Environment International,
Journal Year:
2020,
Volume and Issue:
146, P. 106273 - 106273
Published: Nov. 28, 2020
Advanced
oxidation
process
(AOP),
with
a
high
efficiency,
fast
reaction
speed
(relatively
no
secondary
pollution),
has
become
one
of
the
core
technologies
industrial
wastewater
and
advanced
drinking
water
treatment.
Heterogeneous
Fenton-like
(HFOP)
is
kind
AOP,
which
developed
rapidly
in
recent
years
such
way
to
overcome
disadvantages
traditional
Fenton
reaction.
Metal-organic
frameworks
(MOFs)
their
derivatives
essential
heterogeneous
catalysts
for
organics
mineralization
due
large
specific
surface
area,
abundant
active
sites,
ease
structural
regulation.
However,
knowledge
gap
on
mechanism
fate
catalyst
species
during
degradation
activities
by
MOFs
presents
considerable
impediments,
particularly
wide
application
scaling
up
process.
This
work
potential
provide
guidance
ideas
researchers
engineers
fields
environmental
remediation,
catalysis
functional
materials.
review
focuses
clarifying
critical
•OH
production
from
as
well
its
action
organic's
The
developments
MOF
based
HFOP
are
compared,
more
attention
paid
following
aspects
this
review:
(1)
classifies
systematically
progressive
modification
methods
chemical
physical
treatments;
(2)
analyzes
catalytic
treating
organic
wastewater;
(3)
proposes
design
principles
improving
performance
catalysts;
(4)
discusses
main
factors
influencing
properties
practical
application;
(5)
summarizes
possible
research
challenges
directions
applied
treatment
future.
Advanced Functional Materials,
Journal Year:
2019,
Volume and Issue:
30(41)
Published: Nov. 18, 2019
Abstract
The
demand
for
practical
and
cost‐effective
environmental
treatment
energy
storage
materials
is
exploding.
Porous
polymeric
carbonaceous
have
attracted
tremendous
interest
on
account
of
their
well‐developed
porosity
tunable
surface
chemistry.
Functionalization
pore
structures
further
enhances
properties
storage.
Herein,
the
procedures
functionalization
porous
are
introduced,
including
predesign
postsynthetic
strategies.
Subsequently,
important
advancements
emerging
polymers
in
sorption
(e.g.,
organic
micropollutant
adsorption,
heavy
metal
ion
removal,
radionuclide
extraction,
oil
absorption)
membrane
separation
aqueous
separation,
solvent
nanofiltration,
desalination
pervaporation),
as
well
ranging
from
electrodes
separators
batteries
to
supercapacitor
highlighted.
Moreover,
given
combined
merits
high
intrinsic
conductivity,
porosity,
physicochemical
stability,
novel
polymer‐based
carbons
also
Key
chemistry
each
application
discussed
an
in‐depth
understanding
structure–property
relationships
these
functional
provided.
Finally,
challenges
perspectives
proposed.
ACS Applied Materials & Interfaces,
Journal Year:
2018,
Volume and Issue:
10(28), P. 24164 - 24171
Published: June 25, 2018
Global
environmental
challenges
especially
nuclear
pollution
pose
a
great
threat
to
human
health
and
public
safety.
Metal-organic
frameworks
(MOFs)
with
high
surface
area
excellent
stability
are
potential
candidates
for
the
remediation
of
pollution.
Herein,
ZIF-8-based
polyacrylonitrile
(PAN)
fibrous
filter
was
prepared
by
an
in
situ
hydrothermal
treatment
filters
consisting
PAN,
poly(vinylpyrrolidone)
(PVP),
zinc
ions
electrospinning
method.
In
process
treatment,
PVP
can
be
extracted
from
PAN
nanofibers
result
porous
structures.
Benefiting
these
structures,
ZIF-8/PAN
demonstrated
adsorption
capacity
U(VI)
(530.3
mg
g-1
at
pH
=
3.0).
The
extended
X-ray
absorption
fine
structure
revealed
that
mechanism
complexation
between
2-methylimidazole.
Furthermore,
device
fabricated,
dynamic
shows
is
promising
material
treating
wastewater.
present
work
may
provide
new
strategy
fabricate
MOFs
into
functional
devices
remediate
increasing
global
concerns.
Chemical Reviews,
Journal Year:
2022,
Volume and Issue:
122(24), P. 17241 - 17338
Published: Nov. 1, 2022
Current
energy
and
environmental
challenges
demand
the
development
design
of
multifunctional
porous
materials
with
tunable
properties
for
catalysis,
water
purification,
conversion
storage.
Because
their
amenability
to
de
novo
reticular
chemistry,
metal-organic
frameworks
(MOFs)
have
become
key
in
this
area.
However,
usefulness
is
often
limited
by
low
chemical
stability,
conductivity
inappropriate
pore
sizes.
Conductive
two-dimensional
(2D)
robust
structural
skeletons
and/or
functionalized
surfaces
can
form
stabilizing
interactions
MOF
components,
enabling
fabrication
nanocomposites
characteristics.
Graphene
its
functional
derivatives
are
largest
class
2D
possess
remarkable
compositional
versatility,
diversity,
controllable
surface
chemistry.
Here,
we
critically
review
current
knowledge
concerning
growth,
structure,
graphene
derivatives,
MOFs,
graphene@MOF
composites
as
well
associated
structure-property-performance
relationships.
Synthetic
strategies
preparing
tuning
also
comprehensively
reviewed
together
applications
gas
storage/separation,
catalysis
(organo-,
electro-,
photocatalysis),
electrochemical
storage
conversion.
hybrids
practical
addressed,
revealing
areas
future
investigation.
We
hope
that
will
inspire
further
exploration
new
energy,
electronic,
biomedical,
photocatalysis
studies
on
previously
unreported
known
reveal
potential
"diamonds
rough".
Catalysis Science & Technology,
Journal Year:
2021,
Volume and Issue:
11(12), P. 3946 - 3989
Published: Jan. 1, 2021
The
presented
review
focuses
on
design
strategies
to
develop
tailor-made
MOFs/CPs
of
main
group,
transition
and
inner-transition
elements
their
photocatalytic
properties
decompose
dyes
in
wastewater
discharge
mechanism.
