The Journal of Organic Chemistry,
Journal Year:
2022,
Volume and Issue:
87(19), P. 12921 - 12931
Published: Sept. 21, 2022
A
simple
visible-light-initiated
strategy
has
been
established
for
the
construction
of
organophosphorus
compounds
via
aerobic
multicomponent
reaction
α-diazoesters,
cyclic
ethers,
and
P(O)H
under
air.
number
phosphonates
phosphinates
could
be
efficiently
isolated
in
moderate
to
good
yields
without
use
photosensitizers
metal
reagents.
This
advantages
mild
condition,
operation,
eco-friendly
energy,
functional-group
tolerance,
gram-scale
synthesis.
Green Chemistry,
Journal Year:
2021,
Volume and Issue:
23(21), P. 8533 - 8544
Published: Jan. 1, 2021
Herein
we
have
reported
a
blue
LED
mediated
reaction
of
aryl
diazoacetate
with
stoichiometric
amount
1,4-dioxane/tetrahydropyran
and
various
heterocycles
like
indoles,
pyrrole,
phthalimide,
succinimide,
thiazolidinedione
hydantoin
in
water.
Molecules,
Journal Year:
2023,
Volume and Issue:
28(6), P. 2816 - 2816
Published: March 21, 2023
As
an
underrepresented
functional
group
in
bioorganic
and
medicinal
chemistry,
the
hydroxylamine
unit
has
historically
received
little
attention
from
synthetic
community.
Recent
developments,
however,
suggest
that
hydroxylamines
may
have
broader
applications
such
a
review
covering
recent
developments
synthesis
of
this
is
timely.
With
mind,
primarily
covers
past
15
years
preparation
di-
trisubstituted
hydroxylamines.
The
mechanism
reactions
key
features
shortcomings
are
discussed
throughout
review.
Organic & Biomolecular Chemistry,
Journal Year:
2020,
Volume and Issue:
18(41), P. 8294 - 8345
Published: Jan. 1, 2020
A
review
on
the
wide
range
of
organic
and
inorganic
brominated
compounds,
which
have
been
extensively
used
as
oxidants
in
many
photo-redox
transformations
recent
years,
an
area
sublime
interest
because
greener
milder
approaches.
The Journal of Organic Chemistry,
Journal Year:
2021,
Volume and Issue:
86(23), P. 17528 - 17532
Published: Nov. 18, 2021
Two
visible-light-mediated
O–H
insertion
protocols
involving
oximes
and
aryldiazoacetates
leading
to
different
products
depending
on
the
solvent
employed
are
reported.
In
DCM,
direct
takes
place.
THF,
there
is
additional
incorporation
of
ring-opened
form
this
into
structure
product.
These
metal-free
mild
tolerant
air
moisture.
The
preparation
an
acaricide
has
been
developed
as
example
synthetic
application.
The Journal of Organic Chemistry,
Journal Year:
2022,
Volume and Issue:
87(19), P. 12921 - 12931
Published: Sept. 21, 2022
A
simple
visible-light-initiated
strategy
has
been
established
for
the
construction
of
organophosphorus
compounds
via
aerobic
multicomponent
reaction
α-diazoesters,
cyclic
ethers,
and
P(O)H
under
air.
number
phosphonates
phosphinates
could
be
efficiently
isolated
in
moderate
to
good
yields
without
use
photosensitizers
metal
reagents.
This
advantages
mild
condition,
operation,
eco-friendly
energy,
functional-group
tolerance,
gram-scale
synthesis.
