also prevent poisoning. This work provides promising strategy to tackle current challenges catalytic

Language: Английский

Citations

1
Molybdenum (VI)-catalyzed dehydrative construction of C O and C S bonds formation via etherification and thioetherification of alcohols and thiols DOI

RahulKumar Rajmani Singh,

Alex Whittington,

R. S. Srivastava

et al.

Molecular Catalysis, Journal Year: 2020, Volume and Issue: 492, P. 110954 - 110954

Published: May 30, 2020

Language: Английский

Citations

9
Benzyl thioether formation merging copper catalysis DOI Creative Commons
Bing Xu, Ying‐Chih Lin, Yang Ye

et al.

RSC Advances, Journal Year: 2021, Volume and Issue: 12(2), P. 692 - 697

Published: Dec. 23, 2021

A novel copper-catalyzed thioetherification reaction has been developed to afford benzyl thioethers in moderate excellent yields. Under the mild and easy-to-operate conditions, a variety of are efficiently prepared from readily available alcohols (primary, secondary, tertiary) thiols presence Cu(OTf)2 as Lewis acid catalysis. This C-S bond formation protocol furnishes exceptional chemoselectivity, preliminary mechanism studies show that should proceed through Lewis-acid-mediated SN1-type nucleophilic attack carbocations formed situ.

Language: Английский

Citations

8