One-step synthesis of single-site vanadium substitution in 1T-WS2 monolayers for enhanced hydrogen evolution catalysis DOI Creative Commons
Ali Han, Xiaofeng Zhou, Xijun Wang

et al.

Nature Communications, Journal Year: 2021, Volume and Issue: 12(1)

Published: Jan. 29, 2021

Abstract Metallic tungsten disulfide (WS 2 ) monolayers have been demonstrated as promising electrocatalysts for hydrogen evolution reaction (HER) induced by the high intrinsic conductivity, however, key challenges to maximize catalytic activity are achieving metallic WS with concentration and increasing density of active sites. In this work, single-atom-V catalysts (V SACs) substitutions in 1T-WS (91% phase purity) fabricated significantly enhance HER performance via a one-step chemical vapor deposition strategy. Atomic-resolution scanning transmission electron microscopy (STEM) imaging together Raman spectroscopy confirm atomic dispersion V species on instead energetically favorable 2H-WS monolayers. The growth mechanism SACs@1T-WS is experimentally theoretically demonstrated. Density functional theory (DFT) calculations demonstrate that activated V-atom sites play vital important role enhancing activity. it opens novel path directly synthesize atomically dispersed single-metal metastable materials efficient robust electrocatalysts.

Language: Английский

Synthesis of (100) surface oriented MIL-88A-Fe with rod-like structure and its enhanced fenton-like performance for phenol removal DOI
Xiaoyuan Liao, Fan Wang,

Fang Wang

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2019, Volume and Issue: 259, P. 118064 - 118064

Published: Aug. 7, 2019

Language: Английский

Citations

214
Improving toxic dye removal and remediation using novel nanocomposite fibrous adsorbent DOI Open Access
Ariyan Islam Rehan, Adiba Islam Rasee, Mrs Eti Awual

et al.

Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2023, Volume and Issue: 673, P. 131859 - 131859

Published: June 10, 2023

Language: Английский

Citations

211
Nitrogen doped carbon ribbons modified g-C3N4 for markedly enhanced photocatalytic H2-production in visible to near-infrared region DOI
Huinan Che,

Guang‐Bo Che,

Pengjie Zhou

et al.

Chemical Engineering Journal, Journal Year: 2019, Volume and Issue: 382, P. 122870 - 122870

Published: Sept. 17, 2019

Language: Английский

Citations

209
Conjugated porous polymers: incredibly versatile materials with far-reaching applications DOI
Dominic Taylor, Scott J. Dalgarno, Zhengtao Xu

et al.

Chemical Society Reviews, Journal Year: 2020, Volume and Issue: 49(12), P. 3981 - 4042

Published: Jan. 1, 2020

Conjugated porous polymers (CPPs) are a class of amorphous polymer networks that are, in their design, fully cross-linked and π-conjugated. The nature CPPs means they have permanent intrinsic porosity (on the nanometer scale), which, combination with π-conjugated framework, makes these materials unique among wider polymeric materials. In recent years, need for new efficient functional has driven development as versatile platforms applications including (photo)catalysis, light harvesting, gas separation storage, chemosensing, environmental remediation energy storage. efficiency towards described is heavily influenced by choice molecular building blocks synthetic conditions, allowing facile tailoring optimisation structure properties. aim this review to highlight select works on CPPs, basic structural design principles, various protocols topical

Language: Английский

Citations

208
One-step synthesis of single-site vanadium substitution in 1T-WS2 monolayers for enhanced hydrogen evolution catalysis DOI Creative Commons
Ali Han, Xiaofeng Zhou, Xijun Wang

et al.

Nature Communications, Journal Year: 2021, Volume and Issue: 12(1)

Published: Jan. 29, 2021

Abstract Metallic tungsten disulfide (WS 2 ) monolayers have been demonstrated as promising electrocatalysts for hydrogen evolution reaction (HER) induced by the high intrinsic conductivity, however, key challenges to maximize catalytic activity are achieving metallic WS with concentration and increasing density of active sites. In this work, single-atom-V catalysts (V SACs) substitutions in 1T-WS (91% phase purity) fabricated significantly enhance HER performance via a one-step chemical vapor deposition strategy. Atomic-resolution scanning transmission electron microscopy (STEM) imaging together Raman spectroscopy confirm atomic dispersion V species on instead energetically favorable 2H-WS monolayers. The growth mechanism SACs@1T-WS is experimentally theoretically demonstrated. Density functional theory (DFT) calculations demonstrate that activated V-atom sites play vital important role enhancing activity. it opens novel path directly synthesize atomically dispersed single-metal metastable materials efficient robust electrocatalysts.

Language: Английский

Citations

197