Advanced Science,
Journal Year:
2022,
Volume and Issue:
9(11)
Published: Feb. 4, 2022
Metal-organic
polyhedra
(MOPs)
are
a
subclass
of
coordination
cages
that
can
adsorb
and
host
species
in
solution
permanently
porous
solid-state.
These
characteristics,
together
with
the
recent
development
their
orthogonal
surface
chemistry
assembly
more
stable
cages,
have
awakened
latent
potential
MOPs
to
be
used
as
building
blocks
for
synthesis
extended
networks.
This
review
article
focuses
on
exploring
key
developments
make
extension
possible,
highlighting
most
remarkable
examples
MOP-based
soft
materials
crystalline
frameworks.
Finally,
ventures
offer
future
perspectives
exploitation
fields
still
remain
ripe
toward
use
such
unorthodox
molecular
platforms.
Journal of Materials Chemistry A,
Journal Year:
2021,
Volume and Issue:
9(46), P. 25731 - 25749
Published: Jan. 1, 2021
This
review
summarized
the
recent
advances
made
in
task-specific
design
and
synthesis
of
metalloporphyrin-based
porous
organic
polymers
(POPs)
their
functionalization
for
conversion
CO
2
into
cyclic
carbonates.
ACS Applied Materials & Interfaces,
Journal Year:
2021,
Volume and Issue:
13(33), P. 39404 - 39413
Published: Aug. 13, 2021
The
targeted
synthesis
of
a
novel
ionic
porous
organic
polymer
(iPOP)
was
reported.
compound
(denoted
as
QUST-iPOP-1)
built
up
through
quaternization
reaction
tris(4-imidazolylphenyl)amine
and
cyanuric
chloride,
then
benzyl
bromide
added
to
complete
the
total
imidazolyl
units.
It
featured
special
exchangeable
Cl–/Br–-rich
structure
with
high
permanent
porosity
wide
pore
size
distribution,
enabling
it
rapidly
effectively
remove
environmentally
toxic
oxo-anions
including
Cr2O72–,
MnO4–,
ReO4–
anionic
dyes
different
sizes
methyl
blue,
Congo
red,
orange
from
water.
Notably,
QUST-iPOP-1
showed
ultra-high
capacity
values
for
radioactive
TcO4–
surrogate
anions
(MnO4–
ReO4–),
these
were
comparable
some
reported
compounds
exhaustive
research.
Furthermore,
relative
removal
rate
even
when
other
concurrent
existed.
Chemical Science,
Journal Year:
2022,
Volume and Issue:
13(4), P. 1111 - 1118
Published: Jan. 1, 2022
Porous
materials
have
recently
attracted
much
attention
owing
to
their
fascinating
structures
and
broad
applications.
Moreover,
exploring
novel
porous
polymers
affording
the
efficient
capture
of
iodine
is
significant
interest.
In
contrast
reported
fabricated
with
small
molecular
blocks,
we
herein
report
preparation
polymer
frameworks
using
rigid
polyisocyanides
as
building
blocks.
First,
tetrahedral
four-arm
star
predictable
weight
low
dispersity
were
synthesized;
chain-ends
polyisocyanide
blocks
then
crosslinked,
yielding
well-defined
organic
a
designed
pore
size
narrow
distribution.
Polymers
appropriate
observed
efficiently
radioactive
in
both
aqueous
vapor
phases.
More
than
98%
could
be
captured
within
1
minute
from
saturated
solution
(capacity
up
3.2
g
g-1),
an
adsorption
capacity
574
wt%
was
measured
4
hours.
recovered
recycled
for
at
least
six
times,
while
maintaining
high
performance.
Advanced Science,
Journal Year:
2022,
Volume and Issue:
9(19)
Published: Jan. 20, 2022
Mechanochemistry
uses
mechanical
force
to
break,
form,
and
manipulate
chemical
bonds
achieve
functional
transformations
syntheses.
Over
the
last
years,
many
innovative
applications
of
mechanochemistry
have
been
developed.
Specifically
for
synthesis
activation
carbon-rich
π-conjugated
materials,
offers
reaction
pathways
that
either
are
inaccessible
with
other
stimuli,
such
as
light
heat,
or
improve
yields,
energy
consumption,
substrate
scope.
Therefore,
this
review
summarizes
recent
advances
in
research
field
combining
viewpoints
polymer
trituration
mechanochemistry.
The
highlighted
mechanochemical
include
materials
optical
probes,
force-induced
release
small
dye
molecules,
polyacetylene,
carbon
allotropes,
materials.
Advanced Science,
Journal Year:
2022,
Volume and Issue:
9(11)
Published: Feb. 4, 2022
Metal-organic
polyhedra
(MOPs)
are
a
subclass
of
coordination
cages
that
can
adsorb
and
host
species
in
solution
permanently
porous
solid-state.
These
characteristics,
together
with
the
recent
development
their
orthogonal
surface
chemistry
assembly
more
stable
cages,
have
awakened
latent
potential
MOPs
to
be
used
as
building
blocks
for
synthesis
extended
networks.
This
review
article
focuses
on
exploring
key
developments
make
extension
possible,
highlighting
most
remarkable
examples
MOP-based
soft
materials
crystalline
frameworks.
Finally,
ventures
offer
future
perspectives
exploitation
fields
still
remain
ripe
toward
use
such
unorthodox
molecular
platforms.
