Environment International,
Journal Year:
2020,
Volume and Issue:
146, P. 106273 - 106273
Published: Nov. 28, 2020
Advanced
oxidation
process
(AOP),
with
a
high
efficiency,
fast
reaction
speed
(relatively
no
secondary
pollution),
has
become
one
of
the
core
technologies
industrial
wastewater
and
advanced
drinking
water
treatment.
Heterogeneous
Fenton-like
(HFOP)
is
kind
AOP,
which
developed
rapidly
in
recent
years
such
way
to
overcome
disadvantages
traditional
Fenton
reaction.
Metal-organic
frameworks
(MOFs)
their
derivatives
essential
heterogeneous
catalysts
for
organics
mineralization
due
large
specific
surface
area,
abundant
active
sites,
ease
structural
regulation.
However,
knowledge
gap
on
mechanism
fate
catalyst
species
during
degradation
activities
by
MOFs
presents
considerable
impediments,
particularly
wide
application
scaling
up
process.
This
work
potential
provide
guidance
ideas
researchers
engineers
fields
environmental
remediation,
catalysis
functional
materials.
review
focuses
clarifying
critical
•OH
production
from
as
well
its
action
organic's
The
developments
MOF
based
HFOP
are
compared,
more
attention
paid
following
aspects
this
review:
(1)
classifies
systematically
progressive
modification
methods
chemical
physical
treatments;
(2)
analyzes
catalytic
treating
organic
wastewater;
(3)
proposes
design
principles
improving
performance
catalysts;
(4)
discusses
main
factors
influencing
properties
practical
application;
(5)
summarizes
possible
research
challenges
directions
applied
treatment
future.
Chemical Reviews,
Journal Year:
2019,
Volume and Issue:
119(6), P. 3510 - 3673
Published: March 4, 2019
In
the
last
few
decades,
pharmaceuticals,
credited
with
saving
millions
of
lives,
have
emerged
as
a
new
class
environmental
contaminant.
These
compounds
can
both
chronic
and
acute
harmful
effects
on
natural
flora
fauna.
The
presence
pharmaceutical
contaminants
in
ground
waters,
surface
waters
(lakes,
rivers,
streams),
sea
water,
wastewater
treatment
plants
(influents
effluents),
soils,
sludges
has
been
well
doccumented.
A
range
methods
including
oxidation,
photolysis,
UV-degradation,
nanofiltration,
reverse
osmosis,
adsorption
used
for
their
remediation
from
aqueous
systems.
Many
commercially
limited
by
toxic
sludge
generation,
incomplete
removal,
high
capital
operating
costs,
need
skilled
maintenance
personnel.
Adsorption
technologies
are
low-cost
alternative,
easily
developing
countries
where
there
is
dearth
advanced
technologies,
personnel,
available
capital,
appears
to
be
most
broadly
feasible
removal
method.
integrated
(WWTPs).
Herein,
we
reviewed
literature
(1990–2018)
illustrating
rising
contamination
concerns
efforts
emphasizing
adsorption.
Chemical Society Reviews,
Journal Year:
2019,
Volume and Issue:
48(2), P. 463 - 487
Published: Jan. 1, 2019
We
review
and
analyze
current
water
purification
technologies
in
the
context
of
sustainability,
we
introduce
Ranking
Efficiency
Product
(REP)
index,
to
evaluate
their
efficiency
implementation
this
broader
perspective.
Advanced Materials,
Journal Year:
2021,
Volume and Issue:
33(9)
Published: Jan. 14, 2021
Abstract
Manganese
dioxide
(MnO
2
)
is
a
promising
photo–thermo–electric‐responsive
semiconductor
material
for
environmental
applications,
owing
to
its
various
favorable
properties.
However,
the
unsatisfactory
purification
efficiency
of
this
has
limited
further
applications.
Fortunately,
in
last
few
years,
significant
efforts
have
been
undertaken
improving
and
understanding
underlying
mechanism.
Here,
aim
summarize
recent
experimental
computational
research
progress
modification
MnO
single
species
by
morphology
control,
structure
construction,
facet
engineering,
element
doping.
Moreover,
design
fabrication
‐based
composites
via
construction
homojunctions
/semiconductor/conductor
binary/ternary
heterojunctions
discussed.
Their
applications
systems,
either
as
an
adsorbent
removing
heavy
metals,
dyes,
microwave
(MW)
pollution,
or
thermal
catalyst,
photocatalyst,
electrocatalyst
degradation
pollutants
(water
gas,
organic
inorganic)
are
also
highlighted.
Finally,
gaps
summarized
perspective
on
challenges
direction
future
nanostructured
materials
field
presented.
Therefore,
basic
guidance
rational
high‐efficiency
comprehensive
provided.
Coordination Chemistry Reviews,
Journal Year:
2021,
Volume and Issue:
451, P. 214263 - 214263
Published: Oct. 22, 2021
Cellulose–MOFs
(CelloMOFs)
are
attractive
hybrid
materials
that
make
available
a
range
of
hitherto
unattainable
properties
by
conjugating
cellulosic
with
metal–organic
frameworks
(MOFs).
CelloMOFs
have
demonstrated
great
potential
to
be
applied
in
several
fields
such
as
water
remediation,
air
purification,
gas
storage,
sensing/biosensing,
and
biomedicine.
can
act
an
efficient
adsorbent
remove
emerging
contaminants
metals,
dyes,
drugs,
antibiotics,
pesticides,
oils
via
adsorption.
They
also
used
catalysts
for
catalytic
degradation,
reduction,
oxidation
organic
pollutants.
been
filters
purification
removing
greenhouse
gases
carbon
dioxide
(CO2),
volatile
compounds
(VOCs),
particulate
matter
(PMs).
Biomedical
applications
antibacterial,
drug
delivery,
biosensing
were
reported
materials.
This
review
summarized
the
synthesis,
characterization,
cellulose-MOFs
It
covered
broad
overview
status
combination
cellulose
micron
nanoscale
MOFs.
At
end
review,
challenges
outlook
regarding
discussed.
Hopefully,
this
will
useful
guide
researchers
scientists
who
looking
quick
access
relevant
references
about
their
applications.
ACS Sustainable Chemistry & Engineering,
Journal Year:
2019,
Volume and Issue:
7(8), P. 7456 - 7478
Published: March 20, 2019
Environmental
pollution
and
its
after-effects
have
become
global
concerns
in
recent
years.
Among
all
types
of
pollution,
water
has
been
considered
as
a
major
threat
years;
this
problem
will
be
even
worse
the
near
future.
In
21st
century,
recycling
crucial
issue
more
regions
across
globe
are
witnessing
crisis.
Detoxification
wastewater
via
adsorptive
removal
or
photocatalytic
degradation
for
achieving
purified
drinkable
determined
environmentally
benign,
energy
economic
cost-effective.
context,
porous
materials
gained
enormous
research
consideration
detection
contaminants
effluents
treatment
wastewater.
A
combination
high
porosity,
robustness
structural
tunibility
makes
these
nanosorbents
stand
out
environmental
remediation.
Metal–organic
frameworks,
covalent
organic
frameworks
solids
among
versatile
extensively
investigated
toward
clean
environment
application.
This
review
intends
to
provide
summarized
compilation
progress
sensing
sequestration
pollutants
advanced
materials.